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Editorial

Preparation, Characterization and Industrial Application of Nanocellulose

by
Marc Delgado-Aguilar
1,* and
Carlos Negro
2,*
1
LEPAMAP-PRODIS Research Group, University of Girona, C. Maria Aurèlia Capmany, 61, 17003 Girona, Spain
2
Department of Chemical Engineering and Materials, Complutense University of Madrid, Avda. Complutense s/n, 28040 Madrid, Spain
*
Authors to whom correspondence should be addressed.
Nanomaterials 2023, 13(10), 1592; https://doi.org/10.3390/nano13101592
Submission received: 5 May 2023 / Accepted: 6 May 2023 / Published: 10 May 2023
The international research community has made significant efforts in the production, characterization, and application of cellulose nanofibers (CNFs) in many sectors. CNFs have a great ability to create 3D-structured networks without any additional crosslinking. This network-forming capacity, together with excellent mechanical characteristics and a reactive surface, makes CNF a nanomaterial with great opportunities in several markets. The CNF market is expected to grow from USD 297 million in 2020 to USD 783 million by 2025 at a compounded annual growth rate (CAGR) of 21.3%. The term CNF is often used for those cellulose nanofibers where the lignin content is residual or absent. However, CNFs can be also produced from fibers containing lignin, called lignocellulosic nanofibers (LCNFs). Given the complexity of fiber structure, nanocellulose production processes are still under development at large scale and there are still several challenges in terms of characterization that the scientific community will have to face in the coming years.
Several applications for nanocellulose have been reported to date, but some of them are far from ready for industrial implementation. This is due to the lack of robust production and characterization processes and protocols, but also due to the unknown side-effects that may be represented in several industrial operations. However, the literature reports many benefits of using nanocellulose in a myriad of sectors, such as papermaking, composites, biomedicine, environmental applications, and many others.
For all the above, we decided to organize a Special Issue on “Preparation, Characterization and Industrial Application of Nanocellulose”. This Special Issue is the result of 13 contributions from 50 researchers in 22 research groups from 10 countries (Argentina, Canada, China, France, Japan, Portugal, Spain, Sweden, Tunisia, and the United States of America). These contributions cover most of the relevant areas related to nanocellulose production, characterization, and industrial applications.
In this Special Issue, the authors have discussed novel production methods of nanostructured cellulose, as well as alternative raw materials with the purpose of enhancing the sustainable character of this nanomaterial. Some examples are the use of date palm wastes [1], annual plants [2], and harvesting residues [3]. In terms of production methods, innovative systems such as oxalic acid [4] or deep eutectic solvents (DES) [5] have been proposed in this Special Issue, as well as bottom-up approaches such as bacterial cellulose [6]. While these papers report an exhaustive characterization of the developed materials, the Special Issue also counts on specific articles devoted to characterization techniques, such as using gel-point and morphological measurements for assessing the characteristics of nanocellulose [7,8].
This Special Issue also covers relevant aspects related to nanocellulose applications, with a special emphasis on their use as coating agents for paper [3,9,10,11], for the reinforcement of nanocomposites [6], and one research article is devoted to wastewater treatment [12,13].
We would like to acknowledge all the authors, reviewers, and the editorial team from Nanomaterials who made the process of publishing a Special Issue an exciting and motivating experience.

Funding

This Special Issue was organized in the frame of NANOPROSOST (references CTQ2017-85654-C2-1-R and CTQ2017-85654-C2-2-R) and CON-FUTURO-ES (references PID2020-113850RB-C21 and PID2020-113850RB-C22) projects, both funded by the Spanish Ministry of Science and Innovation.

Acknowledgments

The editors of this Special Issue are grateful to the funding agencies listed in the previous section. Marc Delgado-Aguilar is a Serra Húnter fellow.

Conflicts of Interest

The authors declare no conflict of interest.

References

  1. Najahi, A.; Tarrés, Q.; Mutjé, P.; Delgado-Aguilar, M.; Putaux, J.-L.; Boufi, S. Lignin-Containing Cellulose Nanofibrils from TEMPO-Mediated Oxidation of Date Palm Waste: Preparation, Characterization, and Reinforcing Potential. Nanomaterials 2022, 13, 126. [Google Scholar] [CrossRef] [PubMed]
  2. Aguado, R.; Tarrés, Q.; Pèlach, M.À.; Mutjé, P.; de la Fuente, E.; Sanchez-Salvador, J.L.; Negro, C.; Delgado-Aguilar, M. Micro- and Nanofibrillated Cellulose from Annual Plant-Sourced Fibers: Comparison between Enzymatic Hydrolysis and Mechanical Refining. Nanomaterials 2022, 12, 1612. [Google Scholar] [CrossRef] [PubMed]
  3. De Haro-Niza, J.; Rincón, E.; Gonzalez, Z.; Espinosa, E.; Rodríguez, A. Nanocellulose from Spanish Harvesting Residues to Improve the Sustainability and Functionality of Linerboard Recycling Processes. Nanomaterials 2022, 12, 4447. [Google Scholar] [CrossRef] [PubMed]
  4. Bastida, G.A.; Schnell, C.N.; Mocchiutti, P.; Solier, Y.N.; Inalbon, M.C.; Zanuttini, M.Á.; Galván, M.V. Effect of Oxalic Acid Concentration and Different Mechanical Pre-Treatments on the Production of Cellulose Micro/Nanofibers. Nanomaterials 2022, 12, 2908. [Google Scholar] [CrossRef] [PubMed]
  5. Li, W.; Xue, Y.; He, M.; Yan, J.; Lucia, L.A.; Chen, J.; Yu, J.; Yang, G. Facile Preparation and Characteristic Analysis of Sulfated Cellulose Nanofibril via the Pretreatment of Sulfamic Acid-Glycerol Based Deep Eutectic Solvents. Nanomaterials 2021, 11, 2778. [Google Scholar] [CrossRef] [PubMed]
  6. Kono, H.; Tsujisaki, H.; Tajima, K. Reinforcing Poly (Methyl Methacrylate) with Bacterial Cellulose Nanofibers Chemically Modified with Methacryolyl Groups. Nanomaterials 2022, 12, 537. [Google Scholar] [CrossRef] [PubMed]
  7. Sanchez-Salvador, J.L.; Balea, A.; Negro, C.; Monte, M.C.; Blanco, A. Gel Point as Measurement of Dispersion Degree of Nano-Cellulose Suspensions and Its Application in Papermaking. Nanomaterials 2022, 12, 790. [Google Scholar] [CrossRef] [PubMed]
  8. Sanchez-Salvador, J.L.; Campano, C.; Lopez-Exposito, P.; Tarrés, Q.; Mutjé, P.; Delgado-Aguilar, M.; Monte, M.C.; Blanco, A. Enhanced Morphological Characterization of Cellulose Nano/Microfibers through Image Skeleton Analysis. Nanomaterials 2021, 11, 2077. [Google Scholar] [CrossRef] [PubMed]
  9. Sharma, M.; Aguado, R.; Murtinho, D.; Valente, A.J.M.; Ferreira, P.J.T. Micro-/Nanofibrillated Cellulose-Based Coating Formulations: A Solution for Improving Paper Printing Quality. Nanomaterials 2022, 12, 2853. [Google Scholar] [CrossRef] [PubMed]
  10. Tarrés, Q.; Aguado, R.; Pèlach, M.À.; Mutjé, P.; Delgado-Aguilar, M. Electrospray Deposition of Cellulose Nanofibers on Paper: Overcoming the Limitations of Conventional Coating. Nanomaterials 2022, 12, 79. [Google Scholar] [CrossRef] [PubMed]
  11. Mazega, A.; Tarrés, Q.; Aguado, R.; Pèlach, M.À.; Mutjé, P.; Ferreira, P.J.T.; Delgado-Aguilar, M. Improving the Barrier Properties of Paper to Moisture, Air, and Grease with Nanocellulose-Based Coating Suspensions. Nanomaterials 2022, 12, 3675. [Google Scholar] [CrossRef] [PubMed]
  12. Völtz, L.R.; Geng, S.; Teleman, A.; Oksman, K. Influence of Dispersion and Orientation on Polyamide-6 Cellulose Nanocomposites Manufactured through Liquid-Assisted Extrusion. Nanomaterials 2022, 12, 818. [Google Scholar] [CrossRef] [PubMed]
  13. Ojembarrena, F.d.B.; Sammaraie, H.; Campano, C.; Blanco, A.; Merayo, N.; Negro, C. Hexavalent Chromium Removal from Industrial Wastewater by Adsorption and Reduction onto Cationic Cellulose Nanocrystals. Nanomaterials 2022, 12, 4172. [Google Scholar] [CrossRef] [PubMed]
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MDPI and ACS Style

Delgado-Aguilar, M.; Negro, C. Preparation, Characterization and Industrial Application of Nanocellulose. Nanomaterials 2023, 13, 1592. https://doi.org/10.3390/nano13101592

AMA Style

Delgado-Aguilar M, Negro C. Preparation, Characterization and Industrial Application of Nanocellulose. Nanomaterials. 2023; 13(10):1592. https://doi.org/10.3390/nano13101592

Chicago/Turabian Style

Delgado-Aguilar, Marc, and Carlos Negro. 2023. "Preparation, Characterization and Industrial Application of Nanocellulose" Nanomaterials 13, no. 10: 1592. https://doi.org/10.3390/nano13101592

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