Next Article in Journal
Masonry Columns Confined by Steel Fiber Composite Wraps
Previous Article in Journal
Laser Fabrication of 3D Gelatin Scaffolds for the Generation of Bioartificial Tissues
Materials 2011, 4(1), 300-310; doi:10.3390/ma4010300
Communication

{Fe6O2}-Based Assembly of a Tetradecanuclear Iron Nanocluster

1,2
,
1
,
3
 and
1,3,4,*
Received: 15 December 2010 / Revised: 31 December 2010 / Accepted: 12 January 2011 / Published: 19 January 2011
(This article belongs to the Special Issue Molecular Magnets)
Download PDF [441 KB, uploaded 19 January 2011]

Abstract

The tetradecanuclear FeIII pivalate nanocluster [Fe14O10(OH)4(Piv)18], comprising a new type of metal oxide framework, has been solvothermally synthesized from a hexanuclear iron pivalate precursor in dichlormethane/acetonitrile solution. Magnetic measurements indicate the presence of very strong antiferromagnetic interactions in the cluster core.
Keywords: Iron(III) carboxylates; Solvothermal synthesis; X-ray structure; Magnetic properties Iron(III) carboxylates; Solvothermal synthesis; X-ray structure; Magnetic properties
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Share & Cite This Article

Further Mendeley | CiteULike
Export to BibTeX |
EndNote
MDPI and ACS Style

Baca, S.G.; Speldrich, M.; Ellern, A.; Kögerler, P. {Fe6O2}-Based Assembly of a Tetradecanuclear Iron Nanocluster. Materials 2011, 4, 300-310.

View more citation formats

Article Metrics

Comments

Citing Articles

[Return to top]
Materials EISSN 1996-1944 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert