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Crystals 2017, 7(2), 33; doi:10.3390/cryst7020033

Synthesis, Crystal Structure, and Luminescent Property of a Cd(II) Coordination Polymer with a N-Nicotinoylglycine Ligand

1
College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, China
2
Department of Chemistry, Qinghai Normal University, Xining 810008, China
3
College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266061, China
*
Author to whom correspondence should be addressed.
Academic Editor: Helmut Cölfen
Received: 6 December 2016 / Revised: 19 January 2017 / Accepted: 23 January 2017 / Published: 25 January 2017
View Full-Text   |   Download PDF [2476 KB, uploaded 25 January 2017]   |  

Abstract

A new 1D Cd(II) coordination polymer, [{CdL2(H2O)}·(H2O)3]n (HL = N-nicotinoylglycine), has been synthesized by the assembly of Cd(NO3)2·4H2O with N-nicotinoylglycine, and its composition was determined by elemental analysis, infrared, and X-ray single-crystal diffraction analysis. In this complex, the Cd(II) is seven-coordinated by two N atoms of two N-nicotinoylglycine anions, four O atoms of two N-nicotinoylglycine anions, and one O atom of a coordinated water molecule. The complex forms a 1D looped coordination polymer by the bridging of the N-nicotinoylglycine anion. The luminescent property of the N-nicotinoylglycine ligand and the Cd(II) coordination polymer has also been studied. View Full-Text
Keywords: N-nicotinoylglycine; Cd(II) coordination polymer; synthesis; crystal structure; luminescence N-nicotinoylglycine; Cd(II) coordination polymer; synthesis; crystal structure; luminescence
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Tai, X.-S.; Wang, X.; Li, P.-F. Synthesis, Crystal Structure, and Luminescent Property of a Cd(II) Coordination Polymer with a N-Nicotinoylglycine Ligand. Crystals 2017, 7, 33.

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