Ceramic Materials Containing Volcanic Ash and Characterized by Photoluminescent Activity
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
- A commercial filtered and degassed clay, AFD-000055-Argilla Tornio, was purchased from the Colorobbia Italia S.P.A., Vinci, Italy. It is the clay commonly used by the potters for the manufacturing of their marketed products.
- Hydrochloric acid (ACS reagent 37%) and sodium hydroxide (reagent grade, ≥98%, pellets (anhydrous)) were purchased from Sigma Aldrich, Milano, Italy.
- The volcanic ash (VA) was collected from the slopes of the Etna volcano (Sicily, Italy) after the eruption in 2020.
- The commercial photoluminescent powder used in the present investigation (ZYYINI- MYX-RAG-JM04576-03-FBA) was purchased from ZYYINI, Shenzhen, China
- A ceramic glaze purchased from the Colorobbia Italia S.P.A group was used to fix the photoluminescent powder onto the surface of the specimens. Glaze generates, after firing, a transparent, colorless and waterproofing thin glass coating on the surface of the ceramic material.
2.2. Methods
3. Results and Discussion
4. Conclusions
- The Etna volcanic ash contains inorganic glasses, albite, stishovite, augite–albite, and anorthite. The high content of iron excludes their use in the production of porcelain Upon firing at 950 °C, an increase in the intensity and number of peaks of the crystalline phases was observed and ascribed to minerals formed during the thermal treatment through recrystallisation and sintering.
- Workable and moldable mixtures were prepared by adding up to 30 wt% of VA. The mix with 50 wt% of volcanic ash failed to provide satisfactory fresh properties.
- Weight loss after firing decreases with the increasing of the percentage of clay replacement with volcanic ash, whereas dimensional stability increases. Embedded volcanic ash particles are clearly visible in the microstructure of bricks. It can be assumed that, at the used firing temperature, VA mainly plays the role of nonplastics or temper, providing support for the body.
- Increasing the percentage of VA results in a significant decrease in the mechanical properties up to 66% at the highest replacement percentage. This is due to the presence of volcanic ash particles only partially melted and not firmly joined to the clay matrix, as also confirmed by values of the dynamic elastic modulus and SEM analysis. However, measured the values are higher than those required by the European standard EN 771-2 [43], British Standard BS 3921:1985 [44] and ASTM C62-13 [45] for bricks that can be used in normal weathering.
- The addition of volcanic ash lowers the sorptivity values by up to 10 wt% and hinders the absorption of water of bricks. The produced bricks with VA meet the second-class brick water absorption criteria according to ASTM C20-00 [56].
- A procedure to provide surface of bricks with intense photoluminescent properties, ensuring uniform brightness, was identified.
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Samples | Dried Clay (kg) | Volcanic Ash (kg) | Volcanic Ash (wt%) * | Water (wt%) * |
---|---|---|---|---|
B | 5 | 0.0 | 0.0 | 27 |
BVA10 | 4.5 | 0.5 | 10 | 24 |
BVA30 | 3.5 | 1.5 | 30 | 19 |
BVA50 | 2.5 | 2.5 | 50 | - |
Mineral | wt% | ESD |
---|---|---|
Orthoclase | 3.83 | 0.38 |
Albite | 11.29 | 0.59 |
Rhomboclase | 4.29 | 0.52 |
Calcite | 23.97 | 1.29 |
MgCalcite | 3.18 | 0.59 |
Dolomite | 4.92 | 0.29 |
Mullite21 | 3.55 | 0.41 |
Musc2m1 | 3.21 | 0.61 |
Muscovite2M1 | 1.64 | 0.39 |
Muscovitena037 | 5.52 | 0.92 |
Parago2m | 1.88 | 0.38 |
Parago1m | 4.42 | 0.59 |
Chamosite | 5.35 | 0.30 |
ClinochloreIIb4 | 2.50 | 0.14 |
Halloysite7A | 5.71 | 0.36 |
Halloysite10A | 7.24 | 0.48 |
Quartz | 4.50 | 1.12 |
Illite | 2.99 | 0.65 |
Rwp | 12.79 | |
Rexp | 7.21 | |
Chi2 | 3.1468 | |
GOF | 1.7739 |
Oxide | Spot A (wt%) | Spot B (wt%) |
---|---|---|
Na2O | 7.7 | 6.0 |
MgO | 4.9 | 5.8 |
