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Catalysts 2016, 6(12), 193; doi:10.3390/catal6120193

The Preparation of Cu-g-C3N4/AC Catalyst for Acetylene Hydrochlorination

1
,
1,2,* and 1,2,*
1
School of Chemistry and Chemical Engineering of Shihezi University, Shihezi 832000, Xinjiang, China
2
Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi 832000, Xinjiang, China
*
Authors to whom correspondence should be addressed.
Academic Editors: Shaobin Wang and Xiaoguang Duan
Received: 29 September 2016 / Revised: 29 November 2016 / Accepted: 29 November 2016 / Published: 5 December 2016
(This article belongs to the Special Issue Heterogeneous Catalysis for Environmental Remediation)
View Full-Text   |   Download PDF [4847 KB, uploaded 5 December 2016]   |  

Abstract

A novel catalyst based on g-C3N4/activated carbon was prepared by adding CuCl2. The catalytic performance of the as-prepared catalyst was investigated in the acetylene hydrochlorination reaction. X-ray photoelectron spectroscopy, temperature programmed desorption, low temperature N2 adsorption/desorption (Brunauer–Emmett–Teller), and thermal gravity analysis showed that Cu-g-C3N4/AC significantly enhanced the catalytic performance of the original catalyst by increasing the relative pyrrolic N content. Cu-g-C3N4/AC also affected the adsorption of hydrogen chloride and acetylene, as well as inhibited the coke deposition during acetylene hydrochlorination. View Full-Text
Keywords: acetylene hydrochlorination; non-mercury catalyst; copper acetylene hydrochlorination; non-mercury catalyst; copper
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Zhao, W.; Zhu, M.; Dai, B. The Preparation of Cu-g-C3N4/AC Catalyst for Acetylene Hydrochlorination. Catalysts 2016, 6, 193.

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