Synthesis of Diazonium Tetrachloroaurate(III) Precursors for Surface Grafting
Abstract
:1. Introduction
2. Results and Discussion
2.1. Synthesis and Characterization
2.2. X-ray Structure
Empirical formula | C12H17AuCl4N2 |
---|---|
Formula weight | 528.04 |
Temperature, K | 173(2) |
Wavelength, Å | 0.71073 |
Crystal system | Monoclinic |
Space group | P21/c |
a (Å); ( ° ) | 15.5144(3) |
b (Å); ( ° ) | 38.4270(8) 90.0250(10) |
c (Å); ( ° ) | 8.7773(2) |
Volume, Å3 | 5232.78(19) |
Z | 12 |
Density (cal.), Mg/m3 | 2.011 |
Abs. coefficient, mm−1 | 21.395 |
GOF on F2 | 1.061 |
R1, wR2 [I > 2σ(I)] | 0.0568, 0.1530 |
2.3. Thermal Stability and Residual Gas Analysis Studies
Gas | Partial pressure | Gas | Partial pressure |
---|---|---|---|
N2 | 2.60 × 10−7 | Cl2 | 1.08 × 10−11 |
CH3F | 9.10 × 10−1° | C6H5Cl | 6.47 × 10−12 |
CH2Cl2 | 5.47 × 10−1° | C6H5F | 5.21 × 10−12 |
CHCl3 | 2.90 × 10−11 | CCl4 | 4.29 × 10−12 |
CF4 | 1.10 × 10−11 |
3. Experimental Section
3.1. General Procedures
3.2. Physical Measurements
3.3. Thermogravimetric Analysis and Residual Gas Analysis
3.4. X-ray Diffraction
3.5. Syntheses
4. Conclusions
Acknowledgments
Conflicts of Interest
References
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Neal, S.N.; Orefuwa, S.A.; Overton, A.T.; Staples, R.J.; Mohamed, A.A. Synthesis of Diazonium Tetrachloroaurate(III) Precursors for Surface Grafting. Inorganics 2013, 1, 70-84. https://doi.org/10.3390/inorganics1010070
Neal SN, Orefuwa SA, Overton AT, Staples RJ, Mohamed AA. Synthesis of Diazonium Tetrachloroaurate(III) Precursors for Surface Grafting. Inorganics. 2013; 1(1):70-84. https://doi.org/10.3390/inorganics1010070
Chicago/Turabian StyleNeal, Sabine N., Samuel A. Orefuwa, Atiya T. Overton, Richard J. Staples, and Ahmed A. Mohamed. 2013. "Synthesis of Diazonium Tetrachloroaurate(III) Precursors for Surface Grafting" Inorganics 1, no. 1: 70-84. https://doi.org/10.3390/inorganics1010070