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Int. J. Mol. Sci. 2016, 17(12), 2014; doi:10.3390/ijms17122014

Preparation of a Bis-GMA-Free Dental Resin System with Synthesized Fluorinated Dimethacrylate Monomers

College of Materials Science and Engineering, South China University of Technology, Guangzhou 510641, China
Author to whom correspondence should be addressed.
Academic Editor: Ihtesham ur Rehman
Received: 16 September 2016 / Revised: 21 November 2016 / Accepted: 22 November 2016 / Published: 1 December 2016
(This article belongs to the Section Biomaterial Sciences)
View Full-Text   |   Download PDF [2564 KB, uploaded 1 December 2016]   |  


With the aim of reducing human exposure to Bisphenol A (BPA) derivatives in dentistry, a fluorinated dimethacrylate monomer was synthesized to replace 2,2-bis[4-(2-hydroxy-3-methacryloy-loxypropyl)-phenyl]propane (Bis-GMA) as the base monomer of dental resin. After mixing with reactive diluent triethyleneglycol dimethacrylate (TEGDMA), fluorinated dimethacrylate (FDMA)/TEGDMA was prepared and compared with Bis-GMA/TEGDMA in physicochemical properties, such as double bond conversion (DC), volumetric shrinkage (VS), water sorption (WS) and solubility (WSL), flexural strength (FS) and modulus (FM). The results showed that, when compared with Bis-GMA based resin, FDMA-based resin had several advantages, such as higher DC, lower VS, lower WS, and higher FS after water immersion. All of these revealed that FDMA had potential to be used as a substitute for Bis-GMA. Of course, many more studies, such as biocompatibility testing, should be undertaken to prove whether FDMA could be applied in clinic. View Full-Text
Keywords: dental resin; Bis-GMA free; fluorinated dimethacrylate; physicochemical properties dental resin; Bis-GMA free; fluorinated dimethacrylate; physicochemical properties

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Luo, S.; Zhu, W.; Liu, F.; He, J. Preparation of a Bis-GMA-Free Dental Resin System with Synthesized Fluorinated Dimethacrylate Monomers. Int. J. Mol. Sci. 2016, 17, 2014.

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