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Molbank 2010, 2010(2), M676; doi:10.3390/M676
Short Note

(E)-2-((4R,5R)-5-((Benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-ene-1,4-diol

1, 2, 2, 1, 3,4,*  and 1,*
1 INTEQUI-CONICET-Facultad de Química, Bioquímica y Farmacia, Universidad Nacional de San Luis, Chacabuco y Pedernera, 5700 San Luis, Argentina 2 Instituto Universitario de Bio-Orgánica “Antonio González”, Universidad de La Laguna, Avda. Astrofísico Francisco Sánchez, 2, 38206 La Laguna, Tenerife, Spain 3 Institut für Organische Chemie, Universität Regensburg, Universitätsstr. 31, 93040 Regensburg, Germany 4 ICMA, CSIC-Universidad de Zaragoza, Pedro Cerbuna 12, 50009 Zaragoza, Spain
* Authors to whom correspondence should be addressed.
Received: 11 March 2010 / Accepted: 14 April 2010 / Published: 19 April 2010
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Abstract

The synthesis of (E)-2-((4R,5R)-5-((benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-ene-1,4-diol by a one-step reduction of the appropriate 2-substituted butenolide is reported. Product characterization was carried out by IR, 1H NMR, 13C NMR, MS, elemental analysis and optical rotation.
Keywords: reduction; DIBAL-H; substituted butenolides; allylic diols reduction; DIBAL-H; substituted butenolides; allylic diols
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Carreras, C.R.; García, C.E.; Martín, V.S.; Tonn, C.E.; Díaz, D.D.; Ceñal, J.P. (E)-2-((4R,5R)-5-((Benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-ene-1,4-diol. Molbank 2010, 2010, M676.

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