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Controlled Photoradical Polymerization Mediated by 2,2,6,6-Tetramethylpiperidine-1-Oxyl
Department of Environmental and Life Sciences, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku-cho, Toyohashi, Aichi 441-8580, Japan
Received: 1 March 2012; in revised form: 13 April 2012 / Accepted: 19 April 2012 / Published: 2 May 2012
Abstract: In recent years, controlled photoradical polymerization has been established using 2,2,6,6-tetramethylpiperidine-1-oxyl as a mediator. This review article will describe the molecular weight control, polymerization mechanism, influence of initiator structure, effect of substituents supported on photo-acid generator, stability of the propagating chain end, photo-latency of the polymerization, molecular design, and an application to heterogeneous polymerization in an alcoholic medium.
Keywords: controlled photoradical polymerization; 2,2,6,6-tetramethylpiperidine-1-oxyl; azoinitiators; photo-acid generators; methyl methacrylate
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MDPI and ACS Style
Yoshida, E. Controlled Photoradical Polymerization Mediated by 2,2,6,6-Tetramethylpiperidine-1-Oxyl. Polymers 2012, 4, 1125-1156.
Yoshida E. Controlled Photoradical Polymerization Mediated by 2,2,6,6-Tetramethylpiperidine-1-Oxyl. Polymers. 2012; 4(2):1125-1156.
Yoshida, Eri. 2012. "Controlled Photoradical Polymerization Mediated by 2,2,6,6-Tetramethylpiperidine-1-Oxyl." Polymers 4, no. 2: 1125-1156.