Quantum Numbers and the Eigenfunction Approach to Obtain Symmetry Adapted Functions for Discrete Symmetries

Abstract: The eigenfunction approach used for discrete symmetries is deduced from the concept of quantum numbers. We show that the irreducible representations (irreps) associated with the eigenfunctions are indeed a shorthand notation for the set of eigenvalues of the class operators (character table). The need of a canonical chain of groups to establish a complete set of commuting operators is emphasized. This analysis allows us to establish in natural form the connection between the quantum numbers and the eigenfunction method proposed by J.Q. Chen to obtain symmetry adapted functions. We then proceed to present a friendly version of the eigenfunction method to project functions.