Materials 2012, 5(3), 385-403; doi:10.3390/ma5030385
Article

Elaboration of Prussian Blue Analogue/Silica Nanocomposites: Towards Tailor-Made Nano-Scale Electronic Devices

Received: 19 January 2012; in revised form: 20 February 2012 / Accepted: 20 February 2012 / Published: 5 March 2012
(This article belongs to the Special Issue Advances in Porous Inorganic Materials)
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: The research of new molecular materials able to replace classical solid materials in electronics has attracted growing attention over the past decade. Among these compounds photoswitchable Prussian blue analogues (PBA) are particularly interesting for the elaboration of new optical memories. However these coordination polymers are generally synthesised as insoluble powders that cannot be integrated into a real device. Hence their successful integration into real applications depends on an additional processing step. Nanostructured oxides elaborated by sol-gel chemistry combined with surfactant micelle templating can be used as nanoreactors to confine PBA precipitation and organize the functional nano-objects in the three dimensions of space. In this work we present the elaboration of different CoFe PBA/silica nanocomposites. Our synthetic procedure fully controls the synthesis of PBA in the porosity of the silica matrix from the insertion of the precursors up to the formation of the photomagnetic compound. We present results on systems from the simplest to the most elaborate: from disordered xerogels to ordered nanostructured films passing through mesoporous monoliths.
Keywords: Prussian blue analogue; mesoporous silica; confined precipitation; photomagnetism; sol-gel
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MDPI and ACS Style

Fornasieri, G.; Aouadi, M.; Delahaye, E.; Beaunier, P.; Durand, D.; Rivière, E.; Albouy, P.-A.; Brisset, F.; Bleuzen, A. Elaboration of Prussian Blue Analogue/Silica Nanocomposites: Towards Tailor-Made Nano-Scale Electronic Devices. Materials 2012, 5, 385-403.

AMA Style

Fornasieri G, Aouadi M, Delahaye E, Beaunier P, Durand D, Rivière E, Albouy P-A, Brisset F, Bleuzen A. Elaboration of Prussian Blue Analogue/Silica Nanocomposites: Towards Tailor-Made Nano-Scale Electronic Devices. Materials. 2012; 5(3):385-403.

Chicago/Turabian Style

Fornasieri, Giulia; Aouadi, Merwen; Delahaye, Emilie; Beaunier, Patricia; Durand, Dominique; Rivière, Eric; Albouy, Pierre-Antoine; Brisset, François; Bleuzen, Anne. 2012. "Elaboration of Prussian Blue Analogue/Silica Nanocomposites: Towards Tailor-Made Nano-Scale Electronic Devices." Materials 5, no. 3: 385-403.

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