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Materials 2013, 6(10), 4514-4522; doi:10.3390/ma6104514
Article

Vanadium Pentoxide-Based Composite Synthesized Using Microwave Water Plasma for Cathode Material in Rechargeable Magnesium Batteries

1,2,* , 2
 and 1
Received: 26 July 2013; in revised form: 6 September 2013 / Accepted: 6 October 2013 / Published: 11 October 2013
(This article belongs to the Special Issue Microwave Processing of Materials)
Download PDF [522 KB, updated 15 October 2013; original version uploaded 11 October 2013]
Abstract: Multivalent cation rechargeable batteries are expected to perform well as high-capacity storage devices. Rechargeable magnesium batteries have an advantage in terms of resource utilization and safety. Here, we report on sulfur-doped vanadium pentoxide (S-V2O5) as a potential material for the cathodes of such a battery; S-V2O5 showed a specific capacity of 300 mAh·g−1. S-V2O5 was prepared by a method using a low-temperature plasma generated by carbon felt and a 2.45 GHz microwave generator. This study investigates the ability of S-V2O5 to achieve high capacity when added to metal oxide. The highest recorded capacity (420 mAh·g−1) was reached with MnO2 added to composite SMn-V2O5, which has a higher proportion of included sulfur than found in S-V2O5. Results from transmission electron microscopy, energy-dispersive X-ray spectroscopy, Micro-Raman spectroscopy, and X-ray photoelectron spectroscopy show that the bulk of the SMn-V2O5 was the orthorhombic V2O5 structure; the surface was a xerogel-like V2O5 and a solid solution of MnO2 and sulfur.
Keywords: microwave; rechargeable magnesium battery; cathode material; vanadium pentoxide; sulfur; manganese microwave; rechargeable magnesium battery; cathode material; vanadium pentoxide; sulfur; manganese
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Inamoto, M.; Kurihara, H.; Yajima, T. Vanadium Pentoxide-Based Composite Synthesized Using Microwave Water Plasma for Cathode Material in Rechargeable Magnesium Batteries. Materials 2013, 6, 4514-4522.

AMA Style

Inamoto M, Kurihara H, Yajima T. Vanadium Pentoxide-Based Composite Synthesized Using Microwave Water Plasma for Cathode Material in Rechargeable Magnesium Batteries. Materials. 2013; 6(10):4514-4522.

Chicago/Turabian Style

Inamoto, Masashi; Kurihara, Hideki; Yajima, Tatsuhiko. 2013. "Vanadium Pentoxide-Based Composite Synthesized Using Microwave Water Plasma for Cathode Material in Rechargeable Magnesium Batteries." Materials 6, no. 10: 4514-4522.


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