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Crystals 2011, 1(2), 28-33; doi:10.3390/cryst1020028
Communication

Synthesis and Crystal Structure of 9-(4,6-dichloro-1,3,5-triazin-2-yl)-9H-carbazole

1,* , 1, 1,2 and 3
1 Department of Chemistry, Quaid-i-Azam University, Islamabad 45320, Pakistan 2 Department of Chemistry, Kohat University of Science and Technology (KUST), Kohat 26000, Pakistan 3 Department Chemie, Fakultät fur Naturwissenschaften, Universität Paderborn, Warburgerstrasse 100, D-33098 Paderborn, Germany
* Author to whom correspondence should be addressed.
Received: 31 March 2011 / Revised: 19 April 2011 / Accepted: 22 April 2011 / Published: 26 April 2011
(This article belongs to the Special Issue Feature Paper)
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Abstract

A carbazole-triazine hybrid was prepared by addition-elimination between carbazole and 2,4,6-trichlorotriazine in the presence of base. The compound shows intensely blue fluorescence both in solution and solid state when irradiated with UV-radiation. The structure of (3) was supported by the spectroscopic data and unambiguously confirmed by the single crystal X-ray diffraction data. It was crystallized in the monoclinic space group C2/c with unit cell dimensions a = 20.280(3), b = 8.0726(14), c = 16.005(3) Å, α = γ = 90°, β = 98.947(3)°, V = 2588.3(8) ų, Z = 8.
Keywords: carbazole-triazine hybrid; fluorescence; crystal structure carbazole-triazine hybrid; fluorescence; crystal structure
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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Saeed, A.; Kazmi, M.; Samra, S.A.; Flörke, U. Synthesis and Crystal Structure of 9-(4,6-dichloro-1,3,5-triazin-2-yl)-9H-carbazole. Crystals 2011, 1, 28-33.

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