1. Introduction
Formed during the amalgamation of Rodinia, the Grenville Province represents a long-lived ancient orogenic belt, which comprises the southwestern margin of the Canadian Shield. New continental crust was intruded and sutured onto the Laurentian foreland for nearly a billion years until a terminal collision at 1.1 Ga halted subduction and crustal growth.
The continent-continent collision that formed the Grenville Province is analogous to that of the Himalayas [
1] and resulted in considerable crustal shortening and thickening. The resulting high-grade metamorphism erased much of the evidence necessary to reconstruct the original growth history of the province and led large areas of the Grenville Province to be labeled as “seas of gneisses” [
2]. However, Nd isotope analysis has been successfully used to estimate crustal formation ages for high-grade gneisses in the Grenville Province [
3] and, hence, to identify several large first-order accreted terranes that were amalgamated together on the Laurentian margin over the Paleo- and Mesoproterozoic (
Figure 1).
Figure 1.
Map of the Grenville Province showing major terranes with distinct crustal formation ages, after Dickin [
3]. Boxed area = study of Martin and Dickin [
4]; ABT = Allochthon Boundary Thrust [
5]; M = Manicouagan meteorite impact site (Palaeoproterozoic crust).
Figure 1.
Map of the Grenville Province showing major terranes with distinct crustal formation ages, after Dickin [
3]. Boxed area = study of Martin and Dickin [
4]; ABT = Allochthon Boundary Thrust [
5]; M = Manicouagan meteorite impact site (Palaeoproterozoic crust).
Dickin [
3] attributed much of the Eastern Grenville Province to the accretion of three very large terranes, formed around 1.9, 1.7 and 1.5 Ga, and termed Makkovikia, Labradoria and Quebecia, respectively (
Figure 1). However, isotope mapping of the western part of the province has been complicated by the establishment of long-lived Andean-type arcs on the Laurentian margin [
6,
7], leading to more complex mixed isotope signatures in this area (
Figure 1).
The clearest evidence for such mixing was seen in the Lac St Jean region [
4], represented by the boxed area in
Figure 1. At that time, the adjacent Parent-Clova area to the SW was not studied in detail, due to poor road access. However, recent upgrading of forest access roads has resulted in limited blasting of road-cuts, allowing Nd isotope mapping of this region to fill one of the last remaining gaps in the crustal formation age map of the Grenville Province. This reconnaissance Nd isotope mapping will hopefully reveal major terrane boundaries within the study area, and also allow a better understanding of the geological relationships between the eastern and western parts of the province and their differing history of crustal growth.
2. Regional Geological Background
The geological context of the present study area is shown in more detail on a terrane map of the SW Grenville Province in
Figure 2. As noted above, the present study area (boxed) represents the last major sampling gap for Nd data in the western part of the province, but it also falls in a kind of conceptual gap between the geological complexity of the SW Grenville Province and the somewhat simpler structure of the Central Grenville Province.
Figure 2.
Map of the western Grenville Province showing the present study area (boxed), falling in a sampling gap between the established geological blocks and terranes of the Central and the SW Grenville Province. TSZ = Tawachiche Shear Zone. White = not yet understood.
Figure 2.
Map of the western Grenville Province showing the present study area (boxed), falling in a sampling gap between the established geological blocks and terranes of the Central and the SW Grenville Province. TSZ = Tawachiche Shear Zone. White = not yet understood.
Nd analysis in the Central Grenville Province by Martin and Dickin [
4] showed it to consist of three major blocks or terranes. The western terrane consists of Tonalite-Trondhjemite-Granodiorite (TTG)-type Archean gneisses with homogeneous Nd isotope signatures that are interpreted as the lateral equivalents of Superior Province crust within the structural extent of the Grenville Province. The eastern terrane also has homogenous Nd isotope signatures, which gave rise to a 71 point Sm-Nd isochron age of 1.51 ± 0.05 Ga [
8]. This block also has TTG-type petrology and was identified by Dickin [
3] as an accreted oceanic arc, termed Quebecia after Rondot [
9]. Between these large terranes is a narrow block with heterogeneous Nd isotope signatures and somewhat alkaline petrology, attributed by Martin and Dickin to a Mesoproterozoic ensialic arc established on the Archean margin. The Allochthon Boundary Thrust of Rivers
et al. [
5], separating largely
in situ parautochthonous crust to the NW from far-traveled allochthonous crust to the SE, corresponds to the edge of the Archean terrane in this area, as originally recognised from Rb-Sr dating by Frith and Doig [
10].
The SW Grenville Province is more complex and is divided into several major lithotectonic terranes in
Figure 2, which will be summarized briefly in order of decreasing age. In this area, Archean crust reaches as far as 150 km SE of the Grenville Front, but in some areas, it has been strongly reworked by later plutonism, and in other areas, it is covered by metasedimentary rocks that sampled material with mixed sources [
3]. In some areas, Archean crust is over-ridden by the allochthonous belt, which forms large nappe lobes, but elsewhere, Archean crust is sutured against an accreted Palaeoproterozoic arc terrane with homogeneous Nd isotope signatures that gave rise to a 53 point Sm-Nd isochron age of 1.75 ± 0.05 Ga [
11].
In contrast to this terrane with homogenous Nd signatures, the over-riding Allochthonous Belt, represented in this area by the Algonquin and Lac Dumoine terranes, has a heterogeneous Nd isotope signature with depleted mantle (TDM) model ages ranging from
ca. 1.4 to 1.8 Ga [
6]. The Algonquin terrane was, in turn, overthrust by the Muskoka and Parry Sound terranes with somewhat younger Nd model ages (
ca. 1.4–1.7 Ga). Further to the SE, still younger model ages are also seen in the Mont Laurier Terrane, Central Granulite Terrane and the Adirondacks (
ca. 1.33–1.55 Ga), attributed to crustal formation in an Elzevirian continental margin arc that gradually stepped off the earlier Mesoproterozoic margin to create a strip of juvenile crust along the edge of the continent [
7,
8,
12].
