Int. J. Mol. Sci. 2006, 7(10), 451-455; doi:10.3390/i7100451
Communication

Additional Solvent Ionizing Power Values for Binary Water- 1,1,1,3,3,3-Hexafluoro-2-propanol Solvents

1,* email and 2
Received: 19 October 2006; Accepted: 27 October 2006 / Published: 30 October 2006
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: Determinations of the specific rates of solvolysis of 1-adamantyl bromide and 1-adamantyl iodide in 1,1,1,3,3,3-hexafluoro-2-propanol-water mixtures, in conjunction withearlier reported values in 80% ethanol, have led to additional YBr and YI solvent ionizingpower values. These new values will be especially important in avoiding multicollinearitywhen the extended Grunwald-Winstein equation (extended by addition of a term involvingsolvent nucleophilicity) is used to correlate solvent-induced changes in the specific rates ofsolvolyses involving a bromide or iodide ion leaving group.
Keywords: 1-adamantyl bromide; 1-adamantyl iodide; 1; 1; 1; 3; 3; 3-hexafluoro-2-propanol; Grunwald-Winstein equation; solvent ionizing power.
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MDPI and ACS Style

Kevill, D.N.; Ryu, Z.H. Additional Solvent Ionizing Power Values for Binary Water- 1,1,1,3,3,3-Hexafluoro-2-propanol Solvents. Int. J. Mol. Sci. 2006, 7, 451-455.

AMA Style

Kevill DN, Ryu ZH. Additional Solvent Ionizing Power Values for Binary Water- 1,1,1,3,3,3-Hexafluoro-2-propanol Solvents. International Journal of Molecular Sciences. 2006; 7(10):451-455.

Chicago/Turabian Style

Kevill, Dennis N.; Ryu, Zoon H. 2006. "Additional Solvent Ionizing Power Values for Binary Water- 1,1,1,3,3,3-Hexafluoro-2-propanol Solvents." Int. J. Mol. Sci. 7, no. 10: 451-455.


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