3.3.1. Gaseous Emissions
Standard test were carried out with poplar, poplar and LS and different blends of poplar and pine as is indicated in
Section 2.1. As in optimization test, the thermal power input (
), water temperature gradient (Δ
Tw = Thw − Tcw) and water flow rate (
ṁw) were kept constant within each test (
Table 3). The excess air and
ṁ
pa/
ṁ
sa used during the test were those determined as optimal in the previous section for all samples, except for PO25PI75 and PO5SP95, for which
λ = 1.3 was used instead of
λ = 1.4 due to experimental problems.
Figure 4 and
Table 5 shows the fireplace, stack-1 and stack-2 fume temperatures, the fume mass flow and the heat losses
ϕa. All the fume temperatures were lower with PO98LS2 than with PO100. However, with poplar and pine blends, the pine addition led to higher fireplace fume temperatures. The reason is the higher heating value of the pine. However, the same differences were not observed in the stacks (1 and 2) fume temperatures after heat exchange with the water circuit. A decrease in
Tsf,1 and
Tsf,2 was observed when both, LS and pine, were added to the blend, so the use of LS and poplar improved the heat exchange by decreasing
ϕa. Since the test with PO98LS2 and pellets blends with 75 and 95 wt.%-pine use low
λ, lower efficiency losses (
ϕa) were observed.
Table 6 shows the standard deviations and mean values for gaseous emissions in mg/m
3 considering a 10 vol.% O
2 (b.s), together with heat losses
ϕg. PO100 shows 746.6 mg/m
3 (corrected to 10 vol.% O
2) of CO. This concentration is 200 mg/m
3 (10 vol.% O
2) higher than those in the optimization test. The reason can be some experimental changes in the pellet flowrate (modifying the thermal power input, (
) and longer test time (six hours versus 30 min, making test condition more stable). As a result of LS addition, a considerable reduction in CO emissions was observed, possibly because the increase of the gas-phase reactions, led to improving the combustion process [
42]. Similar results were observed with the pine addition. In this case, although a trend with the pine percentage was not detected, a reduction in CO emissions close to 50% was observed. Some authors indicate that the addition of pine to herbaceous or energy crops leads to a reduction in CO emissions due to the lower ash content in the blend [
14,
16].
The total organic compounds (TOC) emission were similar in all test. The differences observed are within the standard deviations.
An important NO
x emissions reduction was obtained when LS or pine were added to poplar. NO
x emissions from poplar combustion were 229 mg/m
3 (10 vol.% O
2). NO
x emissions in PO95LS2 (199.5 mg/m
3) were slightly lower than those from PO100 probably because of the lower nitrogen content of the pellets and the higher thermal capacity of the blend (due to LS addition). Regarding poplar and pine blends, lowest NO
x emissions were observed (168, 140, 96.7 mg/m
3 (10 vol.% O
2) for PO45PI55, PO25PI75, PO5PI95, respectively) consistently with the highest pine content (and consequently, lower nitrogen content) in the blends.
Figure 5 shows a relation between the nitrogen content in the biomass blend and its NO
x emissions. An increase in NO
x formation rate can be observed when the nitrogen content in biomass increases. Moreover, extrapolating the resulting function to the ordinate axis, some NO
x emission would be observed even when the biomass does not contain any nitrogen. This proves that the main contribution to the NO
x emissions is the fuel-nitrogen mechanism. This is consistent with the low flame temperature reached in boilers, indicating that the contribution of the thermal NO mechanisms is not expected to be important [
47].
Regarding SO
2 emissions, since poplar and pine have a very low sulphur content, emissions were not detected when these biomass samples (alone or mixed) were burned. However, the addition of LS leads to pellets with 0.32 wt.% of sulphur and consistently, 132.7 mg/m
3 (10 vol.%) of SO
2 was registered. Fournel et al. [
8] agrees to indicate an increase in SO
2 emissions when LS is used as additive. Small efficiency losses (
ϕg) were observed when PO100 was burned (0.4%). Moreover, a decrease in
ϕg was observed with the addition of LS and pine due to the decrease in CO emissions.