At the peak of development of this continental margin arc, back arc spreading led to the formation of an Elzevirian back-arc rift system [
13], sub-divided into an ensimatic rift zone in Ontario and an ensialic rift zone in Quebec. These zones are equivalent in extent to the so-called Composite Arc Belt of Carr
et al. [
14], but are attributed to rift-related magmatism rather than arc magmatism, consistent with the geochemistry of mafic units in this area [
15].
3. Geology of the Study Area
The field area encompasses ca. 40,000 km
2 of south-central Quebec, extending from
ca. 47° to 48°30' N and from
ca. 73° to 75° W (
Figure 2). The lack of major roads throughout this region has hindered mapping efforts, which have thus been neglected to this point. Due to the large size of the area, reconnaissance scale mapping of crustal formation ages will allow initial identification of first-order crustal terranes and investigation of the possible continuation of the ensialic arc block of Martin and Dickin [
4] between Archean and Mesoproterozoic terranes to the north and south.
Previous reconnaissance scale mapping in this area was conducted by the Ministère des Ressources naturelles de la Faune et des Parcs, Gouvernement du Québec (MRNFP), leading to a series of 1:250,000 scale regional geological maps that have, in turn, been used to generate a compilation map of the whole Grenville Province [
16].
Much of the field area is dominated by basement lithologies at high metamorphic grades, including orthogneisses and minor paragneisses, whose precursors have been subjected to upper amphibolite to granulite grade metamorphism. The extent of granulite-facies metamorphism (charnockite and mangerite) is clearly indicated on maps of the area, but such variations in grade may actually be a late feature that has little significance for the earlier geological evolution of the region. Finally, a large portion has been characterized as undifferentiated or mixed gneisses, attesting to the complex geology and relative lack of geologic investigation of the region.
The Allochthon Boundary Thrust (ABT), which has been traced along much of the Grenville Province [
5], is believed to cross the northern portion of the study area (heavy line in
Figure 2). South of the ABT lies a band of early Mesoproterozoic mafic gneisses and amphibolites with a few identified granite intrusions generally occurring along regional fault structures. The eastern portion of the study area is dominated by a wide range of lithologies, including mixed, mafic and undifferentiated gneisses. Some anorthosite-mangerite-charnockite-granite (AMCG) suite complexes also trend along regional fault structures to the east [
17]. These variable lithologies are consistent with the existence of an ensialic arc in this area, as identified to the NE by Martin and Dickin [
4].
In the south, the western extent of Quebecia has been currently limited to the Tawachiche Shear Zone (TSZ in
Figure 2) by both U-Pb [
18] and Sm-Nd dating [
3]. Further sampling to the northwest of the TSZ will be used to bridge the remaining gap in Quebecia’s southwestern limit, and identify any crustal mixing [
8] that may have resulted from the younger (<1.45 Ga) Elzevirian arc established on the continental margin [
7].
4. Sampling and Analytical Techniques
Since the objective of this study is to characterize the protolith age of the crust as an estimate of its regional crustal formation age, the strategy adopted was to limit sampling to granitoid orthogneisses that are believed to form by anatexis of primitive arc crust. Previous studies have shown that granitoids of this type have Nd isotope signatures that are consistent and predictable, allowing reliable estimates to be determined of the formation age of the crust using the depleted mantle model of DePaolo [
19]. Mafic gneisses were excluded as far as possible, because of the increased likelihood of a younger mantle-derived component in these rock-types. Metasedimentary gneisses were also excluded, because of their uncertain sedimentary provenance.
On average, 1 kg of rock was crushed, after the removal of any weathered, veined or migmatized material; and careful attention was given to obtain a fine powder that was representative of the whole rock. Major element analyses were performed by Activation Laboratories, Ancaster, Ontario, using Li-borate fusion inductively couple plasma (ICP) analysis. The accuracy of their data was ensured by the inclusion of international standards as part of the analytical protocol.
Sm-Nd analysis followed our established procedures [
6]. After a four-day dissolution at 125 °C in sealed digestion vessels using HF and HNO
3, samples were converted to the chloride form before splitting and spiking. Standard cation and reverse phase column separation methods were used. Nd isotope analyses were performed on a VG Isomass 354 mass spectrometer (VG instruments, Winsford, UK) at McMaster University using double filaments and a 4 collector peak switching algorithm, and were normalised to a
146Nd/
144Nd ratio of 0.7219. Average within-run precision on the samples was ±0.000013 (2σ), and an average value of 0.51185 ± 2 (2σ population) was determined for the La Jolla standard during this work. The reproducibility of
147Sm/
144Nd and
143Nd/
144Nd is estimated at 0.1% and 0.002% (1σ), respectively, leading to an analytical uncertainty on each model age of
ca. 20 Myr (2σ). Duplicate dissolutions in
Table 1 support this estimate, except for two samples with anomalously old ages (#100 and #101) that may contain an inherited refractory sedimentary component.
Table 1.
Nd isotope data for the Parent-Clova area, Quebec.
Table 1.
Nd isotope data for the Parent-Clova area, Quebec.
