Next Article in Journal
Ti-doped ZnO Thin Films Prepared at Different Ambient Conditions: Electronic Structures and Magnetic Properties
Previous Article in Journal
Effects of Interfacial Charge Depletion in Organic Thin-Film Transistors with Polymeric Dielectrics on Electrical Stability
Article Menu

Export Article

Open AccessArticle
Materials 2010, 3(6), 3625-3641; doi:10.3390/ma3063625

Preparation and Characterization of New Inclusion Compounds Using Stable Nitroxide Radicals and an Organic 1-D Nanochannel as a Template

1
Department of Chemistry, College of Humanities and Sciences, Nihon University / 3-25-40, Sakura-jo-sui, Segataya-ku, Tokyo, 156-8550, Japan
2
Graduate School of Science, Osaka University / 1-1, Machikaneyama-cho, Toyonaka, Osaka, 560-0043, Japan
*
Author to whom correspondence should be addressed.
Received: 16 March 2010 / Accepted: 8 June 2010 / Published: 9 June 2010
View Full-Text   |   Download PDF [443 KB, uploaded 9 June 2010]   |  

Abstract

A new inclusion compound (IC) using di-t-buthyl nitroxide (DBNO) radical and tris(o-phenylenedioxy)cyclotriphosphazene (TPP) (1), which has an organic one-dimensional (1-D) nanochannel in the crystal, is reported. According to the characterization using thermogravimetric analysis (TG), ESR measurements, etc., the composition of the inclusion compound was assigned as TPP:DBNO = 1:0.62. The narrowing of the isotropic ESR adsorption line of 1 was observed with a temperature increase from 103 K to room temperature. The line shape indicated a type of 1-D spin diffusion as observed in our previous study of the IC using TPP and 2,2,6,6-tetramethyl-1-piperidinyloxyl (TEMPO). View Full-Text
Keywords: TPP; ESR; inclusion compound; organic radical; 1-D spin chain; organic magnet TPP; ESR; inclusion compound; organic radical; 1-D spin chain; organic magnet
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

Scifeed alert for new publications

Never miss any articles matching your research from any publisher
  • Get alerts for new papers matching your research
  • Find out the new papers from selected authors
  • Updated daily for 49'000+ journals and 6000+ publishers
  • Define your Scifeed now

SciFeed Share & Cite This Article

MDPI and ACS Style

Kobayashi, H.; Asaji, T.; Tani, A. Preparation and Characterization of New Inclusion Compounds Using Stable Nitroxide Radicals and an Organic 1-D Nanochannel as a Template. Materials 2010, 3, 3625-3641.

Show more citation formats Show less citations formats

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Materials EISSN 1996-1944 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top