Al2O3 | 16.6 | 14.7 |
SiO2 | 43.1 | 40.4 |
K2O | 2.8 | 2.7 |
CaO | 10.2 | 11.2 |
Fe O | 12.3 | 16.8 |
TiO2 | 2.1 | 2.3 |
Phase | wt% | ESD |
---|---|---|
Augite | 13.27 | 0.87 |
Anorthite | 4.99 | 0.79 |
Maghemite | 0.64 | 0.24 |
Titanomaghemite | 0.33 | 0.12 |
Muscovite2M1 | 7.16 | 0.91 |
Merrillite | 4.91 | 0.90 |
Stishovite | 13.57 | 0.59 |
Magnetite | 0.03 | 0.07 |
Maghemite | 0.64 | 0.24 |
Sanidine | 0.16 | 0.33 |
Aragonite | 3.33 | 0.50 |
Calcite | 6.77 | 1.23 |
Quartz | 1.00 | 0.41 |
Hematite | 3.60 | 0.29 |
Anortk33 (Albite high_k_33) | 39.43 | 1.57 |
Rwp | 15.67 | |
Rexp | 10.39 | |
Chi2 | 2.27 | |
GOF | 1.51 |
Phase | wt% | ESD |
---|---|---|
Albite | 1.916885 | 0.33499 |
Calcite | 1.284127 | 0.204716 |
Clinochlore1A | 1.600506 | 0.3536 |
Musc2m1 | 0.986358 | 0.279158 |
Siderite | 2.140212 | 0.186105 |
FerrosiliteMg06Fe13Ca | 1.637727 | 0.409432 |
Hematite | 1.833138 | 0.178661 |
Magnetite | 9.677479 | 0.725811 |
Augite | 21.73711 | 1.712169 |
Maghemite | 1.098022 | 0.428042 |
Titanomaghemite | 1.507454 | 0.279158 |
Anorthoclase | 5.601772 | 0.7072 |
Oligoclase | 8.746953 | 0.949137 |
Silica | 26.79917 | 4.466529 |
Cristobalite | 6.885899 | 0.595537 |
Dolomite | 3.666276 | 0.372211 |
Enstatite | 2.493812 | 0.558316 |
Rwp | 14.93 | |
Rexp | 9.96 | |
Chi2 | 2.247 | |
GOF | 1.499 |
Element | (wt%) |
---|---|
O | 68.5 |
Mg | 1.1 |
Al | 7.8 |
Si | 14.5 |
Sr | 4.0 |
Ca | 0.7 |
Na | 2.5 |
Fe | 1.0 |
Oxide | Spot A (wt%) | Spot B (wt%) | Spot C (wt%) |
---|---|---|---|
Na2O | 1.08 | - | 6.8 |
MgO | 27.85 | - | - |
Al2O3 | 3.60 | - | 19.8 |
SiO2 | 0.09 | 1.9 | 64.1 |
K2O | 51.78 | 98.1 | 9.3 |
CaO | 1.47 | - | - |
Fe O | 1.64 | - |
Phase | wt% | ESD |
---|---|---|
Goethite | 1.08 | 0.23 |
Augite | 27.85 | 1.89 |
Hematite | 3.60 | 0.53 |
Calcite | 0.09 | 0.22 |
Anorthoclase | 51.78 | 3.11 |
Stishovite | 1.47 | 0.39 |
Ferrihydrite | 1.64 | 0.39 |
Maghemite | 3.00 | 0.50 |
Quartz | 8.00 | 1.07 |
Stishovite | 1.47 | 0.39 |
Rwp | 20.62 | |
Rexp | 14.58 | |
Chi2 | 2.0001 | |
GOF | 1.4143 |
Oxide | Spot A (wt%) | Spot B (wt%) | Spot C (wt%) |
---|---|---|---|
Na2O | 3.0 | 1.3 | 5.6 |
MgO | 6.1 | 13.8 | - |
Al2O3 | 16.5 | 4.8 | 29.8 |
SiO2 | 48.8 | 47.3 | 49.9 |
P2O5 | 0.5 | - | 9.3 |
Cl | 0.2 | - | - |
K2O | 4.0 | - | 0.5 |
CaO | 9.1 | 23.6 | 13.2 |
TiO2 | 2.2 | 1.7 | - |
FeO | 9.6 | 7.5 | 1.0 |
Phase | wt% | ESD |
---|---|---|
Augite | 13.27 | 0.87 |
Anorthite | 4.99 | 0.79 |
Maghemite | 0.64 | 0.24 |
Titanomaghemite | 0.33 | 0.12 |
Muscovite2M1 | 7.16 | 0.91 |
Merrillite | 4.91 | 0.90 |
Stishovite | 13.57 | 0.59 |
Magnetite | 0.03 | 0.07 |
Maghemite | 0.64 | 0.24 |
Sanidine | 0.16 | 0.33 |
Aragonite | 3.33 | 0.50 |
Calcite | 6.77 | 1.23 |
Quartz | 1.00 | 0.41 |
Hematite | 3.60 | 0.29 |
anortk33 (Albite high_k_33) | 39.43 | 1.57 |
Rwp | 15.67 | |
Rexp | 10.39 | |
Chi2 | 2.27 | |
GOF | 1.51 |
Sample | S (kg/m2min0.5) | a0 (kg/m2) | Average 24-h Water Absorption (%) |
---|---|---|---|
B | 1.87 | −0.612 | 16.05 |
BVA10 | 1.28 | −0.95 | 13.52 |
BVA30 | 1.82 | −0.67535 | 14.86 |
Sample | Density (g/cm3) | Dynamic Modulus of Elasticity (GPa) |
---|---|---|
B | 1.89 | 25.9 |
BVA10 | 1.85 | 19.6 |
BVA30 | 1.80 | 15.85 |
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Candamano, S.; De Luca, P.; Garofalo, P.; Crea, F. Ceramic Materials Containing Volcanic Ash and Characterized by Photoluminescent Activity. Environments 2023, 10, 172. https://doi.org/10.3390/environments10100172
Candamano S, De Luca P, Garofalo P, Crea F. Ceramic Materials Containing Volcanic Ash and Characterized by Photoluminescent Activity. Environments. 2023; 10(10):172. https://doi.org/10.3390/environments10100172
Chicago/Turabian StyleCandamano, Sebastiano, Pierantonio De Luca, Pietro Garofalo, and Fortunato Crea. 2023. "Ceramic Materials Containing Volcanic Ash and Characterized by Photoluminescent Activity" Environments 10, no. 10: 172. https://doi.org/10.3390/environments10100172