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Crystals 2015, 5(4), 608-616; doi:10.3390/cryst5040608

A New 1D Chained Coordination Polymer: Synthesis, Crystal Structure, Antitumor Activity and Luminescent Property

1
College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, China
2
College of Chemical and Environmental Engineering, Weifang University of Science and Technology, Shouguang 262700, China
*
Author to whom correspondence should be addressed.
Academic Editor: Helmut Cölfen
Received: 12 October 2015 / Revised: 17 November 2015 / Accepted: 18 November 2015 / Published: 25 November 2015
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Abstract

A new 1D chained coordination polymer of Zn(II), {[Zn(L)2(4,4′-bipy)]·(H2O)}n(1) (HL = N-acetyl-l-phenylalanine; 4,4′-bipy = 4,4′-bipyridine) has been synthesized and characterized by elemental analysis, IR and X-ray single crystal diffraction analysis. Theresults show that each asymmetric unit of Zn(II) complex belongs to monoclinic, space group P21 with a = 11.421(2) Å, b = 9.2213(17) Å, c = 15.188(3) Å,β = 106.112(3)°, V = 1536.7(5) Å3, Z = 2, Dc = 1.444 g·cm−3, µ = 0.857 mm−1, F(000) = 696, and final R1 = 0.0439, ωR2 = 0.1013. The molecules form one-dimensional chained structure by its the bridging 4,4′-bipyridine ligands. The antitumor activities and luminescent properties of Zn(II) coordination polymer have also been investigated. View Full-Text
Keywords: N-acetyl-l-phenylalanine; Zn(II) coordination polymer; 1D chained structure; antitumor activity; luminescent property N-acetyl-l-phenylalanine; Zn(II) coordination polymer; 1D chained structure; antitumor activity; luminescent property
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Tai, X.-S.; You, H.-Y. A New 1D Chained Coordination Polymer: Synthesis, Crystal Structure, Antitumor Activity and Luminescent Property. Crystals 2015, 5, 608-616.

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