Materials 2014, 7(3), 2340-2355; doi:10.3390/ma7032340
Article

Highly Dispersed Nickel-Containing Mesoporous Silica with Superior Stability in Carbon Dioxide Reforming of Methane: The Effect of Anchoring

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Received: 26 January 2014; in revised form: 12 March 2014 / Accepted: 12 March 2014 / Published: 19 March 2014
(This article belongs to the Special Issue Advances in Mesoporous Materials)
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: A series of nickel-containing mesoporous silica samples (Ni-SiO2) with different nickel content (3.1%–13.2%) were synthesized by the evaporation-induced self-assembly method. Their catalytic activity was tested in carbon dioxide reforming of methane. The characterization results revealed that the catalysts, e.g., 6.7%Ni-SiO2, with highly dispersed small nickel particles, exhibited excellent catalytic activity and long-term stability. The metallic nickel particle size was significantly affected by the metal anchoring effect between metallic nickel particles and unreduced nickel ions in the silica matrix. A strong anchoring effect was suggested to account for the remaining of small Ni particle size and the improved catalytic performance.
Keywords: methane; dry reforming; Ni; mesoporous silica; anchoring effect
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MDPI and ACS Style

Cai, W.; Ye, L.; Zhang, L.; Ren, Y.; Yue, B.; Chen, X.; He, H. Highly Dispersed Nickel-Containing Mesoporous Silica with Superior Stability in Carbon Dioxide Reforming of Methane: The Effect of Anchoring. Materials 2014, 7, 2340-2355.

AMA Style

Cai W, Ye L, Zhang L, Ren Y, Yue B, Chen X, He H. Highly Dispersed Nickel-Containing Mesoporous Silica with Superior Stability in Carbon Dioxide Reforming of Methane: The Effect of Anchoring. Materials. 2014; 7(3):2340-2355.

Chicago/Turabian Style

Cai, Wenjia; Ye, Lin; Zhang, Li; Ren, Yuanhang; Yue, Bin; Chen, Xueying; He, Heyong. 2014. "Highly Dispersed Nickel-Containing Mesoporous Silica with Superior Stability in Carbon Dioxide Reforming of Methane: The Effect of Anchoring." Materials 7, no. 3: 2340-2355.

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