3.3.2. Unburned Matter and Combustion Efficiency
Solid residues from the standard combustion test were collected in order to evaluate their burnout degree, the distribution of the solid residues in the different parts of the boiler and the combustion efficiency.
Figure 6 shows the unburned matter and efficiency losses in the solid residue (
ϕr).
The ratio ṁsolid residue/ṁb in PO100 standard combustion test was close to 2%. Moreover, low ϕr was registered, 0.3%, and the residues obtained were mainly ash. The residues was mainly located in ashtray 1 with particle sizes below 3.15 mm.
Regarding pine and poplar blends, a decrease in the ratio
ṁsolid residue/
ṁb and
ϕr was detected with the addition of pine, with
ṁsolid residue/
ṁb being 0.64 when 95% pine is added and
ϕr = 0.2 independently of the percentage of pine addition. The results are in accordance with previous findings [
14] where a decrease in the solid residue and unburned matter, when mixtures of agricultural residues and pine were burned, was observed. The reason is that pine improves the combustion process by decreasing the ash content of the biomass pellet blend.
For PO98LS2, the LS addition leads to pellets with a slightly lower ratio ṁsolid residue/ṁb than those without it (PO100) and with the lowest ϕr. Concerning the distribution of ash and unburned matter was located, in all tests, mainly in astray 1, with a particle size below 3.15 mm.
Therefore, no unburned matter-related problem during the combustion of the pellet tested (with and without pine or LS) was observed. Moreover, due to the low content of potassium, sodium and chlorine in the pellet tested, as it is normal in woody biomass [
48,
49], sintering problems were not observed and thus, easy ash cleaning was possible for ashtray 1 with the standard cleaning systems.
As commented before, the addition of LS or pine to the poplar pellets led to decreasing
ϕr. However, the differences observed with PO100 were not significant in combustion efficiency.
Figure 7 shows the efficiency losses
ϕa,
ϕg and
ϕr, the combustion and boiler efficiency (
ηi and
ηd, respectively) together with the limits given in standard EN 303-5 [
39] for classifying boilers.
Since boiler efficiency takes into account the heat transferred to the room and the experiments were performed in different months, the efficiency calculated with the direct method was not used to compare the combustion efficiency. Therefore, the combustion efficiency was only compared using the indirect method, where heat losses ϕa, ϕg, ϕr were considered.
Both the use of LS or pine contribute to increase the combustion efficiency (ηi). The combustion of PO98LS2 allowed the use of lower excess air than in the case of PO100 combustion and thus, the fume flow and ϕa were smaller. Moreover, since minor unburned gaseous and solid matter were observed, ϕg and ϕr were also lower. As similar excess air was used (given similar flow and fume temperature), non-important differences in combustion efficiency were observed when 55 wt.% pine was added to the poplar pellets. However, ϕg and ϕr were slightly lower. The increase of pine to the blends PO25P75 and PO5SP95 also allowed the use of lower excess air and thus ϕa, ϕg and ϕr were lower and combustion efficiency (ηi) higher than with PO100 combustion.
Concerning gas emissions and combustion efficiency (
ηi),
Table 7 shows the test classification according to EN 303-5 [
39]. PO100, PO25PI75 and PO45PI55 test can be classified as Class 4 and PO5PI95 and PO98LS2 as Class 3. However, PO98LS2 despite complying with the efficiency and gas emissions limits established in EN 303-5 [
39], is not an appropriate fuel for domestic biomass boilers. Although SO
2 emissions are not regulated in domestic boilers, the PO98LS2 sulphur content determined was eight times higher than allowed in the mandatory standard EN 17225-2 [
1] and consequently, significant emissions of SO
2 were measured.
On the other hand, NO
x emissions are not regulated in EN 303-5 [
39] standard. However, regulation (UE) 2015/1189 [
50] (to new boilers from 2020) indicates NO
x emission limits below 200 mg/m
3. According to this, and considering the result obtained, PO100 combustion could only be burned in domestic boilers when it is blended with pine. Therefore, poplar and pine blends are adequate as fuels for domestic heating.