Map | Field | UTM N | UTM E | ABT | Nd | Sm | 147Sm | 143Nd | E Nd | TDM | Q | P | Met |
---|
# | # | NAD 83 | NAD 83 | km | ppm | ppm | 144Nd | 144Nd | 1.45Ga | Ga | | | grade |
---|
Archean | | | | | | | | | | | | |
1 | CV 12 | 5312260 | 468916 | −3 | 15.6 | 3.13 | 0.1212 | 0.511313 | −11.9 | 2.87 | 153 | −190 | A |
2 | CV 06 | 5322500 | 472900 | −7 | 5.3 | 0.62 | 0.0701 | 0.510707 | −14.3 | 2.49 | 181 | −181 | A |
3 | CV 05 | 5327800 | 472800 | −11 | 12.7 | 2.13 | 0.1013 | 0.510999 | −14.4 | 2.79 | 156 | −192 | A |
4 | CV 01 | 5328100 | 484300 | −4 | 21.1 | 3.67 | 0.1051 | 0.511082 | −13.5 | 2.77 | 133 | −168 | A |
5 | PT 31 | 5340319 | 498776 | −8 | 29.2 | 2.62 | 0.0541 | 0.510223 | −20.8 | 2.71 | 175 | −173 | A |
Ensialic West | | | | | | | | | | | | |
6 | PT 29 | 5329575 | 505950 | 4 | 33.4 | 5.87 | 0.1063 | 0.511573 | −4.1 | 2.08 | 113 | −128 | A |
7 | PT 28 | 5329580 | 507438 | 3 | 32.1 | 5.46 | 0.1027 | 0.511566 | −3.6 | 2.03 | 136 | −93 | A |
8 | PT 27 | 5328314 | 512225 | 7 | 46.9 | 8.16 | 0.1052 | 0.511565 | −4.0 | 2.08 | 100 | −113 | A |
9 | PT 25 | 5324533 | 515720 | 11 | 42.7 | 7.74 | 0.1095 | 0.511670 | −2.8 | 2.00 | 186 | −17 | AG |
10 | PT 24 | 5319037 | 516678 | 16 | 49.0 | 8.19 | 0.1008 | 0.511595 | −2.6 | 1.95 | 120 | −89 | G |
| PT 24R | | | | 41.2 | 7.36 | 0.1079 | 0.511684 | −2.2 | 1.96 | | | |
11 | PT 22 | 5310109 | 522006 | 27 | 43.8 | 8.05 | 0.1110 | 0.511681 | −2.8 | 2.02 | 157 | −41 | G |
12 | PT 21 | 5302873 | 527397 | 35 | 67.6 | 13.30 | 0.1192 | 0.511925 | 0.4 | 1.79 | 156 | −17 | A |
13 | PT 19 | 5293840 | 527596 | 44 | 15.8 | 3.24 | 0.1241 | 0.512041 | 1.8 | 1.69 | 9 | −309 | A |
14 | PT 17 | 5285204 | 526494 | 52 | 45.9 | 6.64 | 0.0874 | 0.511626 | 0.5 | 1.71 | 175 | −10 | A |
15 | PT 34 | 5322886 | 537890 | 19 | 40.8 | 9.91 | 0.1467 | 0.512173 | 0.2 | 1.97 | 19 | −37 | A |
16 | PT 38 | 5331126 | 540795 | 12 | 69.2 | 13.86 | 0.1210 | 0.511904 | −0.3 | 1.87 | 170 | −15 | A |
| PT 38R | | | | 66.6 | 13.43 | 0.1219 | 0.511906 | −0.5 | 1.89 | | | |
17 | PT 39 | 5334297 | 544032 | 12 | 29.2 | 4.23 | 0.0877 | 0.511467 | −2.7 | 1.90 | 175 | −13 | G |
18 | PT 40 | 5338783 | 542855 | 10 | 43.2 | 6.85 | 0.0960 | 0.511547 | −2.7 | 1.94 | 181 | 24 | A |
19 | PT 42 | 5345715 | 542126 | 4 | 45.1 | 9.08 | 0.1217 | 0.511731 | −3.9 | 2.17 | 39 | −245 | A |
20 | PT 43 | 5350500 | 543700 | 1 | 49.0 | 7.43 | 0.0917 | 0.511528 | −2.3 | 1.89 | | | G |
21 | PT 45 | 5349420 | 546184 | 4 | 23.7 | 4.58 | 0.1169 | 0.511736 | −2.9 | 2.05 | 17 | −284 | G |
22 | PT 46 | 5346301 | 556317 | 12 | 58.9 | 9.45 | 0.0969 | 0.511612 | −1.6 | 1.86 | 214 | 34 | G |
23 | PT 49 | 5352843 | 571388 | 16 | 4.2 | 0.46 | 0.0659 | 0.511417 | 0.4 | 1.68 | 229 | −4 | G |
| PT 49R | | | | 5.1 | 0.57 | 0.0678 | 0.511430 | 0.3 | 1.68 | | | |
24 | SM 66 | 5324318 | 590040 | 48 | 105.1 | 17.81 | 0.1024 | 0.511814 | 1.4 | 1.68 | | | G |
25 | SM 63 | 5337877 | 606147 | 52 | 27.8 | 6.18 | 0.1345 | 0.512183 | 2.6 | 1.65 | | | G |
26 | SM 62 | 5339908 | 608634 | 53 | 45.1 | 8.64 | 0.1159 | 0.511957 | 1.7 | 1.69 | | | G |
27 | SM 61 | 5340195 | 608862 | 53 | 48.8 | 10.09 | 0.1250 | 0.511977 | 0.4 | 1.83 | | | G |
28 | SM 33 | 5350767 | 597347 | 37 | 43.8 | 7.81 | 0.1077 | 0.511693 | −2.0 | 1.94 | | | G |
29 | SM 31 | 5348566 | 608753 | 47 | 58.0 | 9.54 | 0.0994 | 0.511611 | −2.1 | 1.91 | | | AG |
30 | SM 53 | 5349001 | 611235 | 48 | 40.3 | 8.40 | 0.1261 | 0.511977 | 0.1 | 1.84 | | | G |
31 | SM 57 | 5360057 | 610729 | 41 | 34.6 | 5.63 | 0.0984 | 0.511646 | −1.2 | 1.84 | | | G |
32 | SM 59 | 5367482 | 608905 | 35 | 40.7 | 7.93 | 0.1177 | 0.511980 | 1.8 | 1.68 | | | AG |
