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Polymers 2018, 10(2), 209; https://doi.org/10.3390/polym10020209

A 3D Stable Metal–Organic Framework for Highly Efficient Adsorption and Removal of Drug Contaminants from Water

Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy, Guangdong Medical University, Dongguan 523808, China
These authors contributed equally to this work.
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Received: 7 January 2018 / Revised: 13 February 2018 / Accepted: 13 February 2018 / Published: 22 February 2018
(This article belongs to the Special Issue Coordination Polymer)
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Abstract

We herein selected a 3D metal–organic framework decorated with carboxylate groups as an adsorbent to remove the pharmaceutical molecules of diclofenac sodium and chlorpromazine hydrochloride from water. The experiment aimed at exploring the effect factors of initial concentration, equilibrium time, temperature, pH and adsorbent dosage on the adsorption process. The adsorption uptake rate of the diclofenac sodium is much higher than that of the chlorpromazine hydrochloride. This paper presents the high adsorption capacity of diclofenac sodium, in which porous MOFs are used for the removal of drug contaminants from water. According to linear fitting with adsorption isotherm equation and kinetic equations, diclofenac sodium conforms to the Langmuir model and pseudo-first-order kinetic equation, while chlorpromazine hydrochloride accords with the Temkin model and pseudo-second-order kinetic equation. The results of the study indicate that the title compound could be a promising hybrid material for removing diclofenac sodium and chlorpromazine hydrochloride from wastewater. View Full-Text
Keywords: metal–organic framework; drug contaminant; adsorption metal–organic framework; drug contaminant; adsorption
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Luo, Z.; Fan, S.; Liu, J.; Liu, W.; Shen, X.; Wu, C.; Huang, Y.; Huang, G.; Huang, H.; Zheng, M. A 3D Stable Metal–Organic Framework for Highly Efficient Adsorption and Removal of Drug Contaminants from Water. Polymers 2018, 10, 209.

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