Next Article in Journal
Development of a Paper-Based Analytical Method for the Selective Colorimetric Determination of Bismuth in Water Samples
Next Article in Special Issue
Highly Dispersive Palladium Loading on ZnO by Galvanic Replacements with Improved Methane Sensing Performance
Previous Article in Journal
Portable, Disposable, Biomimetic Electrochemical Sensors for Analyte Detection in a Single Drop of Whole Blood
Previous Article in Special Issue
The Effect of Thin Film Fabrication Techniques on the Performance of rGO Based NO2 Gas Sensors at Room Temperature
 
 
Search for Articles:
Title / Keyword
Author / Affiliation / Email
Journal
Article Type
 
 
Advanced Search
 
Section
Special Issue
Volume
Issue
Number
Page
 
Journals
Chemosensors
Volume 10
Issue 7
10.3390/chemosensors10070264
chemosensors-logo
Submit to this Journal Review for this Journal Propose a Special Issue
► Article Menu

Article Menu

share Share announcement Help format_quote Cite question_answer Discuss in SciProfiles thumb_up
...
Endorse textsms
...
Comment
first_page
settings
Order Article Reprints
Font Type:
Arial Georgia Verdana
Font Size:
Aa Aa Aa
Line Spacing:
Column Width:
Background:
Article

Gas Sensitive Characteristics of Polyaniline Decorated with Molybdenum Ditelluride Nanosheets

by
Xinpeng Chen
,
Xiangdong Chen
*,
Xing Ding
* and
Xiang Yu
School of Information Science and Technology, Southwest Jiaotong University, Chengdu 610097, China
*
Authors to whom correspondence should be addressed.
Chemosensors 2022, 10(7), 264; https://doi.org/10.3390/chemosensors10070264
Submission received: 26 May 2022 / Revised: 29 June 2022 / Accepted: 4 July 2022 / Published: 6 July 2022
(This article belongs to the Special Issue Advanced Nanomaterials for Flexible and Wearable Chemo- and Bio- Sensors)
Browse Figures
Versions Notes

Abstract

:
In this work, hydrochloric acid (HCl)-doped molybdenum ditelluride (MoTe2) nanosheets/polyaniline (PANI) nanofiber composites are prepared by in situ chemical oxidation polymerization, and then the composites are deposited on interdigital electrodes (IDEs) to fabricate a NH3 gas sensor. Morphological analysis of the composites reveals that the PANI fibers are deposited on 2D MoTe2 sheets, showing a porous mesh microstructure structure with a more continuous distribution of PANI layer. FTIR spectrum analysis indicates the interaction between the MoTe2 nanosheets and the PANI in the MoTe2/PANI composites. The results demonstrate that the as-prepared MoTe2/PANI composites exhibit higher response than the pure PANI, in particular, the 8 wt.% MoTe2/PANI composites display about 4.23 times enhancement in response value toward 1000 ppm NH3 gas compared with the pure PANI. The enhanced NH3 gas-sensitive properties may be due to the increasing surface area of MoTe2/PANI composite films and the possible interaction of the P-N heterojunctions formed between PANI and the 2H-MoTe2 nanosheets.

1. Introduction

Ammonia (NH3) gas is widely used in the chemical industry, light industry, chemical fertilizer and pharmaceutical industries [1]. No matter the field, be it air quality monitoring or health care, it is imperative to the real-time detection of NH3 gas.
Among the large number of NH3 gas-sensitive materials, polyaniline (PANI), as a member of conducting polymer family, has been widely studied due to its operation at room temperature; ease of processing; and unique, simple and reversible acid/base doping/dedoping chemistry [2,3]. However, as a gas sensitive material, PANI has some drawbacks, such as relatively low sensitivity and long response/recovery time, which seriously affect its practical application in NH3 gas sensors [4,5,6]. In order to further improve the performance of PANI-based NH3 gas sensors, a number of works on PANI incorporated with various materials (e.g., metal oxide [7], metallic nanoparticles [8], carbon nanotubes [9], graphene [4,10], MXene [11] and TMDs [12], etc.) have been reported.
Among the above materials, transition metal dichalcogenides (TMDs), such as MoS2, WS2, MoSe2 and MoTe2, have received considerable attention in the field of chemical sensors owing to their unique structural and electrical properties, such as high specific surface area and surface energy level [13,14,15,16]. Jha et al. [12] reported WS2/PANI composite-based sensors with enhanced sensitivity and selectivity toward NH3 gas at room temperature. Liu et al. [17] presented a porous polyaniline/tungsten disulfide (PANI/WS2) nanocomposite film for the detection of NH3 gas at ppm level. Zhang et al. [18] synthesized polyaniline/multiwall carbon nanotubes/molybdenum disulfide ternary nanocomposites (PANI/MWCNTs/MoS2) and PANI/MoS2 binary nanocomposites for NH3 gas sensing under room temperature, respectively.
As one of the promising TMDs materials, the MoTe2 lattice has a three-layer structure, in which a hexagonal plane of Mo atoms is sandwiched between two separate hexagonal planes composed of Te atoms, and each layer is bonded together by weak Van der Waals force [19,20]. Iman Shackery et al. [21] reported a gas sensor based on α-MoTe2 with a back-to-back diode structure, and response tests to NH3 gas and NO2 gas showed that this type of sensor has a better response performance for NH3 gas than it does for NO2 gas, which suggested that MoTe2 could be a candidate for NH3 gas sensing applications. Feng et al. [16] developed a field-effect tube (FET) gas sensor based on MoTe2 flakes (thickness about 6.5 nm) and tested its sensitive properties to NH3 gas and NO2 gas; the results show that the detection sensitivity of MoTe2 for NH3 is higher than that of NO2 and the recovery time in NH3 gas is shorter than that in NO2 gas. However, the more complicated preparation process and the weaker output signal limit the further application of these devices.
Compared to other TMDs, MoTe2 has a larger bond length, lower binding energy and a narrower band gap (about 1.0 eV), which is more favorable for the adsorption of gas molecules [17,22]. Meanwhile, the two crystal structures of MoTe2, 2H (hexagonal) as a semiconductor and 1T’ (distorted octahedral) as a metal type [22], make it beneficial to employ the synergistic effect between multiple materials to facilitate enhanced gas-sensitive properties when incorporated with other materials [15,22]. Moreover, the MoTe2 nanosheet is a 2D material and the flexible PANI is incorporated with the 2D material, so that the 2D material can act as a structural support, thus avoiding the excessive stacking of the PANI matrix and facilitating the formation of a larger contact area with analyte molecules [10]. However, there are few reports of PANI incorporated with MoTe2 for NH3 gas sensor.
In the present work, MoTe2/PANI composites are prepared by a simple in situ chemical oxidative polymerization of aniline on N type 2H-MoTe2 nanosheets. Then, NH3 gas sensors are formed by coating the MoTe2/PANI composites films onto the gold interdigital electrodes (IDE). The experimental results show that the NH3 gas-sensitive properties of the PANI based composites are further enhanced after being hybridized with MoTe2. Finally, the possible sensitive mechanism of the prepared sensor toward NH3 gas is proposed in detail.

