Physical Properties of Electropolished CoCrMo Alloy Coated with Biodegradable Polymeric Coatings Releasing Heparin after Prolonged Exposure to Artificial Urine
Abstract
:1. Introduction
2. Materials and Methods
2.1. Surface Preparation
2.2. Microscopic Observations
2.3. Surface Roughness
2.4. Wettability Tests
2.5. Adhesion Test
2.6. Potentiodynamic Corrosion Test
2.7. Potentiostatic Corrosion Test
2.8. Investigation of the Mass Density of Ions Released into the Solution
2.9. Examination of Surface Degradation and Incrustation
2.10. Investigation of the Kinetics of the Heparin Release Process
2.11. Statistical Analysis
3. Results and Discussion
3.1. Results of Microscopic Observations
3.2. Surface Roughness Test Results
3.3. The Results of the Surface Wettability Tests
3.4. Results of Tests of Coating Adhesion to the Substrate
3.5. Results of Potentiodynamic Tests of Resistance to Pitting Corrosion
3.6. Results of Potentiostatic Tests of Resistance to Crevice Corrosion
3.7. The Results of the Analysis on the Mass Density of Ions Released into the Solution
3.8. The Results of the Surface Degradation and Incrustation Studies
3.9. The Results of the Studies on the Kinetics of the Heparin Release Process
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Sample | Ra, µm |
---|---|
CoCrMo | 0.11 ± 0.02 |
CoCrMo+P(L,L-L/CL) + PVA + HEP | 0.12 ± 0.02 |
CoCrMo+P(D,L-L/CL) + PVA + HEP | 0.12 ± 0.02 |
Sample | Critical Force Fn (N) after Exposition Time | |||
---|---|---|---|---|
0 Days | 30 Days | 60 Days | 90 Days | |
CoCrMo—CoCrMo + P(L,L-L/CL) | 4.74 | 7.85 | 0.03 | 0.03 |
CoCrMo—CoCrMo + P(D,L-L/CL) | 5.92 | 6.94 | 2.28 | 1.50 |
Samples | Exposition Time, Days | Ecorr, mV | SD | Etr, mV | SD | Rp, MΩ⋅cm2 | SD |
---|---|---|---|---|---|---|---|
CoCrMo | 0 | −72 | 15 | 790 | 7 | 2.0 | 0.3 |
30 | −151 | 56 | 775 | 5 | 1.3 | 0.8 | |
60 | −175 | 100 | 781 | 4 | 1.0 | 0.5 | |
90 | −101 | 12 | 770 | 1 | 2.1 | 0.3 | |
CoCrMo+P(L,L-L/CL)+PVA+HEP | 0 | +1 | 10 | 964 | 19 | 6.3 | 3.4 |
30 | −145 | 49 | 858 | 37 | 2.0 | 0.2 | |
60 | −116 | 80 | 828 | 11 | 2.2 | 0.6 | |
90 | −68 | 50 | 828 | 17 | 2.0 | 0.4 | |
CoCrMo+P(D,L-L/CL)+PVA+HEP | 0 | −59 | 57 | 955 | 7 | 5.8 | 1.3 |
30 | −84 | 9 | 778 | 1 | 1.6 | 0.1 | |
60 | −147 | 87 | 780 | 2 | 1.4 | 0.6 | |
90 | −50 | 37 | 783 | 2 | 0.8 | 0.1 |
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Kajzer, W.; Szewczenko, J.; Kajzer, A.; Basiaga, M.; Jaworska, J.; Jelonek, K.; Nowińska, K.; Kaczmarek, M.; Orłowska, A. Physical Properties of Electropolished CoCrMo Alloy Coated with Biodegradable Polymeric Coatings Releasing Heparin after Prolonged Exposure to Artificial Urine. Materials 2021, 14, 2551. https://doi.org/10.3390/ma14102551
Kajzer W, Szewczenko J, Kajzer A, Basiaga M, Jaworska J, Jelonek K, Nowińska K, Kaczmarek M, Orłowska A. Physical Properties of Electropolished CoCrMo Alloy Coated with Biodegradable Polymeric Coatings Releasing Heparin after Prolonged Exposure to Artificial Urine. Materials. 2021; 14(10):2551. https://doi.org/10.3390/ma14102551
Chicago/Turabian StyleKajzer, Wojciech, Janusz Szewczenko, Anita Kajzer, Marcin Basiaga, Joanna Jaworska, Katarzyna Jelonek, Katarzyna Nowińska, Marcin Kaczmarek, and Ada Orłowska. 2021. "Physical Properties of Electropolished CoCrMo Alloy Coated with Biodegradable Polymeric Coatings Releasing Heparin after Prolonged Exposure to Artificial Urine" Materials 14, no. 10: 2551. https://doi.org/10.3390/ma14102551