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Catalysts 2016, 6(4), 59; doi:10.3390/catal6040059

Mixed-Metal Semiconductor Anodes for Electrochemical Water Splitting and Reactive Chlorine Species Generation: Implications for Electrochemical Wastewater Treatment

Linde Center for Global Environmental Science, Division of Engineering & Applied Science, Linde-Robinson Laboratory, California Institute of Technology, Pasadena, CA 91125-0001, USA
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Academic Editors: Bunsho Ohtani and Jae Sung Lee
Received: 16 February 2016 / Revised: 25 March 2016 / Accepted: 31 March 2016 / Published: 20 April 2016
(This article belongs to the Special Issue Photocatalytic Water Splitting-1)
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Abstract

A procedure for the preparation of semiconductor anodes using mixed-metal oxides bound together and protected with a TiO2 nanoglue has been developed and tested in terms of the relative efficiencies of the oxygen evolution (OER), the reactive chlorine species evolution (RCS), and the hydrogen evolution (HER) reactions. The composition of the first anode is a Ti metal substrate coated with IrTaOx and overcoated with TiO2 (P25) that was mixed with TiO2 nanogel, while the second anode consists of a Ti metal substrate coated with IrTaOx and an over-coating layer of La-doped sodium tantalate, NaTaO3:La. The experimental efficiencies for water splitting ranged from 62.4% to 67.5% for H2 evolution and 40.6% to 60.0% for O2 evolution. The corresponding over-potentials for the Ti/IrTa-TiO2 and Ti/IrTa-NaTaO3:La anodes coupled with stainless steel cathodes of the same dimensions were determined to be 437 mV and 367 mV for the OER, respectively, and 239 mV and 205 mV for RCS, respectively. The preparation procedure described herein should allow for easier production of large-surface area anodes at lower costs than standard methods. View Full-Text
Keywords: a facile methodology for electrode fabrication; catalysts; water splitting; wastewater treatment a facile methodology for electrode fabrication; catalysts; water splitting; wastewater treatment
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Ryu, S.Y.; Hoffmann, M.R. Mixed-Metal Semiconductor Anodes for Electrochemical Water Splitting and Reactive Chlorine Species Generation: Implications for Electrochemical Wastewater Treatment. Catalysts 2016, 6, 59.

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