2. Experimental

2.1. Materials and Reagents

An N type 2H-MoTe2 nanosheets dispersion (0.5 mg/mL) was purchased from Nanjing MKNANO Tech. Co., Ltd (Nanjing, China). Aniline monomers, ammonium persulfate (APS), hydrochloride (HCl) and ethanol were purchased from Chengdu Kelong Chemical Reagents Co., Ltd. (Chengdu, China). All materials and reagents used in the experiment were analytical grade without further treatment, except for aniline monomers, which were purified by reduced pressure distillation before use. Deionized (DI) water (18.2 MΩ cm resistivity, Milli-Q) was used in the experiments.

2.2. Synthesis of MoTe2/PANI Composites

MoTe2/PANI composites were synthesized by an in situ oxidative polymerization method, which was reported in our previous work [23]. In this typical process, a 30 mL MoTe2 nanosheet dispersion, 0.2 mL (0.002 mol) aniline monomer and 8.3 mL (1 M) HCl solution were mixed with 50 mL DI water and sonicated for 0.5 h. Then the mixture was transferred to an ice bath (0–5 °C) with continuous magnetic stirring. After that, 0.465 g APS (0.002 mol) was dissolved in 20 mL DI water and gradually dropped into the above mixture. Subsequently, the polymerization reaction occurred. The mixture was kept for 15 h at 0–5 °C and the MoTe2/PANI composites was obtained, showing a dark green color. Next, the obtained precipitate was filtered and rinsed with DI water and ethanol for several times, then dried in a vacuum oven at 25 °C for 24 h. A part of the precipitate was collected for characterization.
For comparison, the pure PANI and MoTe2/PANI composites with the various volumes of nanosheet dispersion (5 mg and 60 mg) were synthesized utilizing the same process. For the prepared MoTe2/PANI composites, the mass ratios of MoTe2 nanosheets (5 mg, 15 mg and 30 mg) to PANI were calculated to be 2.7 wt.%, 8 wt.% and 16 wt.%, respectively.

2.3. Characterization

The surface microstructure and morphology of the as-synthesized materials was elucidated via scanning electron microscopy (FE-SEM, GeminiSEM 300, ZEISS company, Oberkochen, Baden-Württemberg, Germany) and high-resolution transmission electron microscopy (HRTEM, JEM1200EX, JEOL company, Tokyo, Japan). Fourier transform infrared spectra (FTIR) of the as-synthesized materials were recorded on a PerkinElmer Frontier spectrometer with the samples were dispersed and pressed with KBr pellets over the wavenumber range of 400–4000 cm−1 at room temperature.

2.4. Fabrication of NH3 Gas Sensor

The NH3 gas sensor was fabricated by coating the as-synthesized sensitive materials on gold interdigital electrodes. The specific fabrication process is a two-step process as follows:
The first step was to fabricate the gold interdigital electrodes. First, a layer (300 nm) of SiO2 film was thermally grown on the silicon wafer as a passivation layer. A layer (100 nm) of titanium (Ti) layer and a layer (100 nm) of gold (Au) were successively deposited on the SiO2 passivation layer by magnetron sputtering, in which the Ti layer played a role in enhancing the adhesion between the SiO2 passivation layer and the Au electrode. Subsequently, a layer of photoresistance is applied to the silicon wafer and the interdigitated electrode pattern was photo-lithographically defined by using the mask. Each interdigital electrode was composed of 10 pairs of fingers with 25 μm width and 25 μm gaps, and the size of electrodes area was 4 mm × 6 mm. After the developing and wet etching processes, the silicon wafers containing gold interdigitated electrodes were obtained. Finally, the silicon wafer was then diced into individual chips. Before the deposition of sensitive materials, gold interdigitated electrodes were successively rinsed with DI water and ethanol and dried in a vacuum desiccator at room temperature for 24 h.
The second step was to apply the sensitive materials to the gold interdigitated electrodes. First, the as-synthesized MoTe2/PANI composites and pure PANI were, respectively, dispersed ultrasonically into a mixture of DI water and ethanol (1 mg/mL) for 15 min to obtain stable suspension. Then, 4 microliters (μL) of the MoTe2/PANI composites, PANI suspension and MoTe2 Nanosheets dispersion were, respectively, applied onto the interdigitated electrodes by the drop-coating method using a micropipette. Finally, the well-coated interdigitated electrodes were dried in a vacuum desiccator at room temperature for 3 h to obtain the gas sensors.
In order to investigate a possible synergies interaction between the P type PANI and N type MoTe2 nanosheets in the MoTe2/PANI composites, a layered heterostructured sensor composed of 2H-MoTe2 nanosheet films and PANI films was fabricated by sequentially apply the N type 2H-MoTe2 nanosheets dispersion and PANI dispersion onto the channel and electrode of the planar electrode, as shown schematically in Figure 1.

