Materials 2013, 6(10), 4654-4674; doi:10.3390/ma6104654
Review

Thermodynamic Tuning of Mg-Based Hydrogen Storage Alloys: A Review

1,2,* email, 1,2email, 1,2email and 1,2email
Received: 28 August 2013; in revised form: 26 September 2013 / Accepted: 12 October 2013 / Published: 18 October 2013
(This article belongs to the Special Issue Hydrogen Storage Alloys)
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: Mg-based hydrides are one of the most promising hydrogen storage materials because of their relatively high storage capacity, abundance, and low cost. However, slow kinetics and stable thermodynamics hinder their practical application. In contrast to the substantial progress in the enhancement of the hydrogenation/dehydrogenation kinetics, thermodynamic tuning is still a great challenge for Mg-based alloys. At present, the main strategies to alter the thermodynamics of Mg/MgH2 are alloying, nanostructuring, and changing the reaction pathway. Using these approaches, thermodynamic tuning has been achieved to some extent, but it is still far from that required for practical application. In this article, we summarize the advantages and disadvantages of these strategies. Based on the current progress, finding reversible systems with high hydrogen capacity and effectively tailored reaction enthalpy offers a promising route for tuning the thermodynamics of Mg-based hydrogen storage alloys.
Keywords: Mg-based hydrogen storage alloys; thermodynamics; alloying; nanostructuring; changing reaction pathway
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MDPI and ACS Style

Zhu, M.; Lu, Y.; Ouyang, L.; Wang, H. Thermodynamic Tuning of Mg-Based Hydrogen Storage Alloys: A Review. Materials 2013, 6, 4654-4674.

AMA Style

Zhu M, Lu Y, Ouyang L, Wang H. Thermodynamic Tuning of Mg-Based Hydrogen Storage Alloys: A Review. Materials. 2013; 6(10):4654-4674.

Chicago/Turabian Style

Zhu, Min; Lu, Yanshan; Ouyang, Liuzhang; Wang, Hui. 2013. "Thermodynamic Tuning of Mg-Based Hydrogen Storage Alloys: A Review." Materials 6, no. 10: 4654-4674.

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