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Crystals 2011, 1(2), 28-33; doi:10.3390/cryst1020028
Communication

Synthesis and Crystal Structure of 9-(4,6-dichloro-1,3,5-triazin-2-yl)-9H-carbazole

1,* , 1, 1,2 and 3
1 Department of Chemistry, Quaid-i-Azam University, Islamabad 45320, Pakistan 2 Department of Chemistry, Kohat University of Science and Technology (KUST), Kohat 26000, Pakistan 3 Department Chemie, Fakultät fur Naturwissenschaften, Universität Paderborn, Warburgerstrasse 100, D-33098 Paderborn, Germany
* Author to whom correspondence should be addressed.
Received: 31 March 2011 / Revised: 19 April 2011 / Accepted: 22 April 2011 / Published: 26 April 2011
(This article belongs to the Special Issue Feature Paper)
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Abstract

A carbazole-triazine hybrid was prepared by addition-elimination between carbazole and 2,4,6-trichlorotriazine in the presence of base. The compound shows intensely blue fluorescence both in solution and solid state when irradiated with UV-radiation. The structure of (3) was supported by the spectroscopic data and unambiguously confirmed by the single crystal X-ray diffraction data. It was crystallized in the monoclinic space group C2/c with unit cell dimensions a = 20.280(3), b = 8.0726(14), c = 16.005(3) Å, α = γ = 90°, β = 98.947(3)°, V = 2588.3(8) ų, Z = 8.
Keywords: carbazole-triazine hybrid; fluorescence; crystal structure carbazole-triazine hybrid; fluorescence; crystal structure
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).
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Saeed, A.; Kazmi, M.; Samra, S.A.; Flörke, U. Synthesis and Crystal Structure of 9-(4,6-dichloro-1,3,5-triazin-2-yl)-9H-carbazole. Crystals 2011, 1, 28-33.

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