2.5. Gas-Sensing Test

A gas-sensing test was carried out by exposing the sensors to various concentrations of NH3 gas under laboratory conditions (62.7 ± 3% RH, 22 ± 2 °C). The NH3 gas sensing measurement systems used in this work was described in our previous study [23]. The sensor was placed in a test chamber (1 L in volume) with an inlet and an outlet. Standard NH3 gas (10,000 ppm, N2 was used as the balance gas) was purchased from NIMTT (Chengdu, China). Various NH3 gas concentration (ranging from 10 ppm to 1000 ppm) environments were achieved by regulating a mass flow system consisting of a 5 SCCM and a 500 SCCM mass flowmeters. Clean air was used to clear the residual NH3 gas in the test chamber before and after the gas-sensing test. The resistance of the sensor was monitored and measured in real time by a digital multimeter (34461A, Keysight company, Cleveland, OH, USA), which was connected to a computer via the USB interface for data acquisition, and the resistance was recorded at a rate of once every 500 milliseconds. The current–voltage (I-V) characteristics of sensor are measured with a computerized source meter (Keithley 2400, Tektronix, Beaverton, OR, USA).
The response value (S) of the sensor is defined as:
S = R R 0 = R 1 − R 0 R 0
where R1 and R0 are the resistance of the sensor when exposed to the given concentration of NH3 gas and the clean air, respectively. The response times and recovery times of the sensor are calculated as the times to attain 90% of total resistance change.

3. Results and Discussion

3.1. The Characterization of Morphology and Microstructure

SEM images of pure PANI, MoTe2 nanosheets and MoTe2/PANI composites are shown in Figure 2a–c, respectively. High-resolution SEM image of MoTe2/PANI composites (100 nm scale) is shown in Figure 2d. As can be seen in Figure 2b, it is clear that a large number of 2D layered sheets with sizes of tens to hundreds of nanometers stack together. In Figure 2a,c, it can be found that both of pure PANI and MoTe2/PANI composites exhibit an interconnected mesh nanofiber morphology. However, it can also be clearly seen in the SEM images of MoTe2/PANI composites in Figure 2c,d that the PANI fibers are covered and deposited on the lamellar MoTe2 nanosheets, which indicates that there is good contact between PANI nanofibers and MoTe2 nanosheets, facilitating the formation of interactions between different components at interface. On the other hand, compared to the microstructure of pure PANI in Figure 2a, the deposition of PANI fibers on 2D nanosheets in the MoTe2/PANI composites reduces the stacking in the vertical direction and expands the distribution area in the planar direction, resulting in a relatively more uniform distribution of PANI layers. For the application of gas-sensitive materials, this microstructure facilitates a further increase in the contact area with the gas molecules, thus achieving a further improvement in gas-sensitive properties [10].
HRTEM images of pure PANI, MoTe2 nanosheets and MoTe2/PANI composites are shown in Figure 3a–c, respectively. The lamellar structure of MoTe2 nanosheets with a size of about several hundred nanometers can be clearly observed in Figure 3b; the reticulated structural morphology of PANI nanofibers with the diameter of about several tens of nanometers can be observed in Figure 3a; the PANI nanofibers with the reticulated structural morphology can also be clearly observed in Figure 3c; however, compared with Figure 3a, the PANI nanofibers in Figure 3c are deposited on the lamellar MoTe2 nanosheets, and the MoTe2 nanosheets are well distributed without obvious agglomeration. This difference in microstructure morphology is also consistent with SEM characterization in Figure 2a–c above, which suggests a better spatial distribution uniformity of PANI layers in the MoTe2/PANI composites.

3.2. FTIR Analysis

The FTIR spectrum of MoTe2 nanosheets, pure PANI and 8 wt.% MoTe2/PANI composites are shown in Figure 4. The FTIR spectra of 8 wt.% MoTe2/PANI composites, as well as MoTe2 nanosheets, show a similar characteristic peak, both around 669.5 cm−1, which is attributed to the vibration of the Mo–Te bond [22]. For pure PANI, the characteristic peak at 795.9 cm−1 corresponds to the out-of-plane bending vibration of C-H bond of the para-aromatic ring, the characteristic peak at 1113.2 cm−1 is attributed to the in-plane bending vibration of C-H bond, the characteristic peak at 1241.4 cm−1 corresponds to stretching vibration of C≡N bond of aromatic secondary amine and the characteristic peak at 1296.8 cm−1 is ascribed to the stretching vibration of the C-N bond, the characteristic peaks at 1484.4 cm−1 and 1567.8 cm−1 are assigned to stretching vibration of C=C bond and stretching vibration of C=N of quinoid ring, respectively [10,24,25,26,27]. All these main characteristic peaks above can be observed in the FTIR spectrum of 8 wt.% MoTe2/PANI composites with similar peaks, which further confirms that the PANI component in both pure PANI and MoTe2/PANI composites prepared in this work exist in the form of the highly conductive emeraldaniline salt [26,28]. Moreover, the main characteristic peaks of doped PANI observed in the FTIR spectrum of 8 wt.% MoTe2/PANI composites have slight shifts compared to the position of pure PANI, which indicates the interaction between the MoTe2 nanosheets and the PANI matrix in the MoTe2/PANI composites [28,29].

