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Crystals 2011, 1(4), 215-219; doi:10.3390/cryst1040215
Communication

Iodine Molecules Included in the Structure of Dibenzo-24-Crown-8, (I2)@(db24c8)

,
 and
*
Department für Chemie, Universität zu Köln, Greinstraße 6, D-50939 Köln, Germany
* Author to whom correspondence should be addressed.
Received: 15 August 2011 / Revised: 20 September 2011 / Accepted: 27 September 2011 / Published: 28 September 2011
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Abstract

A reaction of YI3, dibenzo-24-crown-8 and iodine in ethanol yielded, as a by-product, red single crystals of (I2)@(db24c8). In the triclinic crystal, P-1, a = 485.0(1), b = 1203.7(3), c = 1280.4(2) pm, α = 64.56(2)°, β = 86.82(2)°, γ = 83.89(2)°, V = 671.1(2) × 106.pm3, Z = 1, R1= 0.0301 for 1965 reflections with I0 > 2σ(I0), iodine molecules with an I–I distance of 268.39(7) pm, slightly longer than in the gas phase, are included in a matrix of db24c8 molecules.
Keywords: iodine; dibenzo-24-crown-8; inclusion compound; crystal structure iodine; dibenzo-24-crown-8; inclusion compound; crystal structure
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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Walbaum, C.; Pantenburg, I.; Meyer, G. Iodine Molecules Included in the Structure of Dibenzo-24-Crown-8, (I2)@(db24c8). Crystals 2011, 1, 215-219.

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