This article is
- freely available
Conversion of CO2 via Visible Light Promoted Homogeneous Redox Catalysis
Catalysis Research Centre, WACKER-Chair of Macromolecular Chemistry, TU-Munich, Lichtenbergstraße 4, 85748 Garching, Germany
* Author to whom correspondence should be addressed.
Received: 27 August 2012; in revised form: 26 October 2012 / Accepted: 13 November 2012 / Published: 27 November 2012
Abstract: This review gives an overview on the principles of light-promoted homogeneous redox catalysis in terms of applications in CO2 conversion. Various chromophores and the advantages of different structures and metal centers as well as optimization strategies are discussed. All aspects of the reduction catalyst site are restricted to CO2 conversion. An important focus of this review is the question of a replacement of the sacrificial donor which is found in most of the current publications. Furthermore, electronic parameters of supramolecular systems are reviewed with reference to the requisite of chromophores, oxidation and reduction sites.
Keywords: CO2; photoreduction; photocatalysis; photooxidation; sacrificial amines
Article StatisticsClick here to load and display the download statistics.
Notes: Multiple requests from the same IP address are counted as one view.
Cite This Article
MDPI and ACS Style
Reithmeier, R.; Bruckmeier, C.; Rieger, B. Conversion of CO2 via Visible Light Promoted Homogeneous Redox Catalysis. Catalysts 2012, 2, 544-571.
Reithmeier R, Bruckmeier C, Rieger B. Conversion of CO2 via Visible Light Promoted Homogeneous Redox Catalysis. Catalysts. 2012; 2(4):544-571.
Reithmeier, Richard; Bruckmeier, Christian; Rieger, Bernhard. 2012. "Conversion of CO2 via Visible Light Promoted Homogeneous Redox Catalysis." Catalysts 2, no. 4: 544-571.