3.3. NH3 Gas Sensing Properties

3.3.1. Gas Response

The sensor response to NH3 gas is achieved by switching the response/recovery cycle between different concentrations of NH3 gas and air. The transient resistance variation of the sensors toward NH3 gas varied from 10 to 1000 ppm are shown in Figure 5. It can be observed that the resistance value of the sensor based on pure MoTe2 nanosheets shows hardly any significant changes when exposed to various concentrations of NH3 gas. However, the resistance values of sensors based on pure PANI and MoTe2/PANI composites increase rapidly with increasing NH3 gas concentrations and gradually reach to saturation, and then return to the approximate baseline state after the test chamber is refilled with air in each response/recovery cycle. Specifically, when the concentration of NH3 gas is varied from 0 to 1000 ppm, the resistance of the MoTe2/PANI composites sensors changes from 1.19 Kohm to 66.8 Kohm (2.7 wt.% MoTe2/PANI composites composites), 27.7 Kohm to 2961.1 Kohm (8 wt % MoTe2/PANI composites), 1.87 Kohm to 148.1 Kohm (16 wt.% MoTe2/PANI composites) and the resistance of the pure PANI sensor changes from 5.34 Kohm to 141.1 Kohm.
Regarding the data in Figure 5, the response values of sensors prepared in this work toward different concentrations of NH3 gas are obtained and collected in Table 1, of which these response values are also demonstrated in Figure 6. Taking the response at a 1000 ppm concentration of NH3 gas as an example, the responses of 2.7 wt.% MoTe2/PANI composites, 8 wt.% MoTe2/PANI composites and 16 wt.% MoTe2/PANI composites sensors are 2.18, 4.23 and 3.11 times as much as those of pure PANI-based sensor, respectively. This result indicates that the response of MoTe2/PANI composites sensors toward NH3 gas have been significantly improved compared to that of a pure PANI sensor. This implies that enhanced response of the MoTe2/PANI composites toward NH3 gas has been achieved by the introduction of MoTe2 nanosheets.
The response data in Figure 6 also reveals the relationship between the number of MoTe2 nanosheets and the response of MoTe2/PANI composites sensors to NH3 gas to some extent. The response of MoTe2/PANI composites sensors to NH3 gas does not always increase with the increase of MoTe2 nanosheet amounts. When the mass ratio of MoTe2 nanosheets to PANI is about 8 wt.%, the MoTe2/PANI composites sensor has the maximum response to NH3 gas.

3.3.2. Response and Recovery Times

The dynamic response and recovery of the gas sensors based on pure PANI and MoTe2/PANI composites to 100 ppm concentration of NH3 gas are shown in Figure 7, respectively. It is estimated that the response times (T1) of the sensors based on pure PANI and MoTe2/PANI composites with various MoTe2 nanosheets amounts are about 36 s, 25 s, 26 s and 25 s, and the corresponding recovery times (T2) are about 27 s, 12 s, 24 s and 24 s, respectively (as shown in Table 2). It can be seen that the response times of MoTe2/PANI composites sensors are usually shorter than those of pure PANI sensors. Therefore, the addition of MoTe2 nanosheets into the PANI matrix can allow the composites sensitive film to exhibit a faster response/recovery speed. When combining the analysis of the morphology with the microstructure of MoTe2/PANI composites described in Section 3.1, the improvement in response/recovery times may be ascribed to the fact that the PANI nanofibers are covered and deposited on the lamellar MoTe2 nanosheets during the in situ polymerization process, resulting in a more continuous distribution and increased surface area. It provides more active sites for the adsorption of the NH3 gas molecules, thus accelerating the response/recovery rate and reducing the response/recovery times.
The NH3 gas-sensitive properties of the MoTe2/PANI composites sensor in this work in comparison with some NH3 gas sensors reported recently are summarized in Table 3.

3.3.3. Repeatability and Selectivity

In this work, repeatability and selectivity tests were carried out for the 8 wt.% MoTe2/PANI composites sensor. Figure 8a shows the response of the 8 wt.% MoTe2/PANI composites sensor when exposed to a 100 ppm concentration of NH3 gas for three repeated cycles; it can be found that there is no significant deviation during the cycle testing of the sensor, which indicates a good reproducibility of the sensor. Figure 8b shows the response of the 8 wt.% MoTe2/PANI composites sensor to 100 ppm concentrations of NH3 gas, methane (CH4), ethanol (C2H5OH), acetone (CH3COCH3), formaldehyde (CH2O), benzene (C6H6) and nitrogen dioxide (NO2), respectively. It is clear that the response of the 8 wt.% MoTe2/PANI composites sensor toward NH3 gas is significantly higher than that of the other gases measured.

3.3.4. Enhanced Mechanism for the Gas-Sensitive Response of MoTe2/PANI Composites

From the results obtained in Section 3.3.1, MoTe2 nanosheets do not show a significant response behavior to NH3 gas, but after compounding with PANI significantly enhance the NH3 gas-sensitive response of the MoTe2/PANI composites. This potential NH3 gas-sensitive mechanism is not fully understood, but these enhanced gas-sensitive properties may be due to the morphology of the composites and the synergistic interaction between the components of the composites.
According to the morphology and microstructure analysis of MoTe2/PANI composites, as discussed in Section 3.1, it is evident that the PANI nanofibers are polymerized on 2D MoTe2 nanosheets in the composites with the introduction of MoTe2 nanosheets. Moreover, due to the deposition of PANI nanofibers on 2D nanosheets in the composites, the stacking in the vertical direction is reduced and the distribution area in the planar direction is expanded, which provides a large number of active sites for the adsorption of NH3 gas molecules onto the composites films.
In order to further investigate the enhanced gas-sensitive mechanism of MoTe2/PANI composites, the characteristics of the layered heterostructured sensor is tested. The I-V characteristic curves of the layered heterostructured sensor when exposed to a 500 ppm concentration of NH3 gas are shown in Figure 9. It can be observed that the I-V characteristic curves of the layered heterostructured sensor exhibit non-ohmic characteristics and show a certain rectification behavior of a P-N heterojunction within the voltage range of −1~+1 V, which indicates a certain degree of heterojunction interaction between N-type 2H-MoTe2 nanosheets and P-type PANI [35,36]. This result is consistent with the observation of a certain degree of interaction between the MoTe2 nanosheets and the PANI in the FTIR spectrum in Section 3.2.
The formation of the heterojunction may be related to the energy level structure of the two materials (as shown in Figure 10). The positions of the lowest unoccupied molecular orbital (LUMO) and the highest occupied molecular orbital (HOMO) in PANI, as well as the positions of the conduction bands (Ec) and valence band (Ev) in the 2H-MoTe2 nanosheets and the positions of their Fermi energy levels relative to the vacuum energy levels, are shown in Figure 10. According to previous reports, the band gaps of PANI and 2H-MoTe2 are 2.8 Ev and 1.0 Ev, respectively [16,37]. When PANI nanofibers are polymerized and deposited on 2H-MoTe2 nanosheets, due to gradient difference in carrier concentrations at the interface between PANI and MoTe2 nanosheets, the majority carriers (holes) in PANI and the majority carriers (electrons) in 2H-MoTe2 nanosheets diffuse along their opposite directions until reaching an equilibrium at the Fermi energy level and P-N heterojunctions are subsequently formed at the interface between PANI and MoTe2 nanosheets [18,38]. When the MoTe2/PANI composites are exposed to NH3 gas, NH3 molecules capture protons from the composites, leading to a decrease in the doping concentrations of the PANI component in the composites, which not only results in an increase for the intrinsic resistance of PANI but also in a broadening of depletion layer of the P-N heterojunction. It may result in a further increase in the resistance of the composites, which enhances the NH3 gas-sensitive response of the MoTe2/PANI composites sensor [39].

