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Catalysts 2013, 3(1), 27-35; doi:10.3390/catal3010027
Communication

Enzyme-Catalyzed Transetherification of Alkoxysilanes

1,†,* , 2
, 1
 and 1,*
Received: 27 November 2012; in revised form: 20 December 2012 / Accepted: 8 January 2013 / Published: 18 January 2013
(This article belongs to the Special Issue Biomimetic Catalysts)
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Abstract: We report the first evidence of an enzyme-catalyzed transetherification of model alkoxysilanes. During an extensive enzymatic screening in the search for new biocatalysts for silicon-oxygen bond formation, we found that certain enzymes promoted the transetherification of alkoxysilanes when tert-butanol or 1-octanol were used as the reaction solvents.
Keywords: enzyme; biomimetic catalysis; transetherification; alkoxysilane enzyme; biomimetic catalysis; transetherification; alkoxysilane
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Abbate, V.; Brandstadt, K.F.; Taylor, P.G.; Bassindale, A.R. Enzyme-Catalyzed Transetherification of Alkoxysilanes. Catalysts 2013, 3, 27-35.

AMA Style

Abbate V, Brandstadt KF, Taylor PG, Bassindale AR. Enzyme-Catalyzed Transetherification of Alkoxysilanes. Catalysts. 2013; 3(1):27-35.

Chicago/Turabian Style

Abbate, Vincenzo; Brandstadt, Kurt F.; Taylor, Peter G.; Bassindale, Alan R. 2013. "Enzyme-Catalyzed Transetherification of Alkoxysilanes." Catalysts 3, no. 1: 27-35.


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