Garcienone, a Novel Compound Involved in Allelopathic Activity of Garcinia Xanthochymus Hook
Abstract
:1. Introduction
2. Results
2.1. Allelopathic Activity of Garcinia Xanthochymus Leaf Extracts
2.2. Structure Determination of Active Substance
2.3. Biological Activity of Garcienone
3. Discussion
4. Materials and Methods
4.1. General Experimental Procedures
4.2. Plant Materials
4.3. Extraction and Bioassay
4.4. Purification of the Active Substance
4.5. Characterization of the Compound
4.5.1. NMR Chemical Shifts Calculation Methods
4.5.2. ECD Calculation Methods
4.6. Spectral Data
4.7. Bioassay of the Isolated Compound
4.8. Statistics
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Aqueous Methanol Extracts (mg Dry Weight Equivalent Extract/mL) | ||
---|---|---|
Test Plant Species | Shoot | Root |
Alfalfa | 8.70 | 13.11 |
Cress | 13.55 | 10.93 |
Barnyard grass | 65.31 | 13.99 |
Foxtail fescue | 15.67 | 5.75 |
δC, Type b | δHa (J in Hz) | |
---|---|---|
1 | 28.1, CH3 | 2.28, s |
2 | 198.3, C | |
3 | 130.9, CH | 6.45, dd (16.2, 1.8) |
4 | 143.8, CH | 6.76, dd (16.2, 4.8) |
5 | 76.3, CH | 4.30, m |
6 | 85.6, C | |
7a | 31.9, CH2 | 2.09, m |
7b | 1.53, m | |
8a | 31.3, CH2 | 2.06, m |
8b | 1.82, m | |
9 | 84.7, CH | 4.39, dd (10.7, 5.7) |
10 | 145.4, C | |
11 | 17.9, CH3 | 1.73, s |
12 | 24.6, CH3 | 1.26, s |
13a | 110.9, CH2 | 5.03, s |
13b | 4.84, s | |
5-OH | 2.65, d (1.1) |
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Rob, M.M.; Iwasaki, A.; Suzuki, R.; Suenaga, K.; Kato-Noguchi, H. Garcienone, a Novel Compound Involved in Allelopathic Activity of Garcinia Xanthochymus Hook. Plants 2019, 8, 301. https://doi.org/10.3390/plants8090301
Rob MM, Iwasaki A, Suzuki R, Suenaga K, Kato-Noguchi H. Garcienone, a Novel Compound Involved in Allelopathic Activity of Garcinia Xanthochymus Hook. Plants. 2019; 8(9):301. https://doi.org/10.3390/plants8090301
Chicago/Turabian StyleRob, Md. Mahfuzur, Arihiro Iwasaki, Ryota Suzuki, Kiyotake Suenaga, and Hisashi Kato-Noguchi. 2019. "Garcienone, a Novel Compound Involved in Allelopathic Activity of Garcinia Xanthochymus Hook" Plants 8, no. 9: 301. https://doi.org/10.3390/plants8090301