33 | SM 30 | 5342182 | 614305 | 55 | 58.4 | 10.35 | 0.1072 | 0.511716 | −1.5 | 1.89 | | | G |
34 | SM 29 | 5339349 | 618111 | 60 | 61.4 | 10.84 | 0.1066 | 0.511784 | 0.0 | 1.79 | | | G |
35 | SM 27 | 5337071 | 620546 | 63 | 61.1 | 12.75 | 0.1261 | 0.511989 | 0.4 | 1.83 | | | G |
36 | SM 56 | 5355500 | 612300 | 45 | 21.6 | 4.65 | 0.1303 | 0.512145 | 2.7 | 1.64 | | | G |
37 | BG 3 | 5374500 | 577300 | 6 | 20.8 | 2.36 | 0.0687 | 0.511291 | −2.6 | 1.84 | | | |
38 | BG 6 | 5358100 | 570800 | 11 | 57.0 | 9.52 | 0.1009 | 0.511715 | −0.3 | 1.79 | | | |
39 | BG 7 | 5349900 | 571200 | 17 | 52.7 | 7.71 | 0.0884 | 0.511554 | −1.1 | 1.81 | | | |
Quebecia West | | | | | | | | | | | | |
40 | PT 16 | 5282400 | 524300 | 56 | 122.1 | 20.70 | 0.1026 | 0.511878 | 2.6 | 1.59 | | | A |
41 | PT 14 | 5274042 | 520503 | 61 | 39.0 | 8.44 | 0.1309 | 0.512181 | 3.3 | 1.57 | 193 | −54 | G |
42 | PT 12 | 5267045 | 515455 | 63 | 22.1 | 5.03 | 0.1378 | 0.512270 | 3.7 | 1.54 | 10 | −184 | A |
43 | PT 13 | 5263282 | 509264 | 60 | 44.5 | 8.11 | 0.1101 | 0.512050 | 4.6 | 1.46 | 164 | −35 | A |
44 | PT 10 | 5247061 | 507356 | 72 | 20.8 | 3.69 | 0.1072 | 0.511924 | 2.6 | 1.60 | 170 | −164 | A |
45 | PT 09 | 5230424 | 502055 | 82 | 77.6 | 11.34 | 0.0884 | 0.511827 | 4.2 | 1.48 | 130 | −34 | A |
46 | PT 08 | 5223870 | 495015 | 85 | 79.3 | 11.77 | 0.0898 | 0.511872 | 4.8 | 1.44 | 130 | −12 | A |
47 | PT 06 | 5212886 | 491489 | 93 | 9.5 | 2.03 | 0.1291 | 0.512164 | 3.3 | 1.58 | 95 | −246 | A |
48 | PT 04 | 5205454 | 488784 | 98 | 42.6 | 8.15 | 0.1156 | 0.512025 | 3.0 | 1.58 | 174 | −9 | A |
49 | LK 17 | 5281989 | 547011 | 62 | 119.6 | 19.19 | 0.0970 | 0.511806 | 2.2 | 1.61 | 189 | −3 | A |
50 | LK 15 | 5273224 | 549785 | 71 | 35.6 | 6.49 | 0.1104 | 0.512043 | 4.4 | 1.47 | 197 | −32 | A |
51 | LK 13 | 5268687 | 557192 | 77 | 111.4 | 17.69 | 0.0959 | 0.511909 | 4.4 | 1.46 | −6 | −64 | A |
52 | LK 12 | 5264800 | 561950 | 85 | 107.1 | 16.28 | 0.0919 | 0.511856 | 4.1 | 1.48 | | | A |
53 | LK 11 | 5259424 | 563191 | 88 | 44.8 | 9.45 | 0.1277 | 0.512176 | 3.7 | 1.53 | 165 | −81 | A |
54 | LK 10 | 5256375 | 564270 | 91 | 49.3 | 10.04 | 0.1230 | 0.512107 | 3.3 | 1.56 | 175 | −87 | A |
55 | LK 09 | 5250482 | 564596 | 97 | 71.7 | 11.13 | 0.0938 | 0.511901 | 4.7 | 1.45 | 115 | −64 | A |
56 | LK 08 | 5245498 | 566212 | 102 | 12.4 | 1.86 | 0.0909 | 0.511931 | 5.8 | 1.38 | 153 | −150 | A |
57 | LK 07 | 5244174 | 570779 | 105 | 30.5 | 6.11 | 0.1211 | 0.512094 | 3.4 | 1.56 | 184 | −188 | A |
58 | LK 04 | 5270000 | 580000 | 85 | 28.0 | 5.28 | 0.1140 | 0.512024 | 3.3 | 1.56 | | | A |
59 | SM 67 | 5308878 | 588859 | 59 | 16.5 | 3.29 | 0.1204 | 0.512044 | 2.5 | 1.62 | | | G |
60 | SM 15 | 5293515 | 594962 | 74 | 14.0 | 2.57 | 0.1110 | 0.511986 | 3.1 | 1.56 | | | G |
| SM 15R | | | | 14.5 | 2.70 | 0.1124 | 0.512005 | 3.2 | 1.57 | | | |
61 | SM 14 | 5290464 | 597932 | 78 | 35.3 | 6.42 | 0.1099 | 0.511985 | 3.3 | 1.55 | | | AG |
62 | SM 11 | 5279366 | 608043 | 94 | 13.1 | 2.26 | 0.1047 | 0.511972 | 4.0 | 1.50 | | | A |
63 | SM 09 | 5273331 | 612022 | 101 | 23.7 | 4.06 | 0.1035 | 0.511916 | 3.1 | 1.56 | | | A |
64 | SM 18 | 5261686 | 610490 | 109 | 36.4 | 5.71 | 0.0948 | 0.511921 | 4.9 | 1.44 | | | A |
65 | SM 07 | 5272071 | 623013 | 109 | 40.6 | 8.69 | 0.1294 | 0.512156 | 3.0 | 1.60 | | | AG |
66 | SM 06 | 5271843 | 629711 | 113 | 17.3 | 3.00 | 0.1048 | 0.511980 | 4.2 | 1.48 | | | A |
67 | SM 04 | 5270537 | 636270 | 119 | 76.8 | 14.75 | 0.1161 | 0.512057 | 3.6 | 1.53 | | | G |
68 | SM 03 | 5269598 | 644006 | 125 | 50.3 | 10.75 | 0.1292 | 0.512142 | 2.8 | 1.61 | | | |