4. Conclusions

MoTe2/PANI nanocomposites were prepared by in situ chemical oxidation polymerization and the NH3 gas sensor was assembled by using MoTe2/PANI nanocomposites combined with an IDE transducer. It was found that PANI nanofibers cover the lamellar MoTe2 nanosheets and form a porous mesh microstructure, which increases the surface area of PANI layer and provides more active sites for the adsorption of gas molecules. The sensitive characteristics of NH3 gas show that the MoTe2/PANI composites sensors have better response to NH3 gas over the concentration range of 10–1000 ppm than the pure PANI sensors. In particular, the 8 wt.% MoTe2/PANI composite sensor shows the highest response (4.23 times as much as the pure PANI sensor at 1000 ppm NH3 gas). The response of MoTe2/PANI nanocomposites is also faster than that of pure PANI sensors. Beyond the morphological and microstructure analysis of the MoTe2/PANI composites, the effect of introducing 2D MoTe2 nanosheets to the enhanced NH3 gas-sensitive properties of PANI is also discussed in this work in terms of the possible formation of P-N heterojunctions at the interface between MoTe2 nanosheets and PANI.

Author Contributions

X.C. (Xinpeng Chen): Conceptualization, methodology, investigation and writing—original draft and revising; X.C. (Xiangdong Chen): Conceptualization, funding acquisition, resources, supervision and writing—review and editing. X.D.: Provide help in improving the manuscript regarding format, language and figures; X.Y.: Provided help in improving the manuscript regarding format, language and figures. All authors have read and agreed to the published version of the manuscript.

Funding

This work was supported in part by the Key Project of National Natural Science Foundation of China (61731016), in part by Fundamental Research Funds for the Central Universities (2682022ZTPY001) and in part by the National Natural Science Foundation of China (61901399).

Institutional Review Board Statement

Not applicable.

Informed Consent Statement

Not applicable.

Data Availability Statement

The data presented in this study are available on request from the corresponding author. The data are not publicly available due to the laboratory confidentiality requirements.

Conflicts of Interest

The authors declare no conflict of interest.

