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Nanomaterials 2018, 8(9), 717; https://doi.org/10.3390/nano8090717

Zinc Oxide Nanoparticles from Waste Zn-C Battery via Thermal Route: Characterization and Properties

Centre for Sustainable Materials Research and Technology (SMaRT@UNSW), School of Materials Science and Engineering, UNSW Sydney, NSW 2052, Australia
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Received: 13 August 2018 / Revised: 3 September 2018 / Accepted: 4 September 2018 / Published: 12 September 2018
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Abstract

Disposable batteries are becoming the primary sources of powering day-to-day gadgets and consequently contributing to e-waste generation. The emerging e-waste worldwide is creating concern regarding environmental and health issues. Therefore, a sustainable recycling approach of spent batteries has become a critical focus. This study reports the detail characterization and properties of ZnO nanoparticles recovered from spent Zn-C batteries via a facile thermal synthesis route. ZnO nanoparticles are used in many applications including energy storage, gas sensors, optoelectronics, etc. due to the exceptional physical and optical properties. A thermal treatment at 900 °C under an inert atmosphere of argon was applied to synthesize ZnO nanoparticles from a spent Zn-C battery using a horizontal quartz tube furnace. X-ray diffraction (XRD), selected area electron diffraction (SAED) and X-ray photoelectron spectroscopy (XPS) results confirmed the formation of crystalline ZnO nanoparticles. Field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM) analysis confirmed that the size of synthesised ZnO particles were less than 50 nm and mainly composed of sphere shaped nanoparticles. Synthesized ZnO exhibited BET surface area of 9.2629 m2/g and showed absorption of light in the UV region. Excitation of ZnO by UV light showed photoluminescence in the visible range. This study will create an opportunity for potential applications of ZnO nanoparticles from spent batteries and will benefit the environment by reducing the volume of e-waste in landfills. View Full-Text
Keywords: waste Zn-C batteries; Zinc-oxide; nanoparticles; optical properties; sustainability waste Zn-C batteries; Zinc-oxide; nanoparticles; optical properties; sustainability
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).
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Farzana, R.; Rajarao, R.; Behera, P.R.; Hassan, K.; Sahajwalla, V. Zinc Oxide Nanoparticles from Waste Zn-C Battery via Thermal Route: Characterization and Properties. Nanomaterials 2018, 8, 717.

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