- freely available
- re-usable

*Energies*
**2014**,
*7*(5),
3204-3217;
doi:10.3390/en7053204

^{1}

^{2}

**Author Contributions**Zhenpo Wang gave precious advice on the test design and test rig set-up as well as necessary assistance in test implementation. Fengchun Sun discussed the main idea behind the work, and helped understand the Extended Kalman Filter Theory more thoroughly. David Dorrell reviewed and revised the manuscript. All authors read and approved the manuscript.

## Abstract

**:**Ultracapacitors (UCs) are the focus of increasing attention in electric vehicle and renewable energy system applications due to their excellent performance in terms of power density, efficiency, and lifespan. Modeling and parameterization of UCs play an important role in model-based regulation and management for a reliable and safe operation. In this paper, an equivalent circuit model template composed of a bulk capacitor, a second-order capacitance-resistance network, and a series resistance, is employed to represent the dynamics of UCs. The extended Kalman Filter is then used to recursively estimate the model parameters in the Dynamic Stress Test (DST) on a specially established test rig. The DST loading profile is able to emulate the practical power sinking and sourcing of UCs in electric vehicles. In order to examine the accuracy of the identified model, a Hybrid Pulse Power Characterization test is carried out. The validation result demonstrates that the recursively calibrated model can precisely delineate the dynamic voltage behavior of UCs under the discrepant loading condition, and the online identification approach is thus capable of extracting the model parameters in a credible and robust manner.

## 1. Introduction

In order to address serious concerns over energy sustainability and environmental impact, governments, the automotive industry, and academia are endeavoring to expedite a paradigm shift to a green transportation system [1]. Electric vehicles have been widely recognized as an integral part of such a high-efficiency system, owing to the fact that the use of electricity can potentially diversify the power sources for vehicle propulsion systems [2]. The performance of electric vehicles is heavily influenced by their energy storage systems (ESSs). Thus, the drivability, fuel economy, and recuperation efficiency of electric vehicles are highly dependent on the specific power and energy of their ESSs [3,4]. Electrochemical devices, including fuel cells [5], rechargeable batteries [6], and ultracapacitors (UCs) [7] are among the most appropriate components for vehicular ESSs, each with strengths and limitations [8].

Ultracapacitors, also known as supercapacitors or double-layer capacitors, have high power density, low internal resistance, high efficiency, and exceedingly long cycle life, while possessing the merits of wide operating temperature range and fast charging [9,10]. However, their drawbacks, such as low energy density and relative high price, limit the possibility of deploying UCs as the single energy storage for electric vehicles. At present, rechargeable batteries, especially Li-ion batteries, are commonly used for energy storage in electric vehicles since they have a much higher energy density in comparison to UCs. Nevertheless, their cycle-life expectancy is still far less than can be expected in the ideal case, and they are highly sensitive to the charging/discharging current rate and the operating temperature. Therefore, one promising alternative is to combine UCs and batteries to constitute a hybrid energy storage system (HESS) with synergistically improved performance [4,11–13].

A model that can simulate the dynamics of an UC with high precision is vital for energy management design in electric vehicles equipped with UCs or HESSs. The modeling of UCs has a rich history. This research can be generally grouped into three categories: electrochemical models, artificial neural networks (ANNs), and equivalent circuit models. Electrochemical models are developed from first principles and depict the real physical-chemical reactions within an ultracapacitor utilizing partial differential equations [14,15]. They are suitable for providing insights into the distributed physical-electrochemical reactions and for related ultracapacitor design/synthesis purposes. However, the large number of model parameters and the inaccessibility of these parameters in terms of the measurability deter their usage for real-time management and power control design. ANN-based models can accurately describe the transient behavior of energy storage units such as batteries and UCs, as long as the model has been well trained beforehand [16–20]. However, the training process may be time-consuming and require a considerable quantity of training data. Furthermore, the model should be retrained if the real characteristics of the UC drift significantly with aging. Therefore, the above mentioned causes make ANN-based models unsuitable for online energy management implementation.

