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An Unusual Bismuth Ethanedisulfonate Network
AbstractThe three dimensional bismuth ethanedisulfonate framework Bi(O3SC2H4SO3)1.5(H2O)2 was synthesized under hydrothermal conditions using the bidentate ligand 1,2-ethanedisulfonate and then characterized through X-ray diffraction and elemental analyses. The bismuth cation coordinates at three different ethanedisulfonate ligands and has a coordination number of eight, which is accompanied by a distorted square antiprismatic configuration. Here, we report on the crystal structure of this bismuth metal–organic framework and its coordination behavior, which has thus far not been reported in heavier main group elements.
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Gschwind, F.; Jansen, M. An Unusual Bismuth Ethanedisulfonate Network. Crystals 2012, 2, 1374-1381.View more citation formats
Gschwind F, Jansen M. An Unusual Bismuth Ethanedisulfonate Network. Crystals. 2012; 2(4):1374-1381.Chicago/Turabian Style
Gschwind, Fabienne; Jansen, Martin. 2012. "An Unusual Bismuth Ethanedisulfonate Network." Crystals 2, no. 4: 1374-1381.