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Polymers 2016, 8(1), 21; doi:10.3390/polym8010021

Phase Behavior and Its Effects on Crystallization in a Poly(trimethylene terephthalate)/Phenoxy Resin Blend

Department of Polymer Science and Engineering, Inha University, Incheon 22212, Korea
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Author to whom correspondence should be addressed.
Academic Editor: Lloyd M. Robeson
Received: 4 December 2015 / Revised: 8 January 2016 / Accepted: 14 January 2016 / Published: 19 January 2016
(This article belongs to the Special Issue Polymer Blends)
View Full-Text   |   Download PDF [3693 KB, uploaded 19 January 2016]   |  

Abstract

Phase behavior and its effects on crystallization in an extruded poly(trimethylene terephthalate) (PTT)/phenoxy resin blend were studied with time-resolved light scattering (TRLS), optical microscopy (OM), differential scanning calorimetry (DSC), and small-angle X-ray scattering (SAXS). During annealing in the molten state, a two-phase structure with unique periodicity and phase connectivity was developed by liquid–liquid phase separation. After the formation of the phase-separated structure, the blend was homogenized by the interchange reactions between the two polymers. The crystallization behavior of PTT predominantly depended on the phase morphology developed during annealing. The pre-existing phase structures disturbed the lamellar orientation, resulting in a poorly ordered spherulitic superstructure. View Full-Text
Keywords: poly(trimethylene terephthalate); phenoxy resin; phase behavior; crystallization poly(trimethylene terephthalate); phenoxy resin; phase behavior; crystallization
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Cho, S.J.; Cho, J.H.; Lee, K.H. Phase Behavior and Its Effects on Crystallization in a Poly(trimethylene terephthalate)/Phenoxy Resin Blend. Polymers 2016, 8, 21.

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