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Molbank 2018, 2018(2), M995; https://doi.org/10.3390/M995

2,4-Bis[(2,6-diisopropylphenyl)imino]-3-methylpentan-3-ol

The Key Laboratory of Life-Organic Analysis and Key Laboratory of Pharmaceutical Intermediates and Analysis of Natural Medicine, Department of Chemistry and Chemical Engineering, Institute of Anticancer Agents Development and Theranostic Application, Qufu Normal University, Qufu 273165, China
The first two authors are equal first authors.
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Authors to whom correspondence should be addressed.
Received: 16 April 2018 / Revised: 8 May 2018 / Accepted: 11 May 2018 / Published: 12 May 2018
(This article belongs to the Section Structure Determination)
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Abstract

The compound 2,4-bis[(2,6-diisopropylphenyl)imino]-3-methylpentan-3-ol was synthesized with a yield of approximately 80% by the reaction of 2,4-bis(2,6-diisopropylphenylimino)pentan-3-one with trimethylaluminum, which was followed by hydrolysis with an aqueous NaOH solution. A chemoselective addition to the C=O bond occurred in this reaction. The structure was confirmed by X-ray crystallography. This new compound was also fully characterized by 1H, 13C-NMR spectroscopy and 1H-13C HSQC spectroscopy, mass spectrometry and elemental analysis. View Full-Text
Keywords: trimethylaluminum; selective reduction; α-hydroxyl-β-diimine; X-ray crystallography trimethylaluminum; selective reduction; α-hydroxyl-β-diimine; X-ray crystallography
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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MDPI and ACS Style

Sun, W.; Kong, W.; Du, Q.; Zhang, S.; Guo, L.; Liu, Z. 2,4-Bis[(2,6-diisopropylphenyl)imino]-3-methylpentan-3-ol. Molbank 2018, 2018, M995.

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