New Fulvalenium Salts of Cobalt Bis(dicarbollide): Crystal Structures and Electrical Conductivities
AbstractNew radical cation salts (BEDT-TTF)[8,8',(7)-Cl2(Cl0.09)-3,3'-Co(1,2-C2B9H9.91)(1',2'-C2B9H10)] (1), (BEDT-TTF)[8,8'-Br0.75Cl1.25-3,3'-Co(1,2-C2B9H10)2] (2), and (BMDT-TTF)4[8,8'-Br1.16(OH)0.72-3,3'-Co(1,2-C2B9H10.06)2] (3) were synthesized, and their crystal structures and electrical conductivities were determined. All the radical cation salts are semiconductors. Compounds 1 and 2 were found to be isostructural, however their electrical conductivities strongly differ (s293 = 2 Ω−1cm−1 and 10−5 Ω−1cm−1, respectively).
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Kazheva, O.N.; Aleksandrov, G.G.; Kravchenko, A.V.; Starodub, V.A.; Lobanova, I.A.; Kosenko, I.D.; Sivaev, I.B.; Bregadze, V.I.; Buravov, L.I.; Dyachenko, O.A. New Fulvalenium Salts of Cobalt Bis(dicarbollide): Crystal Structures and Electrical Conductivities. Crystals 2012, 2, 43-55.
Kazheva ON, Aleksandrov GG, Kravchenko AV, Starodub VA, Lobanova IA, Kosenko ID, Sivaev IB, Bregadze VI, Buravov LI, Dyachenko OA. New Fulvalenium Salts of Cobalt Bis(dicarbollide): Crystal Structures and Electrical Conductivities. Crystals. 2012; 2(1):43-55.Chicago/Turabian Style
Kazheva, Olga N.; Aleksandrov, Grigory G.; Kravchenko, Andrey V.; Starodub, Vladimir A.; Lobanova, Irina A.; Kosenko, Irina D.; Sivaev, Igor B.; Bregadze, Vladimir I.; Buravov, Lev I.; Dyachenko, Oleg A. 2012. "New Fulvalenium Salts of Cobalt Bis(dicarbollide): Crystal Structures and Electrical Conductivities." Crystals 2, no. 1: 43-55.