Equivalent circuit models have been carefully developed, especially for the energy management design and power control; these have been extensively reported in the literature [21–23]. The key advantage of these equivalent models lies in their relatively small number of parameters. For example, Buller et al. proposed an equivalent circuit model composed of a bulk capacitor, a second-order capacitance-resistance network, and a series resistance. This was adopted in [24] to delineate the voltage behavior of an UC. The bulk capacitor mainly accounts for the capacitance behavior while the second-order capacitance-resistance network contributes to better capturing the voltage response under dynamic scenarios. The accuracy of the parameterization is significant in terms of the electric vehicle context. A large body of literature exists pertaining to parameter extraction methods. For example, Spyker and Nelms [25] presented a classical equivalent circuit that comprises an equivalent series resistance, an equivalent parallel resistance, and a main capacitor. The model parameters were derived by measuring the voltage responses during charge and rest. However, the accuracy of this method is highly dependent on the measurement precision so it is sensitive to measurement noise. Gualous et al. [26] used electrochemical impedance spectroscopy (EIS) to characterize a second-order equivalent circuit model for UCs. EIS is a commonly used approach for the measurement of the complex impedances of energy storage devices such as batteries and UCs. This is done for a wide range of frequencies by imposing a known bias voltage upon the terminals of the tested storage device and detecting the corresponding excitation current [27,28]. The obtained frequency spectrum can be modeled with interleaved RC circuits by analyzing the frequency dependency of the real and imaginary parts of impedance, thus resulting in an equivalent circuit model [22]. However, the precision of an identified model when obtained using the EIS method may be compromised under the varying loading conditions due to offline implementation. This should attribute to the fact that the lumped equivalent circuit model parameters are largely dependent on the loading conditions, which makes the offline EIS-obtained model incapable of representing the dynamics of batteries or UCs accurately in the real implementation. The majority of the methods presented in the literature are subject to the similar drawbacks, i.e., susceptibility to measurement precision and noise and offline implementation. In order to tackle these problems, this paper employs the extended Kalman filter (EKF) to recursively estimate the model parameters. The EKF has the advantages of being closed-loop, online, and the availability of error bounds. Hence has been widely used to perform the model calibration for batteries in real time. For example, Hu et al. presented a second-order equivalent circuit model for Li-ion batteries whose parameters were calibrated using the EKF [29]. However, there is a lack of literature reporting the application of the EKF technique to identify online UC model parameters.

This paper is arranged as follows: Section 2 reviews the equivalent circuit model used to describe the voltage response of UCs. Then, the formulation for the extended Kalman filter for model parameter estimation is detailed. Section 3 describes a test rig that was specially developed in order to carry out the experimental UC tests. Section 4 discusses the modeling results, followed by key conclusions in Section 5.

## 2. Modeling and Parameter Estimation for Ultracapacitors

#### 2.1. Ultracapacitor Model Structure

There are a variety of equivalent circuit model structures for UCs as reported in the literature. This paper selects the one that consists of a bulk capacitor, a second-order capacitance-resistance network and a series resistance. The second-order capacitance-resistance network is composed of two parallel RC circuits. The model originates from an impedance model in the frequency domain [30]. The detailed structure is shown in Figure 1 where u_{0} denotes the voltage across the bulk capacitor C, u_{1} and u_{2} denote the voltages of the two RC circuits, respectively, u denotes the output voltage, and R_{s} denotes the series resistance.

According to basic electrical circuit principles, the continuous state equation can be derived as:

The state equation can be further transformed into the discrete state equation so that:

Where ΔT is the sampling time; The output equation can be derived as:

#### 2.2. Parameter Estimation Using the Extended Kalman Filter

Recently, the Kalman filtering has gained more popularity in the field of state estimation, parameter estimation and dual estimation due to its inherent merits [31,32]. That is, it can be implemented online and automatically provides the estimation error bound. In order to implement extended Kalman filtering to recursively estimate the parameters, the process of parameter evolution can be formulated into a state equation so that:

_{k}is the state vector, and:

**θ**denotes the parameter vector, u

_{k}is the output voltage at time interval k, i

_{k}is the charging current (a negative value denotes discharging),

**ω**

_{k}represents the process noise, which is assumed to be Gaussian white noise with zero mean and covariance of

