Next Article in Journal
Previous Article in Journal
Materials 2011, 4(1), 300-310; doi:10.3390/ma4010300
Communication

{Fe6O2}-Based Assembly of a Tetradecanuclear Iron Nanocluster

1,2
, 1
, 3
 and 1,3,4,*
Received: 15 December 2010; in revised form: 31 December 2010 / Accepted: 12 January 2011 / Published: 19 January 2011
(This article belongs to the Special Issue Molecular Magnets)
Download PDF [441 KB, uploaded 19 January 2011]
Abstract: The tetradecanuclear FeIII pivalate nanocluster [Fe14O10(OH)4(Piv)18], comprising a new type of metal oxide framework, has been solvothermally synthesized from a hexanuclear iron pivalate precursor in dichlormethane/acetonitrile solution. Magnetic measurements indicate the presence of very strong antiferromagnetic interactions in the cluster core.
Keywords: Iron(III) carboxylates; Solvothermal synthesis; X-ray structure; Magnetic properties Iron(III) carboxylates; Solvothermal synthesis; X-ray structure; Magnetic properties
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Export to BibTeX |
EndNote


MDPI and ACS Style

Baca, S.G.; Speldrich, M.; Ellern, A.; Kögerler, P. {Fe6O2}-Based Assembly of a Tetradecanuclear Iron Nanocluster. Materials 2011, 4, 300-310.

AMA Style

Baca SG, Speldrich M, Ellern A, Kögerler P. {Fe6O2}-Based Assembly of a Tetradecanuclear Iron Nanocluster. Materials. 2011; 4(1):300-310.

Chicago/Turabian Style

Baca, Svetlana G.; Speldrich, Manfred; Ellern, Arkady; Kögerler, Paul. 2011. "{Fe6O2}-Based Assembly of a Tetradecanuclear Iron Nanocluster." Materials 4, no. 1: 300-310.


Materials EISSN 1996-1944 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert