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Metals 2016, 6(6), 132;

A Conceptual Model for the Interaction between Carbon Content and Manganese Sulphide Inclusions in the Short-Term Seawater Corrosion of Low Carbon Steel

Centre for Infrastructure Performance and Reliability, The University of Newcastle, Newcastle 2308, Australia
Author to whom correspondence should be addressed.
Academic Editor: Recep Avci
Received: 3 March 2016 / Revised: 20 May 2016 / Accepted: 24 May 2016 / Published: 31 May 2016
(This article belongs to the Special Issue The Role of MnS Inclusions in the Localized Corrosion of Carbon Steel)
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The critical role of manganese sulphide (MnS) inclusions for the initiation of the short-term growth of pitting or localized corrosion of low carbon steels has long been recognized. Classical results show that pitting probability and pitting severity increases with increased sulphide concentration for low carbon steels as a result of magnesium sulphides acting as local cathodes for initiating pitting corrosion. However, the iron carbides (cementite) in steels can also act as local cathodes for initiation of pitting corrosion. Herein it is proposed that there is competition between pits for cathodic area and that this will determine the severity of pitting and general corrosion observed in extended exposures. Preliminary experimental data for immersion exposures of up to 56 days in natural seawater of three low carbon steels show, contrary to conventional wisdom, greater pit depths for the steels with lower S content. However, the pit depth results are consistent with lower C/S ratios. This is considered to support the concept of cathodic competition between C and S. It is proposed that this offers explanations for a number of other phenomena, including the thus far unexplained apparently higher reactivity of some MnS inclusions. View Full-Text
Keywords: manganese; sulphides; cathodes; carbon; competition manganese; sulphides; cathodes; carbon; competition

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Melchers, R.E.; Chaves, I.A.; Jeffrey, R. A Conceptual Model for the Interaction between Carbon Content and Manganese Sulphide Inclusions in the Short-Term Seawater Corrosion of Low Carbon Steel. Metals 2016, 6, 132.

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