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Crystals 2017, 7(12), 354; doi:10.3390/cryst7120354

Synthesis, Crystal Structure and Luminescent Properties of 2D Zinc Coordination Polymers Based on Bis(1,2,4-triazol-1-yl)methane and 1,3-Bis(1,2,4-triazol-1-yl)propane

1
Department of Biotechnology and Organic Chemistry, National Research Tomsk Polytechnic University, 30 Lenin Ave., 634050 Tomsk, Russia
2
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Lavrentieva Ave. 3, 630090 Novosibirsk, Russia
3
Department of Natural Sciences, Novosibirsk State University, Pirogova Str. 2, 630090 Novosibirsk, Russia
*
Author to whom correspondence should be addressed.
Academic Editor: Matthias Weil
Received: 8 November 2017 / Revised: 25 November 2017 / Accepted: 27 November 2017 / Published: 29 November 2017
(This article belongs to the Special Issue Crystal Chemistry of Zinc, Cadmium and Mercury)
View Full-Text   |   Download PDF [4906 KB, uploaded 29 November 2017]   |  

Abstract

Two new two-dimensional zinc(II) coordination polymers containing 2,5-thiophenedicarboxylate and bitopic ligands bis(1,2,4-triazol-1-yl)methane (btrm) or 1,3-bis(1,2,4-triazol-1-yl)propane (btrp) were synthesized. Synthesized compounds were characterized by IR spectroscopy, elemental analysis, powder X-ray diffraction, and thermal analysis. Crystal structures of coordination polymers were determined and their structural peculiarities are discussed. The differences in structural features, thermal behavior, and luminescent properties are discussed. View Full-Text
Keywords: zinc; coordination polymer; bitopic ligand; crystal structure; thermal analysis; luminescence; 2,5-thiophenedicarboxylic acid; bis(1,2,4-triazol-1-yl)methane; 1,3-bis(1,2,4-triazol-1-yl)propane zinc; coordination polymer; bitopic ligand; crystal structure; thermal analysis; luminescence; 2,5-thiophenedicarboxylic acid; bis(1,2,4-triazol-1-yl)methane; 1,3-bis(1,2,4-triazol-1-yl)propane
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Semitut, E.; Sukhikh, T.; Filatov, E.; Ryadun, A.; Potapov, A. Synthesis, Crystal Structure and Luminescent Properties of 2D Zinc Coordination Polymers Based on Bis(1,2,4-triazol-1-yl)methane and 1,3-Bis(1,2,4-triazol-1-yl)propane. Crystals 2017, 7, 354.

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