**Q**, and υ

_{k}represents the measured noise which is also assumed to be Gausian white noise with zero mean and a covariance of

**W**. Based on the process and output equations described above, the extended Kalman filter equations can be derived in the state-equation form. At each time interval, the time update and measurement update are consecutively performed. In this paper, two constant values are assigned to the process noise covariance and the measurement noise covariance:

Time update

$${\widehat{\mathit{\theta}}}_{k\mid k-1}={\widehat{\mathit{\theta}}}_{k}$$$${\mathit{\text{P}}}_{k\mid k-1}={\mathit{\text{P}}}_{k-1}+\mathit{\text{Q}}$$**θ̂**_{kk}_{−1}is the priori estimate of the parameter vector**θ**at time interval k before the measurement u_{k}is taken into consideration,**θ̂**_{k}is the a posteriori estimate of the parameter vector at time interval k−1,**P**_{k}_{|}_{k}_{−1}represents the a priori estimation error of parameter vector**θ̂**at time interval k, and**P**_{k}_{−1}represents the posteriori estimation error of parameter vector**θ̂**at time interval k−1.Measurement update:

$${\text{L}}_{k}={\mathit{\text{P}}}_{k\mid k-1}{\mathit{\text{C}}}_{k}^{T}{\left({\mathit{\text{C}}}_{k}{\mathit{\text{P}}}_{k\mid k-1}{\mathit{\text{C}}}_{k}^{T}+W\right)}^{-1}$$$${\widehat{\mathit{\theta}}}_{k}={\widehat{\mathit{\theta}}}_{k\mid k-1}+{\mathit{\text{L}}}_{k}({u}_{k}-g({\widehat{\mathit{\text{x}}}}_{k},{\mathit{\text{i}}}_{k},{\widehat{\mathit{\theta}}}_{k\mid k-1}))$$$${\mathit{\text{P}}}_{k}=(\mathit{\text{E}}-{\mathit{\text{L}}}_{k}{\mathit{\text{C}}}_{k}){\mathit{\text{P}}}_{k\mid k-1}$$$${{\mathit{\text{C}}}_{k}=\frac{dg({\widehat{\mathit{\text{x}}}}_{k},{\mathit{\text{i}}}_{k},{\mathit{\theta}}_{k})}{d\mathit{\theta}}|}_{\mathit{\theta}={\widehat{\mathit{\theta}}}_{k\mid k-1}}$$**W**represents the covariance of the measurement noise υ and**L**is the Kalman gain at time interval k.**x̂**_{k}can be computed given**x̂**_{k}_{−1}and**θ̂**_{k}_{−1}according to Equation (2). Updates in the time and measurement equations at each time interval means that the parameter vector**θ̂**_{k}can be recursively estimated. Since**x̂**_{k}acts as a function of the parameter vector**θ̂**_{k},**C**_{k}can be computed by performing recurrent differentiations, which are:$$\frac{dg({\widehat{\mathit{\text{x}}}}_{k},{\mathit{\text{i}}}_{k},{\mathit{\theta}}_{k})}{d\mathit{\theta}}=\frac{\partial g({\widehat{\mathit{\text{x}}}}_{k},{\mathit{\text{i}}}_{k},{\mathit{\theta}}_{k})}{\partial \mathit{\theta}}+\frac{\partial g({\widehat{\mathit{\text{x}}}}_{k},{\mathit{\text{i}}}_{k},{\mathit{\theta}}_{k})}{\partial {\widehat{\mathit{\text{x}}}}_{k}}\frac{d{\widehat{\mathit{\text{x}}}}_{k}}{d\mathit{\theta}}$$$$\frac{d{\widehat{\mathit{\text{x}}}}_{k}}{d\mathit{\theta}}=\frac{\partial f({\widehat{\mathit{\text{x}}}}_{k-1},{\mathit{\text{i}}}_{k-1},\mathit{\theta})}{\partial \mathit{\theta}}+\frac{\partial f({\widehat{\mathit{\text{x}}}}_{k-1},{\mathit{\text{i}}}_{k-1},\mathit{\theta})}{\partial {\widehat{\mathit{\text{x}}}}_{k-1}}\frac{d{\widehat{\mathit{\text{x}}}}_{k-1}}{d\mathit{\theta}}$$$$\frac{\partial g({\widehat{\mathit{\text{x}}}}_{k},{\mathit{\text{i}}}_{k},{\mathit{\theta}}_{k})}{\partial \mathit{\theta}}=[\begin{array}{cccccc}0& 0& 0& 0& 0& {\mathit{\text{i}}}_{k}\end{array}]$$$$\frac{\partial g({\widehat{\mathit{\text{x}}}}_{k},{\mathit{\text{i}}}_{k},{\mathit{\theta}}_{k})}{\partial {\widehat{\mathit{\text{x}}}}_{k}}=[\begin{array}{ccc}1& 1& 1\end{array}]$$$$\frac{\partial f({\widehat{\mathit{\text{x}}}}_{k-1},{\mathit{\text{i}}}_{k-1},\mathit{\theta})}{\partial \mathit{\theta}}=\left[\begin{array}{cccccc}0& 0& 0& 0& \mathrm{\Delta}T{\mathit{\text{i}}}_{k-1}& 0\\ {u}_{1,k-1}& {\mathit{\text{i}}}_{k-1}& 0& 0& 0& 0\\ 0& 0& {u}_{2,k-1}& {\mathit{\text{i}}}_{k-1}& 0& 0\end{array}\right]$$$$\frac{\partial f({\widehat{\mathit{\text{x}}}}_{k-1},{\mathit{\text{i}}}_{k-1},\mathit{\theta})}{\partial {\widehat{\mathit{\text{x}}}}_{k-1}}=\left[\begin{array}{ccc}1& 0& 0\\ 0& {\widehat{a}}_{1,k-1}& 0\\ 0& 0& {\widehat{a}}_{2,k-1}\end{array}\right]$$It is obvious that the derivative calculation is recursive, and can be initiated by:

$$\frac{d{\widehat{\mathit{\text{x}}}}_{0}}{d\mathit{\theta}}=0$$

## 3. Experimental Setup

In order to collect experimental data for the parameter estimation, a test rig was developed. A block diagram is shown in Figure 2, while components of the actual rig are illustrated in Figure 3. It consists of a Digtron Battery Test System (BTS-600), a thermal chamber, a host computer and an UC. The BTS-600 is assigned to charge the UC according to a pre-designed program with a maximum voltage of 500 V and a maximum charging/discharging current of 300 A. It has the capability of recoding the real-time testing parameters such as terminal voltage, load current and accumulative capacity loss. The terminal voltage and load current are logged and used to perform the parameter estimation. The thermal chamber is used to maintain an ambient temperature of 20 °C during all the tests; this reduces the influence of temperature on the variation of the model parameters. The host computer is responsible for controlling the load profile and logging the measured data from the BTS-600. A commercially available UC was selected to conduct the experimental tests. It has a nominal capacitance of 3000 F and a rated voltage of 2.7 V.

## 4. Results and Discussion

#### 4.1. Parameter Estimation in the DST Test

In order to validate the proposed estimation algorithm, a transient power test based on the standard Dynamic Stress Test (DST) was conducted on the established test rig. The DST-based test can represent the dynamic load conditions of a UC during daily driving of an electric vehicle with UCs as the single or complementary energy storage. The voltage and current of the UC in the DST test are shown in the Figure 4 while a magnified part of the voltage curve is also shown.

It is well-known that Kalman filters require a priori knowledge about the process and the measurement noise statistics. When it comes to the algorithm, the process and measurement noise covariance, namely Q and W, should be carefully selected. Based on the knowledge of the test UC, the parameters for the extended Kalman filter algorithm are specified by:

Given the specified parameters, the proposed extended Kalman filter was implemented in order to estimate online the model parameters of the UC. The evolution of the estimated model parameters is shown in Figure 5. It is clear that all the estimated parameters tend to converge at the end of the test. It can be seen that the value of R_{1} is bigger than that of R_{2} while C_{1} is just slightly smaller than C_{1}. It means that the first RC circuit has a larger time constant than the second RC network in the selected model. It can be observed that the value of the main capacitor of C exhibits a gently decline, which indicates the capacitance varies with the terminal voltage. It can also be seen that the estimated resistance R_{s} increases along with the decline of the voltage in the test. The variations of C and R_{s} reveal the internal characteristics are also dependent on the external loading conditions [33].

