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Crystals 2012, 2(2), 284-293; doi:10.3390/cryst2020284
Article

New BEDT-TTF Radical Cation Salt with Mixed Anions: α'-[BEDT-TTF]2[CuBr2]0.4[CuCl2]0.6

1,2,*  and 2
Received: 8 March 2012; in revised form: 13 April 2012 / Accepted: 13 April 2012 / Published: 23 April 2012
(This article belongs to the Special Issue Molecular Conductors)
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Abstract: A new mixed-anion crystal composed of BEDT-TTF radical cation salt [BEDT-TTF]2(CuBr2)0.4(CuCl2)0.6 with an α'-type donor arrangement with a formal charge of +0.5 per BEDT-TTF was prepared by using a chemical oxidation method and characterized by using X-ray diffraction, four-probe electrical resistivity measurements (semiconductor: ρrt = 2 × 102 Ω cm, Ea = 0.2 eV), and energy band calculations. The results showed that this system had a quasi-one dimensional Fermi surface.
Keywords: molecular conductor; mixed crystal; BEDT-TTF; quasi-one dimensional character; α'-type donor arrangement; Mott-Hubbard insulator molecular conductor; mixed crystal; BEDT-TTF; quasi-one dimensional character; α'-type donor arrangement; Mott-Hubbard insulator
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Kubo, K.; Yamashita, M. New BEDT-TTF Radical Cation Salt with Mixed Anions: α'-[BEDT-TTF]2[CuBr2]0.4[CuCl2]0.6. Crystals 2012, 2, 284-293.

AMA Style

Kubo K, Yamashita M. New BEDT-TTF Radical Cation Salt with Mixed Anions: α'-[BEDT-TTF]2[CuBr2]0.4[CuCl2]0.6. Crystals. 2012; 2(2):284-293.

Chicago/Turabian Style

Kubo, Kazuya; Yamashita, Masahiro. 2012. "New BEDT-TTF Radical Cation Salt with Mixed Anions: α'-[BEDT-TTF]2[CuBr2]0.4[CuCl2]0.6." Crystals 2, no. 2: 284-293.

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