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Sensors 2010, 10(4), 2460-2471; doi:10.3390/s100402460
Article

Estimation of Biological Oxygen Demand and Chemical Oxygen Demand for Combined Sewer Systems Using Synchronous Fluorescence Spectra

1,* , 1
, 1
 and 2
Received: 21 January 2010; in revised form: 1 March 2010 / Accepted: 6 March 2010 / Published: 24 March 2010
(This article belongs to the Special Issue Laser Spectroscopy and Sensing)
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Abstract: Real-time monitoring of water quality for sewer system is required for efficient sewer network design because it provides information on the precise loading of pollutant to wastewater treatment facilities and the impact of loading on receiving water. In this study, synchronous fluorescence spectra and its first derivatives were investigated using a number of wastewater samples collected in sewer systems in urban and non-urban areas, and the optimum fluorescence feature was explored for the estimation of biochemical oxygen demand (BOD) and chemical oxygen demand (COD) concentrations of sewer samples. The temporal variations in BOD and COD showed a regular pattern for urban areas whereas they were relatively irregular for non-urban areas. Irrespective of the sewer pipes and the types of the areas, two distinct peaks were identified from the synchronous fluorescence spectra, which correspond to protein-like fluorescence (PLF) and humic-like fluorescence (HLF), respectively. HLF in sewer samples appears to be associated with fluorescent whitening agents. Five fluorescence characteristics were selected from the synchronous spectra and the first-derivatives. Among the selected fluorescence indices, a peak in the PLF region (i.e., Index I) showed the highest correlation coefficient with both BOD and COD. A multiple regression approach based on suspended solid (SS) and Index I used to compensate for the contribution of SS to BOD and COD revealed an improvement in the estimation capability, showing good correlation coefficients of 0.92 and 0.94 for BOD and COD, respectively.
Keywords: sewer system; fluorescence; prediction; BOD; COD sewer system; fluorescence; prediction; BOD; COD
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Hur, J.; Lee, B.-M.; Lee, T.-H.; Park, D.-H. Estimation of Biological Oxygen Demand and Chemical Oxygen Demand for Combined Sewer Systems Using Synchronous Fluorescence Spectra. Sensors 2010, 10, 2460-2471.

AMA Style

Hur J, Lee B-M, Lee T-H, Park D-H. Estimation of Biological Oxygen Demand and Chemical Oxygen Demand for Combined Sewer Systems Using Synchronous Fluorescence Spectra. Sensors. 2010; 10(4):2460-2471.

Chicago/Turabian Style

Hur, Jin; Lee, Bo-Mi; Lee, Tae-Hwan; Park, Dae-Hee. 2010. "Estimation of Biological Oxygen Demand and Chemical Oxygen Demand for Combined Sewer Systems Using Synchronous Fluorescence Spectra." Sensors 10, no. 4: 2460-2471.


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