69 | SM 01 | 5267158 | 654073 | 134 | 16.1 | 2.71 | 0.1016 | 0.511922 | 3.6 | 1.52 | | | G |
70 | SM 26 | 5333109 | 621877 | 67 | 120.0 | 20.75 | 0.1045 | 0.511900 | 2.7 | 1.59 | | | G |
71 | SM 24 | 5328908 | 631079 | 77 | 38.2 | 7.90 | 0.1249 | 0.512086 | 2.5 | 1.63 | | | G |
72 | SM 23 | 5311667 | 649863 | 102 | 32.8 | 6.38 | 0.1174 | 0.512073 | 3.6 | 1.53 | | | A |
73 | LK 01 | 5199069 | 556421 | 143 | 35.0 | 7.12 | 0.1229 | 0.512117 | 3.5 | 1.55 | 135 | −54 | A |
74 | LK 27 | 5214951 | 548657 | 123 | 46.7 | 9.38 | 0.1215 | 0.512170 | 4.8 | 1.44 | 121 | 46 | A |
75 | LK 02 | 5217669 | 560395 | 127 | 70.2 | 13.48 | 0.1160 | 0.512107 | 4.6 | 1.46 | 99 | −95 | A |
76 | LK 03 | 5224338 | 563232 | 122 | 84.2 | 14.99 | 0.1076 | 0.512044 | 4.9 | 1.43 | 170 | −4 | A |
77 | LK 20 | 5236188 | 581232 | 116 | 4.5 | 1.00 | 0.1361 | 0.512276 | 4.1 | 1.50 | 67 | −243 | A |
78 | LK 21 | 5236132 | 581708 | 116 | 20.3 | 4.01 | 0.1192 | 0.512145 | 4.7 | 1.44 | 68 | −182 | A |
79 | LK 22 | 5234673 | 586649 | 120 | 22.1 | 4.68 | 0.1279 | 0.512262 | 5.4 | 1.39 | 96 | −177 | A |
80 | LK 24 | 5236819 | 597455 | 123 | 56.2 | 10.21 | 0.1098 | 0.512018 | 4.0 | 1.50 | 175 | −150 | A |
81 | LK 26 | 5236356 | 611698 | 130 | 34.0 | 7.09 | 0.1261 | 0.512114 | 2.8 | 1.61 | 21 | −197 | A |
82 | RR 05 | 5233633 | 629851 | 143 | 7.0 | 1.90 | 0.1660 | 0.512595 | 4.8 | 1.42 | | | G |
83 | RR 04 | 5232599 | 638010 | 149 | 14.4 | 1.86 | 0.0782 | 0.511728 | 4.2 | 1.48 | | | G |
84 | RR 03 | 5232775 | 641429 | 151 | 46.6 | 8.05 | 0.1044 | 0.511967 | 4.0 | 1.50 | | | G |
85 | RR 02 | 5231514 | 645627 | 154 | 50.5 | 9.07 | 0.1086 | 0.511986 | 3.6 | 1.53 | | | G |
86 | RR 01 | 5229796 | 649883 | 159 | 31.7 | 7.71 | 0.1472 | 0.512460 | 5.7 | 1.37 | | | G |
87 | SM 20 | 5297854 | 668804 | 125 | 34.2 | 8.60 | 0.1519 | 0.512378 | 3.2 | 1.64 | | | A |
88 | SM 50 | 5339960 | 645205 | 81 | 133.1 | 21.14 | 0.0960 | 0.511868 | 3.6 | 1.52 | | | G |
Archean young | | | | | | | | | | | |
89 | CV 02 | 5334850 | 485700 | −8 | 32.9 | 6.10 | 0.1119 | 0.511677 | −3.1 | 2.05 | 65 | −201 | A |
| CV 02R | | | | 38.6 | 6.95 | 0.1088 | 0.511641 | −3.2 | 2.04 | | | |
90 | PT 30 | 5332089 | 503285 | 1 | 23.1 | 3.99 | 0.1046 | 0.511400 | −7.2 | 2.30 | 113 | −197 | G |
91 | BG 13 | 5361500 | 538700 | −14 | 20.2 | 3.55 | 0.1063 | 0.511443 | −6.6 | 2.28 | 140 | −169 | A |
| BG 13R | | | | 20.8 | 3.62 | 0.1050 | 0.511451 | −6.2 | 2.24 | | | |
Ensialic West, young | | | | | | | | | | | |
92 | PT 32 | 5310663 | 530916 | 29 | 21.0 | 3.70 | 0.1067 | 0.511968 | 3.6 | 1.53 | 127 | −83 | G |
| PT 32R | | | | 24.3 | 4.30 | 0.1072 | 0.511993 | 4.0 | 1.50 | | | |
93 | PT 36 | 5328510 | 538460 | 14 | 29.7 | 6.33 | 0.1288 | 0.512150 | 3.0 | 1.59 | 137 | −131 | A |
94 | SM 65 | 5332003 | 598295 | 49 | 18.0 | 4.19 | 0.1404 | 0.512352 | 4.8 | 1.43 | 26 | −242 | G |
| SM 65R | | | | 19.7 | 4.63 | 0.1421 | 0.512373 | 4.9 | 1.42 | | | |
95 | PT 33 | 5318600 | 535000 | 22 | 26.0 | 5.24 | 0.1216 | 0.512203 | 5.4 | 1.39 | | | A |
96 | BG 4A | 5365200 | 575200 | 10 | 32.2 | 5.26 | 0.0987 | 0.511846 | 2.7 | 1.58 | 139 | −82 | A |
97 | BG 4B | 5365300 | 575300 | 10 | 40.5 | 8.21 | 0.1225 | 0.512078 | 2.8 | 1.61 | | | A |
| BG 4BR | | | | 44.0 | 8.82 | 0.1212 | 0.512067 | 2.8 | 1.60 | | | |
Quebecia West, old | | | | | | | | | | | |
98 | LK 14 | 5269970 | 553081 | 75 | 51.7 | 8.93 | 0.1045 | 0.511649 | −2.3 | 1.95 | 134 | −68 | A |
| LK 14R | | | | 47.5 | 8.52 | 0.1083 | 0.511684 | −2.3 | 1.96 | | | |
99 | LK 05 | 5271948 | 574767 | 81 | 51.9 | 7.59 | 0.0883 | 0.511490 | −2.4 | 1.89 | 205 | −65 | A |
| LK 05R | | | | | | 0.0890 | 0.511494 | −2.4 | 1.89 | | | |
100 | SM 16 | 5302094 | 589326 | 65 | 28.6 | 7.95 | 0.1678 | 0.512363 | 0.0 | 2.25 | 110 | −172 | G |
| SM 16R | | | | | | 0.1651 | 0.512354 | 0.3 | 2.17 | | | |
101 | SM 05 | 5270808 | 634350 | 117 | 82.4 | 16.88 | 0.1237 | 0.511955 | 0.2 | 1.84 | 109 | −103 | A |
| SM 05R | | | | 81.1 | 16.43 | 0.1224 | 0.512002 | | 1.73 | | | |
102 | LK 25 | 5236788 | 603276 | 125 | 77.4 | 15.90 | 0.1242 | 0.512005 | 1.1 | 1.78 | 152 | −30 | G |
5. Nd Isotope Results
Over 100 new Nd model ages for granitoid orthogneisses from the study area are presented in
Table 1. Localities are based on Universal Transverse Mercator (UTM) grid references using the 1983 North American Datum. They are plotted in
Figure 3 using colours to indicate approximate ranges of model ages. Dark blue = Archean (>2.4 Ga); red, yellow and pale blue = Palaeoproterozoic (
ca. 1.64–2.4 Ga); green and pink = largely Mesoproterozoic (1.37–1.64 Ga). Based on these colour schemes, it can be seen that samples with Archean TDM ages are restricted to the area NW of the ABT, while the line across the middle of the map separates most samples with model ages above and below 1.64 Ga. Hence, this line is argued to be a continuation of the boundary between the Eastern and Central blocks of Martin and Dickin [
6], corresponding to the Quebecia and ensialic arc terranes.
Figure 3.
Sample locations within the Parent-Clova region, Quebec. Dark and pale blue = ages, respectively, above and below 2.4 Ga in the Archean Parautochthon; red and pink = ages, respectively, above and below 1.64 Ga in the Ensialic Arc block; yellow and green = ages, respectively, above and below 1.64 Ga in the western extension of Quebecia.
Figure 3.
Sample locations within the Parent-Clova region, Quebec. Dark and pale blue = ages, respectively, above and below 2.4 Ga in the Archean Parautochthon; red and pink = ages, respectively, above and below 1.64 Ga in the Ensialic Arc block; yellow and green = ages, respectively, above and below 1.64 Ga in the western extension of Quebecia.
However, these relatively broad age divisions conceal more subtle internal age variation within these terranes. Therefore, to clarify these internal variations, TDM model ages are plotted against distance from the ABT in
Figure 4, in a similar manner to Martin and Dickin [
4].
This plot reveals that the central block in the present study area has exactly the same age structure as the central block of Martin and Dickin, with correlated trends of the Nd model age against distance that are completely overlapping (red circles and vertical crosses in
Figure 4). Similarly, the young (southerly) terrane in the present study area (green circles) overlaps strongly with Quebecia (black diamonds). Hence, this terrane is here referred to as Quebecia West (
Figure 4).
Figure 4.
Plot of TDM model age
versus distance SE of the ABT for samples of the present study (coloured spots), divided into the same three blocks that were identified by Martin and Dickin [
4]. Linear regression fits are shown for published data (crosses) from the ensialic arc block [
4] and the Algonquin ramp [
20], along with new data for Western Quebecia.
Figure 4.
Plot of TDM model age
versus distance SE of the ABT for samples of the present study (coloured spots), divided into the same three blocks that were identified by Martin and Dickin [
4]. Linear regression fits are shown for published data (crosses) from the ensialic arc block [
4] and the Algonquin ramp [
20], along with new data for Western Quebecia.
One difference is that Western Quebecia has a larger number of samples with Nd model ages below 1.5 Ga, whereas in the main Quebecia terrane, only four such samples were seen amongst 71 with model ages in the range 1.5–1.65 Ga [
8]. This is attributed to the effects of the younger Elzevirian arc, which is believed to have straddled the edge of the continent in this area, reworking the southern edge of the Quebecia terrane and generating new crust offshore, which now forms the Adirondacks [
12].
In addition to the 88 samples in
Table 1 that define these regular patterns, there are 14 samples that show anomalous behavior. For example, within the Western Quebecia terrane, there are five samples that show abnormally old ages. However, because rocks with these old ages are not contiguous, they are unlikely to represent specific structural features, such as tectonic windows, to an underlying thrust sheet. Instead, they are attributed to contamination of the granitoid source by inclusion of small pockets of older sediment into the melting zone.
There are also a few samples from the ensialic and Archean terranes that yield abnormally young model ages. These are attributed to younger plutons that introduced new mantle-derived material into the crust. Although these samples contribute to the geological noise, they can also yield important information. For example, the three abnormally young samples (pale blue) within the Archean terrane show the effects of mixing Archean crustal Nd with (probable) juvenile Mesoproterozoic Nd. Hence, we infer that similar mixing process gave rise to the older (
ca. 2 Ga) model ages within the ensialic block. The fraction of old crustal Nd involved in mixing apparently decreased steadily southwards, as proposed by Martin and Dickin [
4].
Six samples (coloured pink) that yield abnormally young model ages within the ensialic block are attributed to two stages of Nd mixing. The first of these stages yielded the relatively coherent signature of the Nd mixing line described above. Superimposed on this older mixing event was a more scattered younger mixing event, which introduced small amounts of new mantle-derived material into the older mixed crust of the ensialic arc block. This latter event probably represents distal plutonism related to the Elzevirian continental margin arc to the south [
8].
Isotope signatures analogous to this younger mixing event were generated in crust southeast of the Algonquin Ramp in Ontario (diagonal crosses in
Figure 4). This area of Ontario is part of the Algonquin Terrane that overlies the main ramp of the ABT [
20] and was attributed by Dickin and McNutt [
6] to Mesoproterozoic ensialic arc magmatism established on an older Palaeoproterozoic margin.
The overlapping distributions of pink circles and diagonal crosses in
Figure 4 are both attributed to mixing of ensialic arc magma with an older crustal component having Nd model ages around 1.8–2 Ga. However, the origins of the older components are different in the two regions. In Ontario, the older component is attributed to an accreted Palaeoproterozoic arc with geographically homogeneous Nd signatures that yield a 1.75 Ga Sm-Nd isochron [
11], as described in the introduction. In contrast, the older component in the present study area was itself the product of earlier mixing, demonstrated by its highly variable model age structure.
The calculation of model ages for mixed components involves extrapolation from the time of mixing to the apparent intersection with the mantle growth curve [
21]. Hence, this can cause error magnification and, therefore, increased data scatter. To overcome this problem, an alternative data presentation involves plotting epsilon Nd values calculated at the estimated time of mixing. It is not necessary to know the precise time of mixing, because the narrow range of Sm/Nd ratios in granitoid rocks causes most Nd isotope growth lines to be sub-parallel. Hence, the epsilon model is quite insensitive to the exact time (
t) chosen, provided this is the same for all samples. The result (
Figure 5) effectively reproduces the effects seen in
Figure 4, but with less scatter about the mixing lines. The result is strong support for the distance-modulated crustal mixing model.
The epsilon
versus distance plot can also be used to test another feature of the sample suite, namely the effect of metamorphic grade. The study area displays variable metamorphic grade from amphibolite-facies to granulite-facies (A and G, respectively, in
Table 1). It is possible that the variable grade of metamorphism could have affected the closed-system assumption inherent in Nd isotope mapping. However, granulite-facies samples (shown in darker red and green) show no consistent difference from amphibolite-facies samples. Hence, it is argued that metamorphic grade has not affected the Sm-Nd closed-system assumption in the large whole-rock samples analysed.
Figure 5.
Plot of εNd values versus distance SE of the ABT, distinguishing between amphibolite facies and granulite facies gneisses.
Figure 5.
Plot of εNd values versus distance SE of the ABT, distinguishing between amphibolite facies and granulite facies gneisses.
7. Discussion
New Nd data from the Parent-Clova region of south-central Quebec help to fill in a major gap in the crustal formation age map of the Grenville Province. They show clearly that the ensialic arc block of Martin and Dickin [
4] continues a further 100 km to the SW, forming an almost parallel-sided strip between Archean crust and the Quebecia terrane along a distance of over 300 km (
Figure 7).
The positive correlation between epsilon (1450 Ma) values and the distance from the ABT in the ensialic arc block provides strong evidence that this is an isotopic mixing line, and because the mixing line projects towards the compositions of scattered Proterozoic plutons within the Archean terrane (
Figure 5), this suggests strongly that the crustal end-member of the mixing line was Archean. Hence, the mixing line suggests that Mesoproterozoic crustal growth occurred directly on the Archean margin in the present study area, in the absence of the accreted Palaeoproterozoic arc crust.
However, around 76° west, there is an important change in the nature of the Laurentian margin. From this point westwards, Archean crust was fringed by an accreted Palaeoproterozoic arc named Barilia by Dickin [
3]. This transition has been emphasized in
Figure 7 by leaving the Archean crust west of 76° longitude un-coloured. South of the Palaeoproterozoic margin in Ontario, the Algonquin terrane represents an ensialic arc analogous to the central block of Martin and Dickin [
4], forming a similar mixing line on the epsilon Nd
versus distance plot. The samples that gave rise to this mixing line came from the area shaded dark pink in
Figure 7. However, the Algonquin mixing line projects towards a Palaeoproterozoic rather than an Archean end-member (
Figure 4,
Figure 5). Hence, we can see that a Mesoproterozoic ensialic arc was established along this whole margin, but it crossed from Archean crust in the east to Palaeoproterozoic crust in the west.
