Next Article in Journal
σ-Hole Interactions: Perspectives and Misconceptions
Previous Article in Journal
Advanced Scanning Probe Microscopy of Graphene and Other 2D Materials
Article Menu
Issue 7 (July) cover image

Export Article

Open AccessArticle
Crystals 2017, 7(7), 217; doi:10.3390/cryst7070217

Syntheses, Crystal Structures and Thermal Behaviors of Two Supramolecular Salamo-Type Cobalt(II) and Zinc(II) Complexes

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China
*
Author to whom correspondence should be addressed.
Academic Editor: Sławomir J. Grabowski
Received: 4 June 2017 / Revised: 3 July 2017 / Accepted: 5 July 2017 / Published: 12 July 2017
(This article belongs to the Section Interactions in Crystal Structures)
View Full-Text   |   Download PDF [2429 KB, uploaded 12 July 2017]   |  

Abstract

This paper reports the syntheses of two new complexes, [Co(L1)(H2O)2] (1) and [{Zn(L2)(μ-OAc)Zn(n-PrOH)}2] (2), from asymmetric halogen-substituted Salamo-type ligands H2L1 and H3L2, respectively. Investigation of the crystal structure of complex 1 reveals that the complex includes one Co(II) ion, one (L1)2− unit and two coordinated water molecules. Complex 1 shows slightly distorted octahedral coordination geometry, forming an infinite 2D supramolecular structure by intermolecular hydrogen bond and π–π stacking interactions. Complex 2 contains four Zn(II)ions, two completely deprotonated (L2)3− moieties, two coordinated μ-OAc ions and n-propanol molecules. The Zn(II) ions in complex 2 display slightly distorted trigonal bipyramidal or square pyramidal geometries. View Full-Text
Keywords: salamo-type ligand; complex; synthesis; crystal structure; supramolecular interaction salamo-type ligand; complex; synthesis; crystal structure; supramolecular interaction
Figures

This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

Supplementary material

Scifeed alert for new publications

Never miss any articles matching your research from any publisher
  • Get alerts for new papers matching your research
  • Find out the new papers from selected authors
  • Updated daily for 49'000+ journals and 6000+ publishers
  • Define your Scifeed now

SciFeed Share & Cite This Article

MDPI and ACS Style

Li, G.; Hao, J.; Liu, L.-Z.; Zhou, W.-M.; Dong, W.-K. Syntheses, Crystal Structures and Thermal Behaviors of Two Supramolecular Salamo-Type Cobalt(II) and Zinc(II) Complexes. Crystals 2017, 7, 217.

Show more citation formats Show less citations formats

Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Crystals EISSN 2073-4352 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top