A Structural and Spectroscopic Study of the First Uranyl Selenocyanate, [Et4N]3[UO2(NCSe)5]
Abstract
:1. Introduction
2. Results and Discussion
Compound (Solvent) | λabs U=O (nm) | λem (nm) | E0-0 (cm−1) | τ (μs) | χ2 | Ref. |
---|---|---|---|---|---|---|
1 (MeCN) | 460 | 514 | 20,267 | 1.30 | 1.40 | This work |
[Et4N]3[UO2(NCS)5] (MeCN) | 440 | 520 | 20,072 | 1.40 | 1.02 | [11] |
[UO2Cl2(OPPh3)2] (MeCN) | 440 | 515 | 20,325 | 1.08 | 1.07 | [8] |
[UO2Cl4]2− (MeBu3N[Tf2N]) | 509 | 20,329 | 0.7 | [26] |
3. Experimental Section
Synthesis of 1
4. Conclusions
Supplementary Materials
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Nuzzo, S.; Browne, M.P.; Twamley, B.; Lyons, M.E.G.; Baker, R.J. A Structural and Spectroscopic Study of the First Uranyl Selenocyanate, [Et4N]3[UO2(NCSe)5]. Inorganics 2016, 4, 4. https://doi.org/10.3390/inorganics4010004
Nuzzo S, Browne MP, Twamley B, Lyons MEG, Baker RJ. A Structural and Spectroscopic Study of the First Uranyl Selenocyanate, [Et4N]3[UO2(NCSe)5]. Inorganics. 2016; 4(1):4. https://doi.org/10.3390/inorganics4010004
Chicago/Turabian StyleNuzzo, Stefano, Michelle P. Browne, Brendan Twamley, Michael E. G. Lyons, and Robert J. Baker. 2016. "A Structural and Spectroscopic Study of the First Uranyl Selenocyanate, [Et4N]3[UO2(NCSe)5]" Inorganics 4, no. 1: 4. https://doi.org/10.3390/inorganics4010004