References

  1. Li, X.; Li, T.; Ma, Y.; Wei, Q.; Qiu, W.; Guo, H.; Shi, X.; Zhang, P.; Asiri, A.M.; Chen, L.; et al. Boosted electrocatalytic N2 reduction to NH3 by defect-rich MoS2 nanoflower. Adv. Energy Mater. 2018, 8, 1801357. [Google Scholar] [CrossRef]
  2. Virji, S.; Huang, J.; Kaner, R.B.; Weiller, B.H. Polyaniline nanofiber gas sensors: Examination of response mechanisms. Nano Lett. 2004, 4, 491–496. [Google Scholar] [CrossRef]
  3. Matsuguchi, M.; Io, J.; Sugiyama, G.; Sakai, Y. Effect of NH3 gas on the electrical conductivity of polyaniline blend films. Synth. Met. 2002, 128, 15–19. [Google Scholar] [CrossRef]
  4. Bai, S.; Zhao, Y.; Sun, J.; Tian, Y.; Luo, R.; Li, D.; Chen, A. Ultrasensitive room temperature NH3 sensor based on a graphene–polyaniline hybrid loaded on PET thin film. Chem. Commun. 2015, 51, 7524–7527. [Google Scholar] [CrossRef]
  5. Wang, T.; Guo, Y.; Wan, P.; Zhang, H.; Chen, X.; Sun, X. Flexible transparent electronic gas sensors. Small 2016, 12, 3748–3756. [Google Scholar] [CrossRef]
  6. Li, X.; Xu, J.; Jiang, Y.; He, Z.; Liu, B.; Xie, H.; Li, H.; Li, Z.; Wang, Y.; Tai, H. Toward agricultural ammonia volatilization monitoring: A flexible polyaniline/Ti3C2Tx hybrid sensitive films based gas sensor. Sens. Actuators B Chem. 2020, 316, 128144. [Google Scholar] [CrossRef]
  7. Kulkarni, S.; Navale, Y.; Navale, S.; Stadler, F.; Ramgir, N.; Patil, V. Hybrid polyaniline-WO3 flexible sensor: A room temperature competence towards NH3 gas. Sens. Actuators B Chem. 2019, 288, 279–288. [Google Scholar] [CrossRef]
  8. Hien, H.T.; Giang, H.T.; van Hieu, N.; Trung, T.; van Tuan, C. Elaboration of Pd-nanoparticle decorated polyaniline films for room temperature NH3 gas sensors. Sens. Actuators B Chem. 2017, 249, 348–356. [Google Scholar] [CrossRef]
  9. Abdulla, S.; Mathew, T.L.; Pullithadathil, B. Highly sensitive, room temperature gas sensor based on polyaniline-multiwalled carbon nanotubes (PANI/MWCNTs) nanocomposite for trace-level ammonia detection. Sens. Actuators B Chem. 2015, 221, 1523–1534. [Google Scholar] [CrossRef]
  10. Wu, Z.; Chen, X.; Zhu, S.; Zhou, Z.; Yao, Y.; Quan, W.; Liu, B. Enhanced sensitivity of ammonia sensor using graphene/polyaniline nanocomposite. Sens. Actuators B Chem. 2013, 178, 485–493. [Google Scholar] [CrossRef]
  11. Wang, S.; Jiang, Y.; Liu, B.; Duan, Z.; Pan, H.; Yuan, Z.; Xie, G.; Wang, J.; Fang, Z.; Tai, H. Ultrathin Nb2CTx nanosheets-supported polyaniline nanocomposite: Enabling ultrasensitive NH3 detection. Sens. Actuators B Chem. 2021, 343, 130069. [Google Scholar] [CrossRef]
  12. Jha, R.K.; Wan, M.; Jacob, C.; Guha, P.K. Ammonia vapour sensing properties of in situ polymerized conducting PANI-nanofiber/WS2 nanosheet composites. New J. Chem. 2018, 42, 735–745. [Google Scholar] [CrossRef]
  13. Li, X.; Li, X.; Li, Z.; Wang, J.; Zhang, J. WS2 nanoflakes based selective ammonia sensors at room temperature. Sens. Actuators B Chem. 2017, 240, 273–277. [Google Scholar] [CrossRef]
  14. Perkins, F.K.; Friedman, A.L.; Cobas, E.; Campbell, P.; Jernigan, G.; Jonker, B.T. Chemical vapor sensing with monolayer MoS2. Nano Lett. 2013, 13, 668–673. [Google Scholar] [CrossRef] [PubMed]
  15. Late, D.J.; Doneux, T.; Bougouma, M. Single-layer MoSe2 based NH3 gas sensor. Appl. Phys. Lett. 2014, 105, 233103. [Google Scholar] [CrossRef]
  16. Feng, Z.; Xie, Y.; Chen, J.; Yu, Y.; Zheng, S.; Zhang, R.; Li, Q.; Chen, X.; Sun, C.; Zhang, H.; et al. Highly sensitive MoTe2 chemical sensor with fast recovery rate through gate biasing. 2D Mater. 2017, 4, 025018. [Google Scholar] [CrossRef]
  17. Liu, G.; Zhou, Y.; Zhu, X.; Wang, Y.; Ren, H.; Wang, Y.; Gao, C.; Guo, Y. Humidity enhanced ammonia sensing of porous polyaniline/tungsten disulfide nanocomposite film. Sens. Actuators B Chem. 2020, 323, 128699. [Google Scholar] [CrossRef]
  18. Zhang, D.; Wu, Z.; Li, P.; Zong, X.; Dong, G.; Zhang, Y. Facile fabrication of polyaniline/multi-walled carbon nanotubes/molybdenum disulfide ternary nanocomposite and its high-performance ammonia-sensing at room temperature. Sens. Actuators B Chem. 2018, 258, 895–905. [Google Scholar] [CrossRef]
  19. Qiu, L.; Wei, Y.; Pol, V.G.; Gedanken, A. Synthesis of α-MoTe2 nanorods via annealing te-seeded amorphous MoTe2 particles. Inorg. Chem. 2004, 43, 6061–6066. [Google Scholar] [CrossRef]
  20. Panigrahi, P.; Hussain, T.; Karton, A.; Ahuja, R. Elemental substitution of two-dimensional transition metal dichalcogenides (MoSe2 and MoTe2): Implications for enhanced gas sensing. ACS Sens. 2019, 4, 2646–2653. [Google Scholar] [CrossRef]
  21. Cho, S.; Kim, S.; Kim, J.H.; Zhao, J.; Seok, J.; Keum, D.H.; Baik, J.; Choe, D.H.; Chang, K.J. Phase patterning for ohmic homojunction contact in MoTe2. Science 2015, 349, 625–628. [Google Scholar] [CrossRef] [PubMed]
  22. He, H.Y.; He, Z.; Shen, Q. One-pot synthesis of non-precious metal RGO/1T′-MoTe2: Cu heterohybrids for excellent catalytic hydrogen evolution. Mater. Sci. Eng. B 2020, 260, 114659. [Google Scholar] [CrossRef]
  23. Chen, X.; Chen, X.; Ding, X.; Yu, X.; Yu, X. Gas-sensitive enhancement of rGO/HMWCNTs/PANI ternary composites. IEEE Sens. J. 2021, 22, 1905–1915. [Google Scholar] [CrossRef]
