Next Article in Journal
Selective Acetylation of Small Biomolecules and Their Derivatives Catalyzed by Er(OTf)3
Previous Article in Journal
Heck Reaction—State of the Art
Article Menu

Export Article

Open AccessArticle
Catalysts 2017, 7(9), 268; doi:10.3390/catal7090268

Pulse Microcalorimetry Study of Methane Dry Reforming Reaction on Ni/Ceria-Zirconia Catalyst

1
Boreskov Institute of Catalysis, Prospekt Akademika Lavrentieva, 5, Novosibirsk 630090, Russia
2
Novosibirsk State University, Pirogova Street, 2, Novosibirsk 630090, Russia
*
Author to whom correspondence should be addressed.
Received: 24 August 2017 / Revised: 6 September 2017 / Accepted: 7 September 2017 / Published: 12 September 2017
(This article belongs to the Special Issue Conversion of CO2 into CO Using Heterogeneous Catalysis)
View Full-Text   |   Download PDF [2032 KB, uploaded 12 September 2017]   |  

Abstract

For Ni/CeZrO catalyst prepared in supercritical isopropanol main features of methane dry reforming reaction mechanism were studied by the pulse microcalorimetric technique. The reaction scheme is described by a step-wise redox mechanism with independent stages of CH4 transformation on Ni/support interface producing syngas with participation of support oxygen bridging species (the rate-limiting stage) and fast reoxidation of support sites by CO2 yielding CO regenerating reactive oxygen species. View Full-Text
Keywords: synthesis in supercritical alcohol; ceria-zirconia; pulse microcalorimetry; methane dry reforming; mechanism synthesis in supercritical alcohol; ceria-zirconia; pulse microcalorimetry; methane dry reforming; mechanism
Figures

This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

Scifeed alert for new publications

Never miss any articles matching your research from any publisher
  • Get alerts for new papers matching your research
  • Find out the new papers from selected authors
  • Updated daily for 49'000+ journals and 6000+ publishers
  • Define your Scifeed now

SciFeed Share & Cite This Article

MDPI and ACS Style

Simonov, M.N.; Rogov, V.A.; Smirnova, M.Y.; Sadykov, V.A. Pulse Microcalorimetry Study of Methane Dry Reforming Reaction on Ni/Ceria-Zirconia Catalyst. Catalysts 2017, 7, 268.

Show more citation formats Show less citations formats

Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Catalysts EISSN 2073-4344 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top