1. Introduction
A number of serious tunnel fire incidents have been reported worldwide that have led to injuries and life losses, heavy damage in the concrete lining, excess material damage, and significant time periods of tunnel restoration during which the tunnels were unavailable for traffic.
Fires in tunnels can seriously damage their concrete lining rendering it to collapse. The damage is caused particularly by the spontaneous release of great amounts of heat and aggressive fire gases, resulting to spalling of concrete. The spalling phenomena are expected at several temperatures depending on the strength of the concrete. It is generally accepted that concrete exposed at temperatures higher than 380 °C is considered as damaged and should be removed and repaired [
1]. In addition to the damage caused by fire to concrete, special attention has to be paid to the damage caused to the structural steel rebars that normally reinforce the concrete structures since are considered to lose their strength at temperatures between 550 °C and 600 °C [
1,
2,
3,
4,
5]. Therefore, steel and concrete are both fire sensitive construction elements requiring passive protection against fire in order to be capable of withstanding of fire for an appropriate period of time without loss of stability.
Passive fire protection methods are generally divided in two categories: external (insulation) and internal (concrete design). The former are more advantageous being applied in new as well as in existing tunnels and consist of the cladding of the concrete by a fire resistant material which creates a protective external insulation envelope. However, even this kind of protection necessitates renovation of the tunnel lining after the fire. Most of the passive fire protection materials either lose their structural integrity or undergo severe damage which necessitates replacement of them. As a result they offer protection to the tunnel in case of one only fire. Apart from that, most of them necessitate long period of time for restoration and as a result tunnels remain closed with obvious negative economic effects.
This work aims at evaluating the performance of a fire resistant geopolymer for external passive fire protection of concrete tunnels linings under two successive RijksWaterStaat (RWS) fire incidents. Following the European Federation of National Associations Representing producers and applicators of specialist building products for Concrete (EFNARC) guidelines [
6], its efficiency was assessed by subjecting a concrete slab specimen, coated with five cm K-geopolymer layer, to two successive thermal loadings employing the RWS curve, which is the worst case fire scenario among all the standard fire load curves.
The RWS curve considers a 50 m3 petrol tanker fire with a fire load of 300 MW lasting up to 120 min. The initial rapid fire growth is simulated with temperature rise up to 1200 °C within the first 10 min. Then, the temperature increases slowly and reaches the highest achieved value of 1350 °C within the next 50 min, followed by a gradual drop in temperatures to 1200 °C in the next hour as the fuel load is burnt off. The RWS temperature-time curve is able to describe very severe fire incidents in tunnels that are accidentally created by large tanker vehicles transporting oil or petrol. The performance requirements for an efficient fire resistant material are that the temperature of the interface between the concrete and the fire protective lining should not exceed 380 °C and the temperature on the reinforcement should not exceed 250 °C. In this paper, the behavior of the K-geopolymer under two successive RWS fire incidents will be evaluated, in order to test the possibility of leaving the material after the first fire incident on a tunnel lining without any restoration.
Geopolymers is a new family of synthetic aluminosilicate materials formed by alkali activation of solid aluminosilicate raw materials [
7]. The geopolymerization reaction is exothermic and takes place at atmospheric pressure and temperatures below 100 °C [
8,
9]. Under a complicated mechanism, this reaction results in the formation of durable and compact amorphous to semi-crystalline solid materials characterized by a specific three-dimensional polymeric structure. Geopolymers possess excellent physicochemical, thermal and mechanical properties, like micro- or nano- porosity, high mechanical strength, notable surface hardness, thermal stability, fire and chemical resistance [
8,
9,
10]. Due to these properties, geopolymers are viewed as alternatives for construction materials with excellent mechanical and unique thermal properties.
3. Results and Discussion
3.1. Properties
The compressive strength of the K-geopolymer increased from 6.2 MPa to 8.7 MPa within the first 28 days and reached 9.5 MPa at 90 days. The flexural strength was 1.1 MPa at the first day after the geopolymer production and 2.1 MPa at the first 28 days. From the 28 days up to 90 days the flexural strength remained almost constant achieving a flexural strength of 2.1 MPa at 90 days from the production of the material. The thermal conductivity of the K-geopolymer was measured to be 0.16 W/(m·K) at 300 K. The density of K-geopolymer is 1800 kg/m3.
3.2. Fire Tests
The behavior of the K-geopolymer under the first fire loading test is shown in
Figure 1, where the attained temperature at the concrete/geopolymer interface, the real furnace temperature simulating RWS fire load curve and the lower and upper limits of the performed RWS curve according to EFNARC guidelines are shown as a function of time.
