A correction was published on 9 January 2012, see Materials 2012, 5(1), 156.

Materials 2009, 2(1), 22-37; doi:10.3390/ma2010022
Article

Liquid Crystalline π-Conjugated Copolymers Bearing a Pyrimidine Type Mesogenic Group

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Received: 9 December 2008; Accepted: 12 January 2009 / Published: 16 January 2009
(This article belongs to the Special Issue Liquid Crystals)
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: Phenylene-thiophene-based liquid crystalline π-conjugated copolymers bearing mesogenic groups as side chains were synthesized via a Stille polycondensation reaction and confirmed to exhibit a nematic liquid crystal phase at appropriate temperatures. The formation of a nematic phase, but not a smectic phase indicates cooperation of the main chain and side chain in the formation of a nematic main-chain/side-chain liquid crystal phase. The generation of polarons in the main chain as charge carriers during in-situ vapor doping of iodine is confirmed to increase with a doping progresses, exhibiting Dysonian paramagnetic behavior typical of conductive polymers.
Keywords: Liquid crystal; conductive polymer; electron spin resonance
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MDPI and ACS Style

Kawabata, K.; Goto, H. Liquid Crystalline π-Conjugated Copolymers Bearing a Pyrimidine Type Mesogenic Group. Materials 2009, 2, 22-37.

AMA Style

Kawabata K, Goto H. Liquid Crystalline π-Conjugated Copolymers Bearing a Pyrimidine Type Mesogenic Group. Materials. 2009; 2(1):22-37.

Chicago/Turabian Style

Kawabata, Kohsuke; Goto, Hiromasa. 2009. "Liquid Crystalline π-Conjugated Copolymers Bearing a Pyrimidine Type Mesogenic Group." Materials 2, no. 1: 22-37.


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