Dehydrogenative Oxidation of Alcohols Catalyzed by Highly Dispersed Ruthenium Incorporated Titanium Oxide
Abstract
:1. Introduction
2. Results and Discussion
2.1. Catalyst Characterization
2.2. Catalytic Tests
3. Materials and Methods
3.1. Synthesis of TiO2 and Ruthenium-Incorporated TiO2 (RuxTiO2)
3.2. Characterization of Catalysts
3.3. Catalytic Tests
4. Conclusions
Supplementary Materials
Acknowledgments
Author Contributions
Conflicts of Interest
References
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Samples | Size (nm) | Surface Area | Ru Content | |
---|---|---|---|---|
XRD | TEM | (m2/g) | (μmol/g) | |
Pure TiO2 | 26.4 | 45.7 ± 5.3 | 48 | - |
Ru0.01TiO2 | 13.2 | 16.7 ± 0.9 | 104 | 9 |
Ru0.03TiO2 | 13.3 | 16.9 ± 1.0 | 111 | 24 |
Ru0.05TiO2 | 13.4 | 17.0 ± 1.4 | 125 | 37 |
Ru0.07TiO2 | 14.7 | 17.3 ± 1.1 | 126 | 51 |
Entry | Catalysts | Substrates | Products | Conversion (%) | Yield to Aldehyde (%) | Selectivity (%) |
---|---|---|---|---|---|---|
1 | None | 0 | - | - | ||
2 | Degussa, P25 | 2 | 1 | 60 | ||
3 | pure TiO2 | 49 | 1 | 2 | ||
4 | Ru0.01TiO2 | 41 | 34 | 86 | ||
5 | Ru0.03TiO2 | 79 | 72 | 93 | ||
6 | Ru0.05TiO2 | 88 | 82 | 93 | ||
7 | Ru0.07TiO2 | >99 | 92 | 93 | ||
8 | Reuse 7 | 99 | 92 | 93 | ||
9 | Reuse 8 | 98 | 90 | 92 | ||
10 | A-Ru0.07TiO2 | 2 | 2 | 99 | ||
11 | None | 0 | - | - | ||
12 | Degussa, P25 | 3 | 3 | 99 | ||
13 | pure TiO2 | 44 | 43 | 98 | ||
14 | Ru0.01TiO2 | 78 | 78 | >99 | ||
15 | Ru0.03TiO2 | 85 | 84 | >99 | ||
16 | Ru0.05TiO2 | 96 | 94 | 98 | ||
17 | Ru0.07TiO2 | >99 | 98 | 99 | ||
18 | None | 0 | - | - | ||
19 | Degussa, P25 | 3 | 2 | 93 | ||
20 | pure TiO2 | 4 | 4 | 98 | ||
21 | Ru0.01TiO2 | 12 | 12 | >99 | ||
22 | Ru0.03TiO2 | 23 | 22 | 97 | ||
23 | Ru0.05TiO2 | 23 | 22 | >99 | ||
24 | Ru0.07TiO2 | 24 | 23 | 98 |
Entry | Catalysts | Substrates | Products | Conversion (%) | Selectivity (%) |
---|---|---|---|---|---|
1 | None | 0 | - | ||
2 | Degussa, P25 | 3 | >99 | ||
3 | pure TiO2 | 3 | >99 | ||
4 | Ru0.01TiO2 | 38 | >99 | ||
5 | Ru0.03TiO2 | 77 | >99 | ||
6 | Ru0.05TiO2 | 94 | >99 | ||
7 | Ru0.07TiO2 | >99 | >99 |
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Kim, Y.; Ahn, S.; Hwang, J.Y.; Ko, D.-H.; Kwon, K.-Y. Dehydrogenative Oxidation of Alcohols Catalyzed by Highly Dispersed Ruthenium Incorporated Titanium Oxide. Catalysts 2017, 7, 7. https://doi.org/10.3390/catal7010007
Kim Y, Ahn S, Hwang JY, Ko D-H, Kwon K-Y. Dehydrogenative Oxidation of Alcohols Catalyzed by Highly Dispersed Ruthenium Incorporated Titanium Oxide. Catalysts. 2017; 7(1):7. https://doi.org/10.3390/catal7010007
Chicago/Turabian StyleKim, Youngyong, Seokhoon Ahn, Jun Yeon Hwang, Doo-Hyun Ko, and Ki-Young Kwon. 2017. "Dehydrogenative Oxidation of Alcohols Catalyzed by Highly Dispersed Ruthenium Incorporated Titanium Oxide" Catalysts 7, no. 1: 7. https://doi.org/10.3390/catal7010007