Figure 7.
Map of the western Grenville Province showing the change in the age of the Mesoproterozoic Laurentian margin from Archean (blue) in the central Grenville Province to Palaeoproterozoic (orange) in the SW. Red = ensialic arc established on Archean margin (present study area); pink = ensialic arc established on Palaeoproterozoic crust (dark pink = data that generated the Algonquin mixing lines in
Figure 4,
Figure 5); pale green = ensialic arc established on the accreted Mesoproterozoic margin; darker green = ensialic arc established on the older Mesoproterozoic ensialic arc.
Figure 7.
Map of the western Grenville Province showing the change in the age of the Mesoproterozoic Laurentian margin from Archean (blue) in the central Grenville Province to Palaeoproterozoic (orange) in the SW. Red = ensialic arc established on Archean margin (present study area); pink = ensialic arc established on Palaeoproterozoic crust (dark pink = data that generated the Algonquin mixing lines in
Figure 4,
Figure 5); pale green = ensialic arc established on the accreted Mesoproterozoic margin; darker green = ensialic arc established on the older Mesoproterozoic ensialic arc.
It was suggested by Martin and Dickin [
4] that the ensialic arc magmatism that gave rise to the Central Block occurred due to a subduction flip
after the accretion of Quebecia. However, the new data presented here show that the reworking of Quebecia in the Elzevirian arc gave rise to a much more scattered mixing signature than the more regular mixing line seen in the Central Block. Therefore, we now suggest that an early Mesoproterozoic ensialic arc was established on the Laurentian margin as part of the Pinwarian magmatic event [
25], before the accretion of Quebecia (
Figure 8).
In view of the isotopic homogeneity and TTG-type petrology of the Quebecia terrane, Dickin [
3] proposed that this was an accreted oceanic arc. An alternative possibility proposed by Rivers and Corrigan [
7] is that the ensialic arc that gave rise to the Central Block continued to step further away from the continent, so that it generated juvenile ensimatic crust off-shore. However, in the Manicouagan area, homogeneous Mesoproterozoic arc crust abuts directly against Palaeoproterozoic crust [
26], suggesting that in that area, Quebecia was a discrete accreted terrane. In that case, a possible scenario that could explain crustal evolution in the present study area would be two subduction zones, as shown in
Figure 8.
Figure 8.
Cartoon to show proposed early ensialic arc established on the Laurentian margin during the Pinwarian event, followed by more scattered plutonism of the composite margin during the Elzevirian. Red shading indicates crust with mixed isotopic signatures formed in the ensialic arc block.
Figure 8.
Cartoon to show proposed early ensialic arc established on the Laurentian margin during the Pinwarian event, followed by more scattered plutonism of the composite margin during the Elzevirian. Red shading indicates crust with mixed isotopic signatures formed in the ensialic arc block.
Another reason for believing that Quebecia is a discrete accreted terrane is that no such crustal unit is seen in Ontario. Here, it seems that the (Pinwarian) ensialic arc that gave rise to the Algonquin Terrane was followed by continued ensialic arc magmatism on the continental margin, forming the Muskoka Terrane [
6,
20,
27].
Slagstad
et al. [
27] suggested that a 1.55 Ga TDM boundary line, identified in the U.S. Central Plains by van Schmus
et al. [
28], could be traced through the Muskoka terrane of the Grenville Province. However, the data presented here, building on the study of Dickin
et al. [
20], show that no meaningful 1.55 Ga TDM boundary can be traced through Ontario, because the crustal context in Ontario and western Quebec is different from the Central Plains.
Van Schmus
et al. [
28] interpreted the 1.55 Ga TDM line as “a fundamental crustal feature representing the southeastern limit of Palaeoproterozoic crust in Laurentia”. This older Laurentian crust is relatively homogeneous in the Central Plains region, with an average TDM age of 1.7 Ga over large areas. However, the crust to the south of the line is even more homogeneous, with an average TDM age of 1.50 Ga that is barely older than the U-Pb ages of these rocks. Hence, Van Schmus
et al. [
28] suggested that this younger crust “could consist of one or more juvenile terranes accreted to the southeastern margin of early Mesoproterozoic Laurentia”. The 1.55 Ga TDM boundary, therefore, approximates a crustal suture line.
A similar scenario to this is seen in eastern Quebec (
Figure 1), where the homogeneous juvenile Quebecia terrane (TDM 1.55 Ga) is juxtaposed against the Palaeoproterozoic Labradoria terrane (TDM 1.75 Ga) along a sharp boundary line [
3]. However, the situation in Ontario is quite different, because “primary Palaeoproterozoic crust” (with an average TDM age of 1.9 Ga) is here fringed by the Algonquin ensialic arc mixing zone, which was itself reworked by Elzevirian continental arc magmatism. Therefore, in Ontario, the edge of primary Palaeoproterozoic crust is best approximated by a 1.8 Ga demarcation line, which also corresponds to the location of the ABT [
11]. In contrast, a 1.55 Ga age cut-off runs through the middle of the mixing line in the Algonquin ramp, as indicated by the black horizontal bar in
Figure 4.
It is not surprising that suture boundaries of the type identified by van Schmus
et al. [
28] cannot be traced across a whole continent. Most arc systems have a finite geographical extent, so that long-lived active continental margins are expected to periodically break down into separate segments, some of which are characterized by the accretion of large arc terranes, while others are characterized by long-lived ensialic arc subduction zones. Both types are here demonstrated on the Laurentian margin.