Improving Interfacial Charge-Transfer Transitions in Nb-Doped TiO2 Electrodes with 7,7,8,8-Tetracyanoquinodimethane
Abstract
:1. Introduction
2. Results and Discussion
2.1. Structural Characterization of Nb-Doped TiO2
2.2. Optical Properties of Nb-Doped TiO2
2.3. Photovoltaic Performance of Interfacial Charge-Transfer (ICT) Photoconversion Devices
3. Experimental Section
3.1. Preparation of Nb-Doped TiO2
3.2. Cell Fabrication
3.3. Characterization
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Conflicts of Interest
References
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Nb Content (mol %) | 0 | 1.5 | 3.0 | 5.0 |
Eg (eV) | 3.06 | 3.07 | 3.11 | 3.14 |
ECBM–EF (eV) | 0.46 | 0.37 | 0.41 | 0.64 |
Sample | Jsc (mA/cm2) | Voc (V) | FF (%) | H (%) |
---|---|---|---|---|
Nb 0 mol % | 4.5 | 0.40 | 63 | 1.1 |
Nb 1.5 mol % | 5.5 | 0.41 | 59 | 1.3 |
Nb 3.0 mol % | 5.7 | 0.38 | 57 | 1.2 |
Nb 5.0 mol % | 4.4 | 0.36 | 56 | 0.87 |
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Eguchi, R.; Takekuma, Y.; Ochiai, T.; Nagata, M. Improving Interfacial Charge-Transfer Transitions in Nb-Doped TiO2 Electrodes with 7,7,8,8-Tetracyanoquinodimethane. Catalysts 2018, 8, 367. https://doi.org/10.3390/catal8090367
Eguchi R, Takekuma Y, Ochiai T, Nagata M. Improving Interfacial Charge-Transfer Transitions in Nb-Doped TiO2 Electrodes with 7,7,8,8-Tetracyanoquinodimethane. Catalysts. 2018; 8(9):367. https://doi.org/10.3390/catal8090367
Chicago/Turabian StyleEguchi, Reo, Yuya Takekuma, Tsuyoshi Ochiai, and Morio Nagata. 2018. "Improving Interfacial Charge-Transfer Transitions in Nb-Doped TiO2 Electrodes with 7,7,8,8-Tetracyanoquinodimethane" Catalysts 8, no. 9: 367. https://doi.org/10.3390/catal8090367