Biosorptive Removal of Ni(Ii) from Wastewater and Industrial Effluent
Abstract
:Introduction
Materials and Methods
Preparation of Biosorbent Material (FBM)
Preparation of Chemically Treated Leached Biomass (LBM)
Preparation of Nickel Solution
Instrumentation
Batch Mode Adsorption Study
- Ci-initial concentration of metal ion mg/L;
- Ce – Equilibrium concentration of metal ion mg/L;
- m – mass of adsorbent g/L;
- qe – Amount of metal ion adsorbed per gram of adsorbent.
Column Mode Adsorption Studies
Desorption Study
FT-IR Method
Results and Discussion
Effect of pH on Biosorption
Effect of Biosorbent Dose
Effect of Initial Metal Concentration
Analysis of the Kinetic of Ni(II) Removals
- Kad – is the rate constant of adsorbent
- q- is the amount of metal ion adsorbed at time t (mg/g)
- qe is the amount of metal ions adsorbed at equilibrium (mg/g)
- Kad – is the rate constant of adsorbent
- q- is the amount of metal ion adsorbed at time t (mg/g)
- qe is the amount of metal ions adsorbed at equilibrium (mg/g)
Effect of Background Ions
Column Study
Study on the Regeneration of Impregnated Biomass
Adsorption Isotherms
- S = moles sorbed at equilibrium per mass of sorbent (mg/g) i.e. (Ce/m)
- KF = Freundlich isotherm constant (L/g)
- N = Freundlich isotherm constant; N ≥ 1
- Cs = Sorbate concentration in solution at equilibrium (mg/L)
- S = moles sorbed at equilibrium /mass of sorbent (mg/g) i.e. Ce/m
- AM = maximum sorption capacity of the sorbent (mg/g)
- KL = Langmuir adsorption constant, related to binding energy of the Sorbate (l/mg)
- Cs = Sorbate concentration in solution at equilibrium (mg/L)
- Am = the maximum sorption capacity of the sorbent
Identification of Ni (II) Binding Functional Group
Application of Biomass for Removal of Nickel from Industrial Effluents
Conclusion
Biomass | Adsorption Mode | R2 | 1/N | KF |
---|---|---|---|---|
FBM | Batch | 0.9561 | 0.2042 | 0.6174 |
LBM | Batch | 0.9802 | 0.2354 | 0.9630 |
Biomass | Adsorption Mode | R2 | AM | KL |
---|---|---|---|---|
FBM | Batch | 0.7728 | 0.606 | −0.9712 |
LBM | Batch | 0.83 | 0.9451 | −0.3477 |
Sample | pH | Percentage removal of nickel |
---|---|---|
Lab | 3.0 | 85 |
Wastewater | 2.5 | 56 |
Wastewater(adjusted pH) | 3.0 | 70 |
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Pandey, P.K.; Choubey, S.; Verma, Y.; Pandey, M.; Kamal, S.S.K.; Chandrashekhar, K. Biosorptive Removal of Ni(Ii) from Wastewater and Industrial Effluent. Int. J. Environ. Res. Public Health 2007, 4, 332-339. https://doi.org/10.3390/ijerph200704040009
Pandey PK, Choubey S, Verma Y, Pandey M, Kamal SSK, Chandrashekhar K. Biosorptive Removal of Ni(Ii) from Wastewater and Industrial Effluent. International Journal of Environmental Research and Public Health. 2007; 4(4):332-339. https://doi.org/10.3390/ijerph200704040009
Chicago/Turabian StylePandey, Piyush Kant, Shweta Choubey, Yashu Verma, Madhurima Pandey, S. S. Kalyan Kamal, and K. Chandrashekhar. 2007. "Biosorptive Removal of Ni(Ii) from Wastewater and Industrial Effluent" International Journal of Environmental Research and Public Health 4, no. 4: 332-339. https://doi.org/10.3390/ijerph200704040009