(E)-2-((4R,5R)-5-((Benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-ene-1,4-diol

doi:10.3390/M676

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Molbank 2010, 2010(2), M676; doi:10.3390/M676

Short Note

(E)-2-((4R,5R)-5-((Benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-ene-1,4-diol

Carlos R. Carreras¹, Celina E. García², Víctor S. Martín², Carlos E. Tonn¹, David Díaz Díaz^3,4,* and Juan Pedro Ceñal^1,*

¹ INTEQUI-CONICET-Facultad de Química, Bioquímica y Farmacia, Universidad Nacional de San Luis, Chacabuco y Pedernera, 5700 San Luis, Argentina ² Instituto Universitario de Bio-Orgánica “Antonio González”, Universidad de La Laguna, Avda. Astrofísico Francisco Sánchez, 2, 38206 La Laguna, Tenerife, Spain ³ Institut für Organische Chemie, Universität Regensburg, Universitätsstr. 31, 93040 Regensburg, Germany ⁴ ICMA, CSIC-Universidad de Zaragoza, Pedro Cerbuna 12, 50009 Zaragoza, Spain

* Authors to whom correspondence should be addressed.

Received: 11 March 2010 / Accepted: 14 April 2010 / Published: 19 April 2010

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Abstract: The synthesis of (E)-2-((4R,5R)-5-((benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-ene-1,4-diol by a one-step reduction of the appropriate 2-substituted butenolide is reported. Product characterization was carried out by IR, ¹H NMR, ¹³C NMR, MS, elemental analysis and optical rotation.

Keywords: reduction; DIBAL-H; substituted butenolides; allylic diols

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Cite This Article

MDPI and ACS Style

Carreras, C.R.; García, C.E.; Martín, V.S.; Tonn, C.E.; Díaz, D.D.; Ceñal, J.P. (E)-2-((4R,5R)-5-((Benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-ene-1,4-diol. Molbank 2010, 2010, M676.

AMA Style

Carreras CR, García CE, Martín VS, Tonn CE, Díaz DD, Ceñal JP. (E)-2-((4R,5R)-5-((Benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-ene-1,4-diol. Molbank. 2010; 2010(2):M676.

Chicago/Turabian Style

Carreras, Carlos R.; García, Celina E.; Martín, Víctor S.; Tonn, Carlos E.; Díaz, David Díaz; Ceñal, Juan Pedro. 2010. "(E)-2-((4R,5R)-5-((Benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-2-ene-1,4-diol." Molbank 2010, no. 2: M676.

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