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Catalysts 2018, 8(8), 318; https://doi.org/10.3390/catal8080318

Catalytic Copyrolysis of Cork Oak and Waste Plastic Films over HBeta

1
School of Environmental Engineering, University of Seoul, Seoul 02504, Korea
2
Department of Environmental Sciences and Biotechnology, Hallym University, Chuncheon 24252, Korea
3
Frontier Laboratories Ltd., 4-16-20, Saikon, Koriyama, Fukushima 963-8862, Japan
4
Korea National Industrial Convergence Center, Korea Institute of Industrial Technology, Ansan 15588, Korea
*
Author to whom correspondence should be addressed.
Received: 13 July 2018 / Revised: 30 July 2018 / Accepted: 1 August 2018 / Published: 3 August 2018
(This article belongs to the Special Issue Synthesis and Application of Zeolite Catalysts)
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Abstract

The catalytic fast copyrolysis (CFCP) of cork oak (CoOak) and waste plastic films (WPFs) over HBeta(25) (SiO2/Al2O3: 25) was investigated using a thermogravimetric (TG) analyzer and a tandem micro reactor-gas chromatography/mass spectrometry (TMR-GC/MS) to determine the effectiveness of WPFs as the hydrogen donating cofeeding feedstock on the CFCP of biomass. By applying CFCP, the maximum decomposition temperatures of CoOak (373.4 °C) and WPFs (487.9 °C) were reduced to 364.5 °C for CoOak and 436.5 °C for WPFs due to the effective interaction between the pyrolysis intermediates of CoOak and WPFs over HBeta(25), which has strong acidity and an appropriate pore size. The experimental yields of aromatic hydrocarbons on the CFCP of CoOak and WPFs were higher than their calculated yields concluded from the yields obtained from the individual catalytic fast pyrolysis (CFP) of CoOak and WPFs. The coke amount produced from the CFP of CoOak and WPFs over HBeta(25) were also decreased by applying CFCP. View Full-Text
Keywords: catalytic copyrolysis; biomass; waste plastic films; HBeta(25) catalytic copyrolysis; biomass; waste plastic films; HBeta(25)
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Park, Y.-K.; Lee, B.; Watanabe, A.; Lee, H.W.; Lee, J.Y.; Kim, S.; Han, T.U.; Kim, Y.-M. Catalytic Copyrolysis of Cork Oak and Waste Plastic Films over HBeta. Catalysts 2018, 8, 318.

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