The evolution of the measured and estimated voltages is shown in Figure 6. It can be seen that the estimated voltage shows good agreement with the measured voltage in the DST test. This proves that the recursively identified model can precisely capture the voltage response after compensating for the initial model error. The relative voltage error is illustrated in Figure 7 which further demonstrates the model performance. The converged estimation result is shown in Table 1. According to Equations (3) to (6), the model parameters can be computed and these are shown in Table 2.

#### 4.2. Model Validation in the HPPC

In order to validate the derived model, a Hybrid Pulse Power Characterization (HPPC) was conducted. The voltage and current profiles in the HPPC test are shown in Figure 8, while a magnified part of the voltage curve is also shown. The simulated and measured voltages are illustrated in Figure 9. It is obvious that the model with the previously estimated parameters can well represent the voltage behavior under the HPPC test. The error, instead of the relative error between the simulated and measured voltages, is used to indicate the accuracy of the identified model because the voltage of the UC generally decreases to 0 V at the end of the test. The error curve is shown in Figure 10. The mean error is 0.058 V, indicating the high accuracy of the model. It verified that proposed estimation algorithm can achieve robust parameter estimation and be used to derive a model that can predict the dynamics of a UC under different load profiles. Owing to that the DST and HPPC loading profiles are highly dynamic and representative of the real driving conditions of vehicles, it is reasonable to conclude that the derived model is applicable to the real driving scenarios with sufficient accuracy. That is to say, the proposed method can identify the model with robustness and precision in real implementation.

## 5. Conclusions

This paper presents an online model identification method for a UC model based on the well-known Kalman filter. An equivalent circuit model was used to represent the dynamics of a UC. It was composed of a bulk capacitor, a second-order RC network and a series internal resistance. The rationale for the use of this model is that it can sufficiently capture the transient voltage response without introducing heavy computation load. The evolution of the model dynamics was depicted by a body of discrete state equations according to electrical principles. The equation parameters were extracted and used as the targets for the proposed estimation method. The extended Kalman filter was formulated and applied to recursively identify the parameters through a DST test conducted on the test rig. The results show that the recursively calibrated model can precisely represent the transient voltage behavior under the dynamic operating conditions. In order to further validate the accuracy of the model, the HPPC test was implemented. The result shows that the model can also depict the voltage behavior under the HPPC operating scenarios with high fidelity. This verifies that the proposed method can identify a model in a robust manner against different load profiles.

## Acknowledgments

Lei Zhang is grateful to the funding from the China Scholarship Council as well as the University of Technology Sydney and Beijing Institute of Technology for his studies.

## Conflicts of Interest

The authors declare no conflict of interest.

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**Figure 3.**Pictures of the test rig. (

**a**) The Digtron BTS-600, which is responsible for charging and discharging; (

**b**) Thermal chamber; (

**c**) Tested ultracapacitor in chamber.

**Figure 5.**The evolution of the estimated model parameters in the DST test:

**(a**) R

_{1}; (

**b**) C

_{1}; (

**c**) R

_{2}; (

**d**) C

_{2}; (

**e**) C (

**f**) R

_{s}.

a_{1} | b_{1} | a_{2} | b_{2} | C_recip | R_{s} |
---|---|---|---|---|---|

0.9677 | 1.55 × 10^{−5} | 0.8767 | 8.77 × 10^{−6} | 3.85 × 10^{−4} | 6.93 × 10^{−4} |

C(F) | C_{1}(F) | C_{2}(F) | R_{1}(Ω) | R_{2}(Ω) | R_{s}(Ω) |
---|---|---|---|---|---|

2601 | 628 | 1065 | 4.85 × 10^{−4} | 7.14 × 10^{−4} | 6.93 × 10^{−4} |

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