Int. J. Mol. Sci. 2006, 7(10), 451-455; doi:10.3390/i7100451
Communication

Additional Solvent Ionizing Power Values for Binary Water- 1,1,1,3,3,3-Hexafluoro-2-propanol Solvents

1 Department of Chemistry and Biochemistry, Northern Illinois University, Dekalb, Illinois 60115-2862, U.S.A. 2 Department of Chemistry, Dong-Eui University, 995 Eomgwangno, Busan-Jin-Gu, Busan 614-714, Korea
* Author to whom correspondence should be addressed.
Received: 19 October 2006; Accepted: 27 October 2006 / Published: 30 October 2006
PDF Full-text Download PDF Full-Text [41 KB, uploaded 20 June 2008 16:51 CEST]
Abstract: Determinations of the specific rates of solvolysis of 1-adamantyl bromide and 1-adamantyl iodide in 1,1,1,3,3,3-hexafluoro-2-propanol-water mixtures, in conjunction withearlier reported values in 80% ethanol, have led to additional YBr and YI solvent ionizingpower values. These new values will be especially important in avoiding multicollinearitywhen the extended Grunwald-Winstein equation (extended by addition of a term involvingsolvent nucleophilicity) is used to correlate solvent-induced changes in the specific rates ofsolvolyses involving a bromide or iodide ion leaving group.
Keywords: 1-adamantyl bromide; 1-adamantyl iodide; 1; 1; 1; 3; 3; 3-hexafluoro-2-propanol; Grunwald-Winstein equation; solvent ionizing power.

Article Statistics

Load and display the download statistics.

Citations to this Article

Cite This Article

MDPI and ACS Style

Kevill, D.N.; Ryu, Z.H. Additional Solvent Ionizing Power Values for Binary Water- 1,1,1,3,3,3-Hexafluoro-2-propanol Solvents. Int. J. Mol. Sci. 2006, 7, 451-455.

AMA Style

Kevill DN, Ryu ZH. Additional Solvent Ionizing Power Values for Binary Water- 1,1,1,3,3,3-Hexafluoro-2-propanol Solvents. International Journal of Molecular Sciences. 2006; 7(10):451-455.

Chicago/Turabian Style

Kevill, Dennis N.; Ryu, Zoon H. 2006. "Additional Solvent Ionizing Power Values for Binary Water- 1,1,1,3,3,3-Hexafluoro-2-propanol Solvents." Int. J. Mol. Sci. 7, no. 10: 451-455.

Int. J. Mol. Sci. EISSN 1422-0067 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert