Families of Molecular Hexa- and Trideca-Metallic Vanadium(III) Phosphonates

doi:10.3390/ma3010232

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Materials 2010, 3(1), 232-240; doi:10.3390/ma3010232

Article

Families of Molecular Hexa- and Trideca-Metallic Vanadium(III) Phosphonates

Sumit Khanra, Rachel Shaw, Madeleine Helliwell, Floriana Tuna, Christopher A. Muryn, Eric J. L. McInnes* and Richard E. P. Winpenny*

School of Chemistry, The University of Manchester, Manchester M13 9PL, UK

* Authors to whom correspondence should be addressed.

Received: 30 November 2009; in revised form: 18 December 2009 / Accepted: 22 December 2009 / Published: 8 January 2010

(This article belongs to the Special Issue Polyoxometalate Compounds)

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Abstract: The synthesis and structural characterization of two families of low-valent vanadium(III) {V₆P₄} and vanadium(III/IV) {V₁₃P₈} phosphonate complexes are reported. Magnetic characterization is reported for representative examples.

Keywords: polyoxovanadium clusters; vanadium(III); phosphonates

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MDPI and ACS Style

Khanra, S.; Shaw, R.; Helliwell, M.; Tuna, F.; Muryn, C.A.; McInnes, E.J.L.; Winpenny, R.E.P. Families of Molecular Hexa- and Trideca-Metallic Vanadium(III) Phosphonates. Materials 2010, 3, 232-240.

AMA Style

Khanra S, Shaw R, Helliwell M, Tuna F, Muryn CA, McInnes EJL, Winpenny REP. Families of Molecular Hexa- and Trideca-Metallic Vanadium(III) Phosphonates. Materials. 2010; 3(1):232-240.

Chicago/Turabian Style

Khanra, Sumit; Shaw, Rachel; Helliwell, Madeleine; Tuna, Floriana; Muryn, Christopher A.; McInnes, Eric J.L.; Winpenny, Richard E.P. 2010. "Families of Molecular Hexa- and Trideca-Metallic Vanadium(III) Phosphonates." Materials 3, no. 1: 232-240.

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