Materials 2011, 4(10), 1693-1704; doi:10.3390/ma4101693

Manganese-based Materials Inspired by Photosynthesis for Water-Splitting

Department of Physical Sciences, Alabama State University, Montgomery, AL 36104, USA
Received: 4 August 2011; in revised form: 28 August 2011 / Accepted: 21 September 2011 / Published: 28 September 2011
(This article belongs to the Special Issue Advanced Materials for Water-Splitting)
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Abstract: In nature, the water-splitting reaction via photosynthesis driven by sunlight in plants, algae, and cyanobacteria stores the vast solar energy and provides vital oxygen to life on earth. The recent advances in elucidating the structures and functions of natural photosynthesis has provided firm framework and solid foundation in applying the knowledge to transform the carbon-based energy to renewable solar energy into our energy systems. In this review, inspired by photosynthesis robust photo water-splitting systems using manganese-containing materials including Mn-terpy dimer/titanium oxide, Mn-oxo tetramer/Nafion, and Mn-terpy oligomer/tungsten oxide, in solar fuel production are summarized and evaluated. Potential problems and future endeavors are also discussed.
Keywords: photosynthesis; manganese; photosystem II; artificial photosynthesis; semiconductor; Nafion

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MDPI and ACS Style

Hou, H.J. Manganese-based Materials Inspired by Photosynthesis for Water-Splitting. Materials 2011, 4, 1693-1704.

AMA Style

Hou HJ. Manganese-based Materials Inspired by Photosynthesis for Water-Splitting. Materials. 2011; 4(10):1693-1704.

Chicago/Turabian Style

Hou, Harvey J. 2011. "Manganese-based Materials Inspired by Photosynthesis for Water-Splitting." Materials 4, no. 10: 1693-1704.

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