Figure 1.
Performance of K-geopolymer at the first RijksWaterStaat (RWS) fire load curve.
Figure 1.
Performance of K-geopolymer at the first RijksWaterStaat (RWS) fire load curve.
As it is observed, the temperature at the geopolymer/concrete interface was lower than 380 °C which is the requirement of the RWS curve during the whole duration of the fire test. The temperature reached 250 °C at the end of the test which is 130 °C lower than the performance requirements for an efficient fire resistant material set by the EFNARC for a passive fire protection test with the RWS fire loading curve. In addition, the interface temperature remained below 100 °C for almost the first 85 min of the fire test. At the first 25 min, where the temperature in the furnace were increased rapidly from the ambient temperature to 1250 °C, the interface temperature was remained at a temperature under 50 °C establishing a temperature gradient across the fire resistant geopolymer equal to 24 °C/mm. Then, the interface temperature started increasing reaching a plateau at 90–100 °C at about 55 min test duration. At this time, the furnace temperature was 1320 °C and the established temperature gradient across the geopolymer was even higher at 24.5 °C/mm. The interface temperature remained at about 100 °C for the next 25 min until the fire duration of 80 min. The temperature plateau at 100 °C is attributed to the removal of geopolymeric water through an endothermic water evaporation process consuming large amount of the incoming heat due to the large latent heat of water evaporation and keeping the interface temperature more or less constant at around 100 °C. From this point onwards, the temperature at the geopolymer/concrete interface started increasing while the furnace temperature decreased to 1200 °C. At the end of the fire test, the interface temperature was 250 °C and the temperature gradient was 19 °C/mm, which is the lowest value during the whole duration of the fire test. Finally, the temperature in the back surface of the concrete slab did not exceed 60 °C during the whole duration of the fire test, as is seen in
Figure 1, which means that across the concrete slab the temperature was varied between 60 °C and 250 °C. After the end of the test, the specimen was cooled down at ambient temperature and during the next day the second fire test was performed under the RWS curve according to EFNARC specifications and guidelines. The results are shown in
Figure 2.
Figure 2.
Performance of K-geopolymer at the second RWS fire load curve.
Figure 2.
Performance of K-geopolymer at the second RWS fire load curve.
As it is observed, the temperature at the geopolymer/concrete interface was slightly lower (=370 °C) than the RWS requirements of 380 °C during the whole duration of the fire test. In the second test, the interface temperature remained below 100 °C for 55 min instead of 85 min in the first fire test. At the first 20 min, where the temperature in the furnace was increased rapidly from the ambient temperature to 1200 °C, the interface temperature remained below 50 °C. The main difference with the first test is the time period during which the concrete/geopolymer interface temperature remains at the plateau of 100 °C. In the second test, the interface temperature does not reach a plateau at 100 °C because the geopolymeric water had been removed during the first test. Thus, the interface temperature constantly increased reaching the temperature of 370 °C at the end of the test. The temperature at the back surface of the concrete slab did not exceed 100 °C during the whole duration of the fire test, which means that across the concrete slab the temperature was varied in-between 90 °C and 370 °C.
In the photographs of
Figure 3, the geopolymer before and after the fire tests may be observed. As it is seen the geopolymer superficial material after the end of both tests did not appear to have mechanical damage. It remained on top of the concrete slab without any change in its geometry. Even more, the surface of the geopolymer that was exposed during the fire tests directly at temperature as high as 1350 °C remained almost intact without cracks or other mechanical damages except some local, small in extent and not deep, superficial scaling. The concrete slab protected by the geopolymer did not present any spalling or other mechanical damage and remained as it was initially before the fire test.
The performance of the K-geopolymer under two successive RWS thermal loads was excellent. The material proved to have the ability to put an efficient heat flux barrier protecting the tunnel concrete lining as well as the steel reinforcement from the most severe fire incidents that may happen in underground constructions. In addition, the great macroscopic behaviour of the material after the fire tests without any mechanical damage or deformation proved that there is no need of renovation of the geopolymer material after the first fire test since it can withstand a second RWS curve according to EFNARC specifications and requirements. The material can remain on top of the concrete lining necessitating only minor interventions.
Figure 3.
(a) Specimen before the fire tests. (b) Specimen after the first fire test. (c) Specimen after the second fire test.
Figure 3.
(a) Specimen before the fire tests. (b) Specimen after the first fire test. (c) Specimen after the second fire test.