  24. Trchová, M.; Šeděnková, I.; Tobolková, E.; Stejskal, J. FTIR spectroscopic and conductivity study of the thermal degradation of polyaniline films. Polym. Degrad. Stab. 2004, 86, 179–185. [Google Scholar] [CrossRef]
  25. Yan, C.; Zou, L.; Short, R. Single-walled carbon nanotubes and polyaniline composites for capacitive deionization. Desalination 2012, 290, 125–129. [Google Scholar] [CrossRef]
  26. Ginic-Markovic, M.; Matisons, J.G.; Cervini, R.; Simon, G.P.; Fredericks, P.M. Synthesis of new polyaniline/nanotube composites using ultrasonically initiated emulsion polymerization. Chem. Mater. 2006, 18, 6258–6265. [Google Scholar] [CrossRef]
  27. Gavgani, J.N.; Hasani, A.; Nouri, M.; Mahyari, M.; Salehi, A.J.S. Highly sensitive and flexible ammonia sensor based on S and N co-doped graphene quantum dots/polyaniline hybrid at room temperature. Sens. Actuators B Chem. 2016, 229, 239–248. [Google Scholar] [CrossRef]
  28. Fan, H.; Zhao, N.; Wang, H.; Xu, J.; Pan, F. 3D conductive network-based free-standing PANI–RGO–MWNTs hybrid film for high-performance flexible supercapacitor. J. Mater. Chem. A 2014, 2, 12340–12347. [Google Scholar] [CrossRef]
  29. Saini, P.; Choudhary, V.; Singh, B.P.; Mathur, R.B.; Dhawan, S.K. Polyaniline–MWCNT nanocomposites for microwave absorption and EMI shielding. Mater. Chem. Phys. 2009, 113, 919–926. [Google Scholar] [CrossRef]
  30. Andre, R.S.; Shimizu, F.M.; Miyazaki, C.M.; Riul, A., Jr.; Manzani, D.; Ribeiro, S.J.; Oliveira, O.N., Jr.; Mattoso, L.H.; Correa, D.S. Hybrid layer-by-layer (LbL) films of polyaniline, graphene oxide and zinc oxide to detect ammonia. Sens. Actuators B Chem. 2017, 238, 795–801. [Google Scholar] [CrossRef] [Green Version]
  31. Bandgar, D.K.; Navale, S.T.; Navale, Y.H.; Ingole, S.M.; Stadler, F.J.; Ramgir, N.; Aswal, D.K.; Gupta, S.K.; Mane, R.S.; Patil, V.B. Flexible camphor sulfonic acid-doped PAni/α-Fe2O3 nanocomposite films and their room temperature ammonia sensing activity. Mater. Chem. Phys. 2017, 189, 191–197. [Google Scholar] [CrossRef] [Green Version]
  32. Kulkarni, S.B.; Navale, Y.H.; Navale, S.T.; Ramgir, N.S.; Debnath, A.K.; Gadkari, S.C.; Gupta, S.K.; Aswal, D.K.; Patil, V.B. Enhanced ammonia sensing characteristics of tungsten oxide decorated polyaniline hybrid nanocomposites. Org. Electron. 2017, 45, 65–73. [Google Scholar] [CrossRef]
  33. Tohidi, S.; Parhizkar, M.; Bidadi, H.; Mohamad-Rezaei, R.J.N. High-performance chemiresistor-type NH3 gas sensor based on three-dimensional reduced graphene oxide/polyaniline hybrid. Nanotechnology 2020, 31, 415501. [Google Scholar] [CrossRef]
  34. Wang, S.; Liu, B.; Duan, Z.; Zhao, Q.; Zhang, Y.; Xie, G.; Jiang, Y.; Li, S.; Tai, H. PANI nanofibers-supported Nb2CTx nanosheets-enabled selective NH3 detection driven by TENG at room temperature. Sens. Actuators B Chem. 2021, 327, 128923. [Google Scholar] [CrossRef]
  35. Gong, J.; Li, Y.; Hu, Z.; Zhou, Z.; Deng, Y. Ultrasensitive NH3 gas sensor from polyaniline nanograin enchased TiO2 fibers. J. Phys. Chem. C 2010, 114, 9970–9974. [Google Scholar] [CrossRef]
  36. Rigoni, F.; Drera, G.; Pagliara, S.; Perghem, E.; Pintossi, C.; Goldoni, A.; Sangaletti, L. Gas sensing at the nanoscale: Engineering SWCNT-ITO nano-heterojunctions for the selective detection of NH3 and NO2 target molecules. Nanotechnology 2016, 28, 035502. [Google Scholar] [CrossRef]
  37. Qin, Y.; Wang, L.; Wang, X. A high performance sensor based on PANI/ZnTi-LDHs nanocomposite for trace NH3 detection. Org. Electron. 2019, 66, 102–109. [Google Scholar] [CrossRef]
  38. Xie, Y.; Wu, E.; Zhang, J.; Hu, X.; Zhang, D.; Liu, J. Gate-tunable photodetection/voltaic device based on BP/MoTe2 heterostructure. ACS Appl. Mater. Interfaces 2019, 11, 14215–14221. [Google Scholar] [CrossRef]
  39. Zhang, D.; Wu, Z.; Zong, X. Metal-organic frameworks-derived zinc oxide nanopolyhedra/S, N: Graphene quantum dots/polyaniline ternary nanohybrid for high-performance acetone sensing. Sens. Actuators B Chem. 2019, 288, 232–242. [Google Scholar] [CrossRef]
Chemosensors 10 00264 g001 550
Figure 1. Schematic diagram of the layered heterostructured sensor device composed of 2H-MoTe2 film and PANI film.
Figure 1. Schematic diagram of the layered heterostructured sensor device composed of 2H-MoTe2 film and PANI film.
Chemosensors 10 00264 g001
Chemosensors 10 00264 g002 550
Figure 2. SEM images of (a) pure PANI, (b) MoTe2 nanosheets, (c) MoTe2/PANI nanocomposites; (d) high-resolution SEM image of MoTe2/PANI nanocomposites (100 nm scale).
Figure 2. SEM images of (a) pure PANI, (b) MoTe2 nanosheets, (c) MoTe2/PANI nanocomposites; (d) high-resolution SEM image of MoTe2/PANI nanocomposites (100 nm scale).
Chemosensors 10 00264 g002
Chemosensors 10 00264 g003 550
Figure 3. High-resolution TEM (HRTEM) images of (a) pure PANI, (b) MoTe2 nanosheets, (c) MoTe2/PANI nanocomposites (200 nm scale); (d) HRTEM image of MoTe2/PANI nanocomposites (50 nm scale).
Figure 3. High-resolution TEM (HRTEM) images of (a) pure PANI, (b) MoTe2 nanosheets, (c) MoTe2/PANI nanocomposites (200 nm scale); (d) HRTEM image of MoTe2/PANI nanocomposites (50 nm scale).
