Materials 2011, 4(1), 300-310; doi:10.3390/ma4010300

{Fe6O2}-Based Assembly of a Tetradecanuclear Iron Nanocluster

1,2email, 1email, 3email and 1,3,4,* email
Received: 15 December 2010; in revised form: 31 December 2010 / Accepted: 12 January 2011 / Published: 19 January 2011
(This article belongs to the Special Issue Molecular Magnets)
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: The tetradecanuclear FeIII pivalate nanocluster [Fe14O10(OH)4(Piv)18], comprising a new type of metal oxide framework, has been solvothermally synthesized from a hexanuclear iron pivalate precursor in dichlormethane/acetonitrile solution. Magnetic measurements indicate the presence of very strong antiferromagnetic interactions in the cluster core.
Keywords: Iron(III) carboxylates; Solvothermal synthesis; X-ray structure; Magnetic properties
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MDPI and ACS Style

Baca, S.G.; Speldrich, M.; Ellern, A.; Kögerler, P. {Fe6O2}-Based Assembly of a Tetradecanuclear Iron Nanocluster. Materials 2011, 4, 300-310.

AMA Style

Baca SG, Speldrich M, Ellern A, Kögerler P. {Fe6O2}-Based Assembly of a Tetradecanuclear Iron Nanocluster. Materials. 2011; 4(1):300-310.

Chicago/Turabian Style

Baca, Svetlana G.; Speldrich, Manfred; Ellern, Arkady; Kögerler, Paul. 2011. "{Fe6O2}-Based Assembly of a Tetradecanuclear Iron Nanocluster." Materials 4, no. 1: 300-310.

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