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Appl. Sci. 2015, 5(2), 114-121; doi:10.3390/app5020114

SnCl4·5H2O: A Highly Efficient Catalyst for Hydration of Alkyne

1,2,3
,
1,2,3
,
1,2,3,* and 1,2,3,*
1
Key Laboratory of Chemical Engineering Process & Technology for High-efficiency Conversion, College of Heilongjiang Province, Heilongjiang University, Harbin 150080, China
2
International Joint Research Center of Catalytic Technology, Heilongjiang University, Harbin 150080, China
3
School of Chemistry and Material Sciences, Heilongjiang University, Harbin 150080, China
*
Authors to whom correspondence should be addressed.
Academic Editor: Rajender S. Varma
Received: 20 March 2015 / Revised: 8 May 2015 / Accepted: 13 May 2015 / Published: 21 May 2015
View Full-Text   |   Download PDF [663 KB, uploaded 21 May 2015]   |  

Abstract

SnCl4·5H2O is a highly efficient catalyst in the hydration of terminal alkynes that affords carbonyl compounds in high to good yields. Under the optimized reaction conditions, the moderate to excellent yields of corresponding ketones were obtained when the aromatic and aliphatic terminal alkynes were used as substrates. With using diphenylacetylene as an internal alkyne, the corresponding ketone was not detected in the reaction mixture. View Full-Text
Keywords: hydration; alkynes; ketones; stannic chloride pentahydrate hydration; alkynes; ketones; stannic chloride pentahydrate
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Chen, D.; Wang, D.; Wu, W.; Xiao, L. SnCl4·5H2O: A Highly Efficient Catalyst for Hydration of Alkyne. Appl. Sci. 2015, 5, 114-121.

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