Chemosensors 10 00264 g003
Chemosensors 10 00264 g004 550
Figure 4. FTIR spectrum of MoTe2 nanosheets, pure PANI and MoTe2/PANI nanocomposites.
Figure 4. FTIR spectrum of MoTe2 nanosheets, pure PANI and MoTe2/PANI nanocomposites.
Chemosensors 10 00264 g004
Chemosensors 10 00264 g005 550
Figure 5. Transient resistance of gas sensors based on (a) pure MoTe2 nanosheets, (b) pure PANI, (c) 2.7 wt.% MoTe2/PANI composites, (d) 8 wt.% MoTe2/PANI composites and (e) 16 wt.% MoTe2/PANI composites when exposed to various concentrations of NH3 gas in a laboratory environment.
Figure 5. Transient resistance of gas sensors based on (a) pure MoTe2 nanosheets, (b) pure PANI, (c) 2.7 wt.% MoTe2/PANI composites, (d) 8 wt.% MoTe2/PANI composites and (e) 16 wt.% MoTe2/PANI composites when exposed to various concentrations of NH3 gas in a laboratory environment.
Chemosensors 10 00264 g005
Chemosensors 10 00264 g006 550
Figure 6. Response of pure PANI sensor and MoTe2/PANI composites sensors as a function of NH3 gas concentration at laboratory environment.
Figure 6. Response of pure PANI sensor and MoTe2/PANI composites sensors as a function of NH3 gas concentration at laboratory environment.
Chemosensors 10 00264 g006
Chemosensors 10 00264 g007 550
Figure 7. Dynamic response–recovery curves of gas sensors based on (a) the pure PANI, (b) 2.7 wt.% MoTe2/PANI composites, (c) 8 wt.% MoTe2/PANI composites and (d) 16 wt.% MoTe2/PANI composites when exposed to a 100 ppm concentration of NH3 gas in a laboratory environment.
Figure 7. Dynamic response–recovery curves of gas sensors based on (a) the pure PANI, (b) 2.7 wt.% MoTe2/PANI composites, (c) 8 wt.% MoTe2/PANI composites and (d) 16 wt.% MoTe2/PANI composites when exposed to a 100 ppm concentration of NH3 gas in a laboratory environment.
Chemosensors 10 00264 g007
Chemosensors 10 00264 g008 550
Figure 8. (a) Repeatability and (b) selectivity of 8 wt.% MoTe2/PANI composites gas sensor.
Figure 8. (a) Repeatability and (b) selectivity of 8 wt.% MoTe2/PANI composites gas sensor.
Chemosensors 10 00264 g008
Chemosensors 10 00264 g009 550
Figure 9. I-V characteristic curve of the layered heterostructured sensor composed of 2H-MoTe2 film and PANI film when exposed to exposed to a 500 ppm concentration of NH3 gas.
Figure 9. I-V characteristic curve of the layered heterostructured sensor composed of 2H-MoTe2 film and PANI film when exposed to exposed to a 500 ppm concentration of NH3 gas.
Chemosensors 10 00264 g009
Chemosensors 10 00264 g010 550
Figure 10. Schematic diagram of band structure at the interface between MoTe2 nanosheets and PANI nanofibers of MoTe2/PANI composites.
Figure 10. Schematic diagram of band structure at the interface between MoTe2 nanosheets and PANI nanofibers of MoTe2/PANI composites.
Chemosensors 10 00264 g010
Table
Table 1. The response values of sensors prepared in this work regarding NH3 gas.
Table 1. The response values of sensors prepared in this work regarding NH3 gas.
NH3 Gas Concentration Response10 ppm25 ppm50 ppm100 ppm200 ppm500 ppm1000 ppm
pure PANI0.481.241.693.156.9114.1225.01
2.7 wt.% MoTe2/PANI composites0.761.191.997.1617.1233.954.44
8 wt.% MoTe2/PANI composites1.232.244.128.163559.62105.9
16 wt.%MoTe2/PANI composites1.141.973.377.519.138.4877.99
Table
Table 2. Response times (T1) and recovery times (T2) of sensors under 100 ppm NH3 gas.
Table 2. Response times (T1) and recovery times (T2) of sensors under 100 ppm NH3 gas.
Sensitive FilmPure PANI2.7 wt.% MoTe2/PANI8 wt.% MoTe2/PANI16 wt.% MoTe2/PANI
Response times (T1)36 s25 s26 s25 s
Recovery times (T2)27 s12 s24 s24 s
Table
Table 3. Comparison of MoTe2/PANI composites based NH3 gas sensor and those reported in the literature.
Table 3. Comparison of MoTe2/PANI composites based NH3 gas sensor and those reported in the literature.
MaterialResponse (×100%)T1 (s)T2 (s)Type of TransducerReference
PANI/GO/PANI/ZnO38.31%@100 ppm30—Impedance[30]
PANI-α-Fe2O372%@100 ppm501575Resistive[31]
PANI/WS281%@200 ppm260790Resistive[12]
PAni-WO3158%@100 ppm39377Resistive[32]
3D RGO/PANI hybrid10.8%@100 ppm370675Resistive[33]
PANI/Nb2CTx nanosheets301%@100 ppm105143Voltage[34]
MoTe2/PANI816%@100 ppm2524ResistiveThis work
Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Share and Cite

MDPI and ACS Style

Chen, X.; Chen, X.; Ding, X.; Yu, X. Gas Sensitive Characteristics of Polyaniline Decorated with Molybdenum Ditelluride Nanosheets. Chemosensors 2022, 10, 264. https://doi.org/10.3390/chemosensors10070264

AMA Style

Chen X, Chen X, Ding X, Yu X. Gas Sensitive Characteristics of Polyaniline Decorated with Molybdenum Ditelluride Nanosheets. Chemosensors. 2022; 10(7):264. https://doi.org/10.3390/chemosensors10070264

Chicago/Turabian Style

Chen, Xinpeng, Xiangdong Chen, Xing Ding, and Xiang Yu. 2022. "Gas Sensitive Characteristics of Polyaniline Decorated with Molybdenum Ditelluride Nanosheets" Chemosensors 10, no. 7: 264. https://doi.org/10.3390/chemosensors10070264

Note that from the first issue of 2016, this journal uses article numbers instead of page numbers. See further details here.

Article Metrics

Back to TopTop